Thermally responsive anti-sag agents
Methods for the use of treatment fluids that include thermally responsive anti-sag agents in subterranean formations are provided. In one embodiment, the methods include introducing a treatment fluid including a base fluid and an anti-sag agent including a thermally responsive hydrogel that includes at least one thermoresponsive polymer into at least a portion of a subterranean formation.
1. A method comprising: introducing a treatment fluid comprising a base fluid and an anti-sag agent comprising a thermally responsive hydrogel that comprises at least one thermoresponsive polymer into at least a portion of a subterranean formation, wherein the anti-sag agent undergoes a thickening transition without a surfactant present in the treatment fluid, and generates a number of solid, neutral density particles, wherein the treatment fluid remains pumpable.
2. The method of claim 1 , wherein the base fluid comprises at least one component selected from the group consisting of: water, salt water, brine, seawater, a gas, a liquid hydrocarbon, an oil-water mixed production fluid, a natural oil based mud, a synthetic based mud, a natural base oil, a synthetic base oil, an invert emulsion, and any combination thereof.
3. The method of claim 1 , wherein the thermally responsive hydrogel is present in the treatment fluid in an amount from about 1% to about 20% by weight of the treatment fluid.
4. The method of claim 1 , further comprising forming a solid thermally responsive hydrogel at about, or above, a thickening transition temperature.
5. The method of claim 4 , wherein the solid thermally responsive hydrogel is present in the treatment fluid in an amount from about 0.01 to about 0.2 by volume fraction of solids of the treatment fluid.
6. The method of claim 1 , further comprising chilling the treatment fluid prior to introducing the treatment fluid into the at least a portion of the subterranean formation.
7. The method of claim 1 further comprising circulating the treatment fluid through a wellbore while drilling into the subterranean formation.
8. The method of claim 1 , wherein the thermally responsive hydrogel comprises a hydrogel selected from the group consisting of: a multipolymer interpenetrating polymeric hydrogel, a semi-interpenetrating polymer hydrogel, and any combination thereof.
9. The method of claim 1 , wherein the at least one thermoresponsive polymer comprises at least one monomer selected from the group consisting of: N-isopropylacrylamide, hydroxyethyl methacrylate, acrylamide, N,N-diethylacrylamide, N-ethylacrylamide, N-methylacrylamide, N-n-butylacrylamide, N-tert-butylacrylamide, butyl acrylate, ethyl acrylate, propyl acrylate, methacrylamide, a methacrylate, methyl vinyl ether, N-vinyl-caprolactam, polypeptides, ethylene oxide, propylene oxide, chitosan, any salt thereof, and any combination thereof.
10. The method of claim 1 , wherein the at least one thermoresponsive polymer undergoes the thickening transition at a thickening transition temperature of from about 30° C. to about 210° C.
11. A method of drilling a wellbore in a subterranean formation, the method comprising: using a drilling fluid comprising a base fluid and an anti-sag agent comprising a thermally responsive hydrogel that comprises at least one thermoresponsive polymer to drill at least a portion of a wellbore in the subterranean formation, wherein the anti-sag agent undergoes a thickening transition without a surfactant present in the treatment fluid, and generates a number of solid, neutral density particles, wherein the treatment fluid remains pumpable.
12. The method of claim 11 , wherein the base fluid comprises at least one component selected from the group consisting of: water, salt water, brine, seawater, a gas, a liquid hydrocarbon, an oil-water mixed production fluid, a natural oil based mud, a synthetic based mud, a natural base oil, a synthetic base oil, an invert emulsion, and any combination thereof.
13. The method of claim 11 , wherein the thermally responsive hydrogel is present in the drilling fluid in an amount from about 1% to about 20% by weight of the drilling fluid.
14. The method of claim 11 , further comprising forming a solid thermally responsive hydrogel at about, or above, a thickening transition temperature.
15. The method of claim 14 , wherein the solid thermally responsive hydrogel is present in the drilling fluid in an amount from about 0.01 to about 0.2 by volume fraction of solids of the drilling fluid.
16. The method of claim 11 , wherein the at least one thermoresponsive polymer comprises at least one monomer selected from the group consisting of: N-isopropylacrylamide, hydroxyethyl methacrylate, acrylamide, N,N-diethylacrylamide, N-ethylacrylamide, N-methylacrylamide, N-n-butylacrylamide, N-tert-butylacrylamide, butyl acrylate, ethyl acrylate, propyl acrylate, methacrylamide, a methacrylate, methyl vinyl ether, N-vinyl-caprolactam, polypeptides, ethylene oxide, propylene oxide, chitosan, any salt thereof, and any combination thereof.
17. A method comprising: introducing a treatment fluid comprising a base fluid and an anti-sag agent comprising a thermally responsive hydrogel that comprises at least one thermoresponsive polymer into at least a portion of a subterranean formation; and allowing the at least one thermoresponsive polymer to undergo an at least partially reversible thickening transition at about, or above, a thickening transition temperature, wherein the anti-sag agent undergoes a thickening transition without a surfactant present in the treatment fluid, and generates a number of solid, neutral density particles, wherein the treatment fluid remains pumpable.
18. The method of claim 17 , wherein the thickening transition temperature is from about 30° C. to about 210° C.
19. The method of claim 17 , wherein the thermally responsive hydrogel is present in the treatment fluid in an amount from about 1% to about 20% by weight of the treatment fluid.
20. The method of claim 17 , wherein the at least one thermoresponsive polymer comprises at least one monomer selected from the group consisting of: N-isopropylacrylamide, hydroxyethyl methacrylate, acrylamide, N,N-diethylacrylamide, N-ethylacrylamide, N-methylacrylamide, N-n-butylacrylamide, N-tert-butylacrylamide, butyl acrylate, ethyl acrylate, propyl acrylate, methacrylamide, a methacrylate, methyl vinyl ether, N-vinyl-caprolactam, polypeptides, ethylene oxide, propylene oxide, chitosan, any salt thereof, and any combination thereof.