Methane ethane crackers
A process for producing olefins by cracking paraffins in the presence of methane. In the conventional steam cracking processes for olefin production, steam is used as a diluent in the feed mixture to the thermal cracker. In the processes provided herein, methane replaces steam as a diluent in the feed mixture to the thermal cracker. Replacing steam with methane as a diluent has a potential for cost savings in the construction and operation of a thermal cracking plant for olefin production. In addition, it leads to a much simpler cracking process compared to the conventional steam cracking technology as in the state of the art.
1. A process for converting paraffins to olefins, comprising:
obtaining a feed stream comprising naturally occurring methane and one or more paraffins, wherein the feed stream comprises 30 mol % to about 95 mol % of the naturally occurring methane;
passing the feed stream containing the naturally occurring methane and one or more paraffins to a cracker;
converting at least a portion of the one or more paraffins to one or more olefins within the cracker in the presence of the naturally occurring methane to provide a product stream comprising the one or more olefins.
2. The process of claim 1 , further comprising removing sour gas from the feed stream prior to passing the feed stream to the cracker, wherein the feed stream after sour gas removal comprises the same naturally occurring methane and same one or more paraffins as the feed stream prior to the sour gas removal.
3. The process of claim 1 , wherein the naturally occurring methane and one or more paraffins are derived directly from a wellhead, reservoir, or pipeline.
4. The process of claim 1 , wherein the cracker operates at a temperature of 500° C. to about 1,000° C., and a pressure of about 1 atm to about 30 atm.
5. The process of claim 1 , wherein the one or more paraffins are converted to one or more olefins in the presence of a catalyst.
6. The process of claim 1 , further comprising separating at least a portion of the naturally occurring methane from the feed stream prior to passing the feed stream to the cracker to adjust the amount of the naturally occurring methane in the feed stream entering into the cracker.
7. The process of claim 1 , further comprising separating at least a portion of the methane from the product stream and recycling the separated methane to the feed stream prior to passing the feed stream to the cracker.
8. The process of claim 1 , wherein the one or more paraffins are converted to one or more olefins in the absence of catalyst.
9. The process of claim 1 , wherein the cracker contains a catalyst bed.
10. The process of claim 9 , wherein the catalyst bed is a fixed bed, fluidized bed or moving bed.
11. The process of claim 1 , wherein the feed stream further comprises less than 15 mol % of one or more non-paraffinic hydrocarbons and/or non-hydrocarbons.
12. The process of claim 11 , wherein the non-hydrocarbons comprise nitrogen, helium, steam, or a mixture thereof, and wherein the one or more paraffins comprise ethane, propane, butane, pentane, naphtha or any combinations thereof.
13. The process of claim 1 , wherein the methane concentration in the feed stream is about 30 mol % to about 90 mol %.
14. The process of claim 1 , wherein methane concentration in the feed stream is about 50 mol % to about 90 mol %.
15. The process of claim 1 , wherein the feed stream and cracker have no added steam.
16. A process for converting paraffins to olefins, comprising:
obtaining a feed stream comprising naturally occurring methane and one or more paraffins, wherein the feed stream comprises 30 mol % to about 95 mol % of the naturally occurring methane;
removing sour gas from the feed stream, wherein the feed stream after sour gas removal comprises the same naturally occurring methane and same one or more paraffins as the feed stream prior to the sour gas removal;
passing the feed stream containing naturally occurring methane and one or more paraffins to a cracker, wherein the feed stream comprises 30 mol % to about 95 mol % of the naturally occurring methane and less than 5 mol % steam;
converting at least a portion of the one or more paraffins to one or more olefins within the cracker to provide a product stream comprising the one or more olefins.
17. The process of claim 16 , wherein the cracker operates at a temperature of 500° C. to about 1,000° C., and a pressure of about 1 atm to about 30 atm.
18. The process of claim 16 , wherein the residence time through the tubes is between 0.001 to 10 seconds.
19. The process of claim 16 , further comprising separating at least a portion of the naturally occurring methane from the feed stream prior to passing the feed stream to the cracker.
20. The process of claim 19 , further comprising separating methane from the product stream and recycling at least a portion of the separated methane to the feed stream prior to passing the feed stream to the cracker.