IP Library Granted Patent US 11,268,188
Granted Patent B2
US 11,268,188 · App. 16/519,288 · Granted Mar 8, 2022

Aluminum physical vapor deposition for the cosmetic finishing of recycled aluminum alloys

Inventors: Brian S. Tryon (Redwood City, CA); Alexander W. Williams (Santa Clara, CA); James A. Curran (Morgan Hill, CA); Sonja R. Postak (Sunnyvale, CA)
Assignee: Apple Inc.
C23C14/5853B32B15/043B32B15/20C23C14/18C23C14/20B32B18/00B32B2255/06B32B2255/205C23C14/0015C23C14/06C23C14/08C23C14/083C23C14/14C23C28/00C23C28/3455
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Quick Facts
Patent No.
US 11,268,188
App. No.
16/519,288
Granted
Mar 8, 2022
Kind
B2
Abstract

A method of forming a surface coating on a component of an electronic device can include depositing an aluminum layer including at least about 0.05 weight percent (wt %) of a grain refiner on a surface of the component by a physical vapor deposition process, and anodizing the aluminum layer to form an anodized aluminum oxide layer having a L* value greater than about 85 in the CIELAB color space.

Claims (23)

1. A component for an electronic device, comprising:

a substrate material defining a surface;

an anodized aluminum oxide layer formed over the surface, the anodized aluminum oxide layer having a thickness greater than about 4 microns and an L* value in a CIELAB color space of greater than about 85; and

a continuous stop layer disposed between the substrate material and the anodized aluminum oxide layer.

2. The component of claim 1 , wherein the substrate material is a first material and the anodized aluminum oxide layer is formed from a second material different than the first material.

3. The component of claim 2 , wherein the first material comprises an aluminum alloy.

4. The component of claim 1

wherein the continuous stop layer comprises a thickness of less than about 1 micron;

the continuous stop layer including titanium, platinum group metals, or a conductive oxide material.

5. The component of claim 1 , further comprising:

an aluminum layer disposed between the anodized aluminum oxide layer and the substrate, the aluminum layer having a thickness of less than about 100 microns and including at least about 0.05 weight percent (wt %) of a grain refiner;

wherein the anodized aluminum oxide layer is formed from the aluminum layer.

6. The component of claim 1 , wherein the anodized aluminum oxide layer has a b* value in the CIELAB color space of between about −0.04 and about 0.4.

7. The component of claim 1 , wherein the surface comprises a three-dimensional surface.

8. The component of claim 1 , wherein the anodized aluminum oxide layer comprises a thickness of less than about 200 microns.

9. A coating formed on a substrate material, comprising:

an aluminum layer having grains with a major surface dimension greater than 1 micron and grains with a major surface dimension less than 1 micron, wherein a surface area ratio of grains with a major surface dimension greater than 1 micron to grains with a major surface dimension less than 1 micron, wherein the surface area ratio is less than about 0.1;

the aluminum layer having a thickness greater than about 2 microns.

10. The coating of claim 9 , wherein the thickness of the aluminum layer is less than about 100 microns.

11. The coating of claim 9 , wherein the surface area ratio is less than about 0.07.

12. The coating of claim 9 , wherein the surface area ratio is less than about 0.05.

13. The coating of claim 9 , wherein the aluminum layer comprises greater than about 0.05 weight percent (wt %) of a grain refiner.

14. The coating of claim 13 , wherein the grain refiner comprises at least one of zirconium, scandium, silicon, or silver.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 23, 2019
From: TRYON, BRIAN S.; WILLIAMS, ALEXANDER W.; CURRAN, JAMES A.; POSTAK, SONJA R.
To: APPLE INC.
Reel/Frame 049832/0099 →
Continuity (2)
Provisional Application 62842341 · May 2, 2019
Related Publication 20200347492A1 · Nov 5, 2020