Through hole filling paste
Through hole filling pastes which include a magnetic powder (A), an epoxy resin (B), and a curing agent (C), in which the magnetic powder (A) is surface-treated with a surface treating agent containing at least one element selected from Si, Al, and Ti, are capable of achieving a cured product excellent in plating adhesion.
1. A through hole filling paste, comprising:
(A) at least one magnetic powder;
(B) at least one epoxy resin; and
(C) at least one curing agent,
wherein said at least one magnetic powder (A) is surface treated with a surface treating agent containing at least one element selected from the group consisting of Si, Al, and Ti.
2. The through hole filling paste according to claim 1 , wherein said surface treatment agent is at least one member selected from the group consisting of an alkoxy silane, a silane-based coupling agent, an aluminate-based coupling agent, and a titanate-based coupling agent.
3. The through hole filling paste according to claim 1 , wherein said at least one magnetic powder (A) is at least one member selected from the group consisting of an iron oxide powder and an iron alloy-based metal powder.
4. The through hole filling paste according to claim 1 , wherein said at least one magnetic powder (A) has an average particle diameter of 0.01 μm to 10 μm.
5. The through hole filling paste according to claim 1 , wherein said at least one magnetic powder (A) has an aspect ratio of 2 or less.
6. The through hole filling paste according to claim 1 , wherein said at least one magnetic powder (A) is present in an amount of 70% by mass to 98% by mass, based on 100% by mass of non-volatile components in the through hole filling paste.
7. The through hole filling paste according to claim 1 , wherein said at least one magnetic powder (A) is an iron oxide powder, said iron oxide powder being ferrite containing at least one metal selected from the group consisting of Ni, Cu, Mn, and Zn.
8. The through hole filling paste according to claim 1 , wherein said at least one magnetic powder (A) is an iron alloy-based metal powder containing at least one metal selected from the group consisting of Si, Cr, Al, Ni, and Co.
9. The through hole filling paste according to claim 1 , wherein said at least one epoxy resin (B) comprises an epoxy resin that remains liquid at 25° C.
10. The through hole filling paste according to claim 1 , wherein said at least one curing agent (C) is at least one member selected from the group consisting of an acid anhydride-based epoxy resin curing agent, an amine-based curing accelerator, and an imidazole-based curing accelerator.
11. A circuit board, comprising a substrate in which a through hole is filled with a cured product of a through hole filling paste according to claim 1 .
12. An inductor component, comprising a circuit board according to claim 11 .
13. A method for producing a circuit board, said method comprising:
(1) filling a through hole with a through hole filling paste and thermally curing said through hole filling paste to obtain a cured product;
(2) polishing a surface of said cured product, to obtain a polished surface; and
(3) forming a conductive layer on said polished surface of said cured product,
in an order of the step (1), the step (2), and the step (3), wherein
said through hole filling paste comprises:
(A) at least one magnetic powder;
(B) at least one epoxy resin; and
(C) at least one curing agent (C),
wherein said at least one magnetic powder (A) is surface-treated with a surface treating agent containing at least one element selected from the group consisting of Si, Al, and Ti.
14. The method according to claim 13 , wherein said surface treatment agent is at least one member selected from the group consisting of an alkoxy silane, a silane-based coupling agent, an aluminate-based coupling agent, and a titanate-based coupling agent.
15. The method according to claim 13 , which does not include roughening said polished surface of said cured product after step (2) and before step (3).