Quantum dots and quantum dot solutions
Quantum dots including semiconductor nanocrystals, methods of producing the same, and quantum dot solutions and electronic devices including the same. The quantum dots do not include cadmium, lead, or a combination thereof. The quantum dots include an organic ligand and a halogen on the surfaces, and the quantum dots are dispersible in an organic solvent to form organic solutions.
1. Quantum dots comprising a semiconductor nanocrystal, wherein the quantum dots do not comprise cadmium, lead, or a combination of thereof,
the quantum dots comprise an organic ligand and a halogen disposed on a surface of the quantum dots,
an amount of the organic ligand is less than or equal to about 10 weight percent based on a total weight of the quantum dots.
2. The quantum dots of claim 1 , wherein an amount of the halogen is greater than or equal to about 1 microgram per milligram of quantum dots and less than about 20 micrograms per milligram of quantum dots.
3. The quantum dots of claim 1 , wherein
the quantum dots comprise a core comprising a first semiconductor nanocrystal and a shell disposed on the core, the shell comprising a second semiconductor nanocrystal having a different composition from the first semiconductor nanocrystal, and
the first semiconductor nanocrystal and the second semiconductor nanocrystal independently comprise a Group II-VI compound, a Group III-V compound, or a combination thereof.
4. The quantum dots of claim 3 , wherein the first semiconductor nanocrystal and second semiconductor nanocrystal independently comprise a metal comprising indium, zinc, or a combination thereof, and a non-metal comprising phosphorus, selenium, tellurium, sulfur, or a combination thereof.
5. The quantum dots of claim 1 , wherein the halogen comprises chlorine.
6. The quantum dots of claim 1 , wherein a mole ratio of the halogen relative to the organic ligand is less than about 2.
7. The quantum dots of claim 1 , wherein the organic ligand comprises RCOOH, RNH 2 , R 2 NH, R 3 N, R 3 PO, R 3 P, ROH, RCOOR, RPO(OH) 2 , RHPOOH, R 2 POOH, or a combination thereof, wherein, R is each independently a C3 to C40 substituted or unsubstituted aliphatic hydrocarbon group, a C6 to C40 substituted or unsubstituted aromatic hydrocarbon group, or a combination thereof.
8. The quantum dots of claim 1 , wherein the organic ligand comprises a C6 to C40 aliphatic carboxylic acid compound.
9. The quantum dots of claim 1 , wherein the quantum dots do not comprises butanethiol, pentanethiol, hexanethiol, heptanethiol, octanethiol, nonanethiol, decanethiol, undecanethiol, dodecanethiol, octadecanethiol, 2-(2-methoxyethoxy)ethanethiol, 3-methoxybutyl 3-mercaptopropionate, 3-methoxybutylmercaptoacetate, thioglycolic acid, 3-mercaptopropionic acid, thiopronin, 2-mercaptopropionic acid, a 2-mercaptopropionate ester, 2-mercaptoethanol, cysteamine, 1-thioglycerol, mercaptosuccinic acid, L-cysteine, dihydrolipoic acid, 2-(dimethylamino)ethanethiol, 5-mercaptomethyltetrazole, 2,3-dimercapto-1-propanol, glutathione, methoxypoly(ethylene glycol) thiol, a dialkyldithiocarbamic acid or a metal salt thereof, or a combination thereof.
10. The quantum dots of claim 1 , wherein the quantum dots exhibit a maximum photoluminescence peak in a wavelength range of greater than or equal to about 440 nanometers and less than or equal to about 465 nanometers.
11. The quantum dots of claim 1 , wherein the quantum dots have a quantum efficiency of greater than or equal to about 80 percent.
12. The quantum dots of claim 1 , wherein the quantum dots are dispersible in an organic solvent to form an organic solution, and the organic solvent comprises a substituted or unsubstituted C5 to C40 aliphatic hydrocarbon, a substituted or unsubstituted C6 to C40 aromatic hydrocarbon, a C3 to C40 alicyclic hydrocarbon, or a combination thereof.
13. The quantum dots of claim 1 , wherein the quantum dots have an amount of an organic material of greater than or equal to about 1 weight percent and less than or equal to about 9 weight percent as determined by a thermogravimetric analysis.
14. A method of producing the quantum dots of claim 1 , which comprises:
obtaining an organic dispersion comprising a plurality of quantum dots comprising the organic ligands on a surface of the quantum dots, and a first organic solvent;
obtaining a halide solution comprising a polar organic solvent compatible with the first organic solvent and a metal halide; and
combining the halide solution with the organic dispersion to form a mixture, wherein an amount of the metal halide is greater than or equal to about 0.1 weight percent and less than or equal to about 10 weight percent based on a total weight of the quantum dots, and
stirring the mixture at a temperature of greater than or equal to about 45° C. and less than or equal to about 150° C.
15. The method of claim 14 , wherein the metal halide comprises a zinc halide, an indium halide, a gallium halide, a magnesium halide, a lithium halide, or a combination thereof.
16. The method of claim 14 , wherein the metal halide comprises a metal chloride, or wherein the first organic solvent comprises a substituted or unsubstituted C5 to C40 aliphatic hydrocarbon, a substituted or unsubstituted C6 to C40 aromatic hydrocarbon, a substituted or unsubstituted C3 to C40 alicyclic hydrocarbon, or a combination thereof, and the polar organic solvent comprises a C1 to C10 alcohol, or a combination thereof.
17. A light emitting device, comprising
a first electrode and a second electrode facing each other,
an emission layer disposed between the first electrode and the second electrode,
the emission layer comprising quantum dots,
wherein the quantum dots comprise an organic ligand and a halogen disposed on a surface of the quantum dots, wherein an amount of the organic ligand is less than or equal to about 10 weight percent based on a total weight of the quantum dots, and
the quantum dots do not comprise cadmium, lead, or a combination of thereof.
18. The light emitting device of claim 17 , wherein the quantum dots do not comprise a thiol-containing organic compound or a salt thereof, which is bound to a surface of the quantum dots.
19. The light emitting device of claim 17 , wherein the light emitting device comprises an electron auxiliary layer disposed between the emission layer and the second electrode, and the electron auxiliary layer comprises a nanoparticle comprising a zinc metal oxide represented by Chemical Formula 1:
Zn 1-x M x O Chemical Formula 1
wherein, in Chemical Formula 1,
M is Mg, Ca, Zr, W, Li, Ti, Y, Al, or a combination thereof, and
0≤x≤0.5.
20. The light emitting device of claim 17 , wherein the light emitting device emits blue light and has a maximum luminance of greater than or equal to about 10,000 candela per square meter and T50 of greater than or equal to about 20 hours.