Negative active material for rechargeable lithium battery, method for preparing same, negative electrode including the same and rechargeable lithium battery including same

1. A negative active material for a rechargeable lithium battery, comprising: natural graphite comprising a plurality of primary particles assembled into a spheroidal secondary particle; and amorphous carbon, a first portion of the amorphous carbon being on a surface of the plurality of primary particles, internal to the secondary particle and a second portion of the amorphous carbon comprised within a coating layer surrounding the secondary particle, the plurality of primary particles having an average particle diameter of about 5 μm to about 15 μm, the secondary particle having an average particle diameter of about 8 μm to about 24 μm, and a peak intensity ratio, I(002)/I(110), of the negative active material being less than or equal to about 120, as measured by X-ray diffraction, wherein the negative active material has a pore volume fraction of less than or equal to about 2%, and wherein the negative active material has a tap density of about 0.7 g/cc to about 1.3 g/cc.

2. The negative active material of claim 1 , wherein the natural graphite is flake-shaped natural graphite.

3. The negative active material of claim 1 , wherein the negative active material has a pore volume fraction of about 1.0% to about 1.5%.

4. The negative active material of claim 1 , wherein the coating layer has a thickness of about 5 nm to about 50 nm.

5. The negative active material of claim 1 , wherein the negative active material has a specific surface area (BET) of less than or equal to about 10 m 2 /g.

6. The negative active material of claim 1 , wherein the negative active material comprises the natural graphite and the amorphous carbon in a weight ratio of about 90:10 to about 75:25.

7. The negative active material of claim 1 , wherein the amorphous carbon is one selected from soft carbons, hard carbons, mesophase pitch carbonized products, fired cokes, and mixtures thereof.

8. A method of preparing the negative active material of claim 1 , the method comprising:

pulverizing natural graphite raw materials into the plurality of primary particles;

assembling the plurality of primary particles into the spheroidal secondary particle;

adding an amorphous carbon precursor to the secondary particle to prepare a mixture; and

heat-treating the mixture to prepare the negative active material.

9. The method of claim 8 , wherein:

the natural graphite raw materials have an average particle diameter of about 80 μm to about 140 μm,

the primary particles have an average particle diameter of about 5 μm to about 15 μm, and

the secondary particle having an average particle diameter of about 8 μm to about 24 μm.

10. The method of claim 8 , wherein the negative active material comprises the natural graphite and the amorphous carbon in a weight ratio of about 90:10 to about 75:25.

11. The method of claim 8 , wherein the amorphous carbon precursor is one selected from phenolic resins, furan resins, epoxy resins, polyacrylonitriles, polyimide resins, polyimide resins, polyamideimide resins, synthetic pitches, petroleum-based pitches, coal-based pitches, tars, pitch carbon and combinations thereof.

12. The method of claim 8 , wherein the heat-treating is performed by maintaining the mixture in a furnace of about 1,000° C. to about 2,000° C. for about 1 hour to about 5 hours.

13. A negative electrode comprising the negative active material of claim 1 .

14. A rechargeable lithium battery comprising:

the negative electrode of claim 13 ;

a positive electrode comprising a positive active material; and

an electrolyte with the negative electrode and the positive electrode.

15. The negative active material of claim 1 , wherein the plurality of primary particles have an average particle diameter of about 5.5 μm to about 15 μm.