IP Library › Granted Patent US 11,292,742
Granted Patent B2
US 11,292,742 · App. 16/452,835 · Granted Apr 5, 2022

High alumina low soda glass compositions

Inventors: John Rich (Allison Park, PA); Alan Miller (Gibsonia, PA); José Guadalupe Cid-Aguilar (Nuevo Leon, MX)
Assignee: Vitro Flat Glass LLC
C03C3/087C03C3/078C03C4/085C03C2203/10
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Quick Facts
Patent No.
US 11,292,742
App. No.
16/452,835
Granted
Apr 5, 2022
Kind
B2
Abstract

A glass composition includes a base glass portion comprising: 65-75 wt % SiO 2 ; 5-15 wt % CaO; 0-5 wt % MgO; 0-5 wt % K 2 O; 10-14 wt % Na 2 O; and 1-5 wt % Al 2 O 3 ; wherein the glass composition has a ratio of Na 2 O to Al 2 O 3 is in the range of 9.5-12.5 wt %/wt %.

Claims (45)

1. A glass composition comprising a base glass portion comprising:

65-75 wt % SiO 2 ;

5-15 wt % CaO;

0-5 wt % MgO;

0.1-0.5 wt % K 2 O;

10-14 wt % Na 2 O; and

1-1.47 wt % Al 2 O 3 ;

wherein the glass composition has a weight ratio of Na 2 O to Al 2 O 3 is in the range of 9.5-12.

2. The glass composition of claim 1 , wherein the base glass portion has a weight ratio of CaO to MgO in the range of 1.5-2.2.

3. The glass composition of claim 1 , wherein the base glass portion comprises 0.2-0.4 wt % K 2 O.

4. The glass composition of claim 1 , wherein the base glass portion comprises:

68-74 wt % SiO 2 ;

13-13.5 wt % Na 2 O;

1-1.4 wt % Al 2 O 3 ;

8.1-8.6 wt % CaO; and

4.5-5 wt % MgO.

5. The glass composition of claim 1 , wherein the total iron in the glass composition is in the range of 0.01 to 0.30 wt %.

6. The glass composition of claim 1 , further comprising a colorant portion, the colorant portion comprising:

CoO in an amount ranging from 30 to 120 ppm; or

Se in an amount no greater than 7.5 ppm.

7. The glass composition of claim 1 , wherein the glass composition, when formed as a glass sheet, has a color described by the following chromaticity coordinates: an a* ranging from −4 to +4 and a b* ranging from 0 to −20.

8. The glass composition of claim 1 , wherein the glass composition, when formed as a glass sheet, has a visible light transmittance of no greater than 80%.

9. The glass composition of claim 1 , wherein the total iron in the glass composition is in the range of 0.2 to 0.8 wt %.

10. The glass composition of claim 1 , wherein the glass composition has a redox ratio in the range of 0.4-0.6.

11. The glass composition of claim 1 , further comprising a colorant portion comprising: CoO in an amount no greater than 20 ppm; or Se in an amount no greater than 3 ppm.

12. The glass composition of claim 1 , wherein the glass composition, when formed as a glass sheet, has a color described by the following chromaticity coordinates: an a* ranging from −8 to −16 and a b* ranging from +3 to −17.

13. The glass composition of claim 1 , further comprising a colorant portion comprising at least one of the following: oxides of manganese, tin, cerium, molybdenum, vanadium, copper, zinc, tungsten, and lanthanum, or any combination thereof.

14. The glass composition of claim 1 further comprising 0.16-0.18 wt. % Fe 2 O 3 .

15. The glass composition of claim 1 further comprising 0.49-0.58 wt. % Fe 2 O 3 .

16. A glass composition comprising a base glass portion comprising:

SiO 2 71.2-71.6 wt. %;

CaO 8.3-8.6 wt. %;

MgO 5.0-5.2 wt. %;

K 2 O 0.24-0.25 wt. %;

Na 2 O 13.4-13.5 wt. %; and

Al 2 O 3 1.1-1.2 wt. %.

17. The glass composition of claim 16 further comprising 0.20-0.21 wt. % Fe 2 O 3 .

18. The glass composition of claim 16 wherein the weight ratio of Na 2 O to Al 2 O 3 is 11.1 to 11.3.

19. The glass composition of claim 16 wherein the weight ratio of CaO to MgO is 1.7 to 1.9.

20. A glass composition comprising a base glass portion comprising:

65-75 wt % SiO 2 ;

5-15 wt % CaO;

0-5 wt % MgO;

0.1-0.5 wt % K 2 O; and,

wherein the glass composition comprises an amount of Na 2 O to Al 2 O 3 in a weight ratio in the range of 9.5-12.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 28, 2022
From: CID-AGUILAR, JOSÉ GUADALUPE
To: VITRO FLAT GLASS LLC
Reel/Frame 059763/0727 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 1, 2021
From: CID-AGUILAR, JOSÉ GUADALUPE
To: VITRO FLAT GLASS LLC
Reel/Frame 057358/0517 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 17, 2019
From: RICH, JOHN; MILLER, ALAN
To: VITRO FLAT GLASS LLC
Reel/Frame 051300/0339 →
Continuity (2)
Provisional Application 62690663 · Jun 27, 2018
Related Publication 20200002216A1 · Jan 2, 2020
Cited By (1)
US 12,590,393