Structure comprising a reflective layer having lines formed by bright portions and dark portions derived from a cholesteric liquid crystalline phase and method for forming the reflective layer
An object of the present invention is to provide a structure having a reflective layer that has satisfactory transparency and diffuse reflectivity and is also capable of reducing the occurrence of glare, and a method for forming the reflective layer. The object of the present invention is achieved by a structure including a substrate and a reflective layer formed by immobilizing a cholesteric liquid crystalline phase, in which, upon observing a cross section of the reflective layer by a scanning electron microscope, lines formed by bright portions and lines formed by dark portions derived from the cholesteric liquid crystalline phase have a wave-like structure or are inclined with respect to the surface of the substrate, and at least a part of the lines formed by the bright portions and the lines formed by the dark portions are discontinuous.
1. A structure comprising:
a substrate; and
a reflective layer formed by immobilizing a cholesteric liquid crystalline phase,
wherein, upon observing a cross section of the reflective layer in a thickness direction by a scanning electron microscope, lines formed by bright portions and lines formed by dark portions derived from the cholesteric liquid crystalline phase have a wave-like structure or are inclined with respect to a surface of the substrate,
at least a part of the lines formed by the bright portions and the lines formed by the dark portions are discontinuous, and
the number of a portion where the lines formed by the dark portions are discontinuous is 0.05 or more per 1 μm 2 of the cross section of the reflective layer.
2. The structure according to claim 1 ,
wherein the lines formed by the bright portions and the lines formed by the dark portions derived from the cholesteric liquid crystalline phase have a periodic wave-like structure or are inclined with respect to the surface of the substrate and have a periodic structure in which lines formed by linear bright portions and lines formed by linear dark portions are alternately formed.
3. The structure according to claim 1 ,
wherein an alignment defect of the cholesteric liquid crystalline phase is included in a portion where the lines formed by the bright portions and the lines formed by the dark portions are discontinuous.
4. The structure according to claim 1 ,
wherein a particle is present in a portion where the lines formed by the bright portions and the lines formed by the dark portions are discontinuous.
5. The structure according to claim 1 ,
wherein the lines formed by the bright portions and the lines formed by the dark portions have a wave-like structure, and a wave period of the wave-like structure is 0.3 to 10 μm.
6. A method for forming a reflective layer, comprising:
applying a composition containing a liquid crystal compound and a chiral agent onto a surface of a substrate without subjecting the surface of the substrate to an alignment treatment, and curing the composition,
in a case of forming a reflective layer, which is formed by immobilizing a cholesteric liquid crystalline phase, on the surface of the substrate,
wherein, upon observing a cross section of the reflective layer in a thickness direction by a scanning electron microscope, lines formed by bright portions and lines formed by dark portions derived from the cholesteric liquid crystalline phase have a wave-like structure or are inclined with respect to the surface of the substrate, at least a part of the lines formed by the bright portions and the lines formed by the dark portions are discontinuous, and the number of a portion where the lines formed by the dark portions are discontinuous is 0.05 or more per 1 μm 2 of the cross section of the reflective layer.
7. The method for forming a reflective layer according to claim 6 ,
wherein, after applying the composition onto the surface of the substrate, the composition is heated to bring the liquid crystal compound into a cholesteric liquid crystalline phase state, and then the composition is cooled or heated.
8. A method for forming a reflective layer, comprising:
applying a composition containing a liquid crystal compound, a chiral agent, and a vertical alignment agent onto a surface of a substrate, and curing the composition,
in a case of forming a reflective layer, which is formed by immobilizing a cholesteric liquid crystalline phase, on the surface of the substrate,
wherein, upon observing a cross section of the reflective layer in a thickness direction by a scanning electron microscope, lines formed by bright portions and lines formed by dark portions derived from the cholesteric liquid crystalline phase have a wave-like structure or are inclined with respect to the surface of the substrate, at least a part of the lines formed by the bright portions and the lines formed by the dark portions are discontinuous, and the number of a portion where the lines formed by the dark portions are discontinuous is 0.05 or more per 1 μm 2 of the cross section of the reflective layer.
9. The method for forming a reflective layer according to claim 8 ,
wherein, after applying the composition onto the surface of the substrate, the composition is heated to bring the liquid crystal compound into a cholesteric liquid crystalline phase state, and then the composition is cooled or heated.
10. A method for forming a reflective layer, comprising:
applying a composition containing a liquid crystal compound, a chiral agent, and a particle onto a surface of a substrate, and curing the composition,
in a case of forming a reflective layer, which is formed by immobilizing a cholesteric liquid crystalline phase, on the surface of the substrate,
wherein, upon observing a cross section of the reflective layer in a thickness direction by a scanning electron microscope, lines formed by bright portions and lines formed by dark portions derived from the cholesteric liquid crystalline phase have a wave-like structure or are inclined with respect to the surface of the substrate, at least a part of the lines formed by the bright portions and the lines formed by the dark portions are discontinuous, and the number of a portion where the lines formed by the dark portions are discontinuous is 0.05 or more per 1 μm 2 of the cross section of the reflective layer.
11. The method for forming a reflective layer according to claim 10 ,
wherein, after applying the composition onto the surface of the substrate, the composition is heated to bring the liquid crystal compound into a cholesteric liquid crystalline phase state, and then the composition is cooled or heated.
12. A structure comprising:
a substrate; and
a reflective layer formed by immobilizing a cholesteric liquid crystalline phase,
wherein, upon observing a cross section of the reflective layer in a thickness direction by a scanning electron microscope, lines formed by bright portions and lines formed by dark portions derived from the cholesteric liquid crystalline phase have a wave-like structure or are inclined with respect to a surface of the substrate,
at least a part of the lines formed by the bright portions and the lines formed by the dark portions are discontinuous, and
the lines formed by the bright portions and the lines formed by the dark portions have a wave-like structure, and a wave period of the wave-like structure is 0.3 to 10 μm.