Rotaxane polymer binder for lithium secondary battery, electrode comprising same, and secondary battery comprising same
The present disclosure provides a rotaxane polymer binder containing a polymer based on a rotaxane structure. The polymer binder may further contain a polymer cross-linked with a polar polymer. The polar polymer may be a polymer containing the element F, O or N in a functional group and having high polarity. In addition, the present disclosure provides an electrode containing the rotaxane polymer binder as a binder for a lithium secondary battery, and a secondary battery containing the electrode.
1. A polymer binder comprising:
a polymer based on a rotaxane structure comprising a ring molecule as a host molecule, a string polymer as a guest molecule, and a stopper molecule at each end of the string polymer for preventing dissociation of the ring molecule from the string polymer,
wherein the ring molecule consists of cyclodextrin covalently cross-linked to a polyacrylic acid binder for acting as a molecule moving pulley.
2. The polymer binder according to claim 1 , wherein the rotaxane is a supramolecular structure comprising:
the ring molecule;
the string polymer, wherein the string polymer is a linear-type, branched-type, graft-type, dendrimer-type, or network-type polymer, and comprises at least one selected from the group consisting of an ether (—O—), a hydrocarbon (—CH 2 —), an aromatic (—C 6 H 4 —), and a siloxane (—Si—O—); or is a conductive polymer selected from polyaniline (—C 6 H 4 N—) or poly-3,4-ethylenedioxythiophene (PEDOT); and
the stopper, wherein the stopper is any molecule whose diameter is larger than an inner diameter of the ring molecule.
3. An electrode comprising:
the polymer binder according to claim 1 ; and
one or more of active material selected from the group consisting of a silicon-containing composite, a tin-containing composite, a germanium-containing composite, a phosphorus-containing composite, a lead-containing composite, a sulfur-containing composite, a zinc-containing composite, an arsenic-containing composite, a carbon-based material, a silicon oxide-based molecule (SiO x , 0<x<2), a metal oxide-based molecule, a metal sulfide-based molecule and a lithium metal oxide-based molecule.
4. The electrode according to claim 3 , wherein each of the composite comprises one or more active elements.
5. The electrode according to claim 3 , wherein the carbon-based material is selected from the group consisting of graphite, graphene, acetylene carbon, carbon nanotube, hard carbon and amorphous carbon.
6. The electrode according to claim 3 , wherein the active material is selected from the group consisting of the silicon oxide-based molecule, the metal oxide-based molecule, the metal sulfide-based molecule and the lithium metal oxide-based molecule.
7. The electrode according to claim 3 , the metal oxide-based molecule is selected from the group consisting of TiO 2 , WO 2 , FeO 2 , Fe 2 O 3 , CoO 2 , NiO, CuO, Cr 2 O 3 , MoO 2 , MoO 3 , Mn 3 O 4 , SnO, SnO 2 , ZnO, In 2 O 3 and Ag 2 O.
8. The electrode according to claim 3 , the lithium metal oxide-based molecule is selected from the group consisting of lithium manganese oxide, lithium cobalt oxide, lithium nickel manganese cobalt oxide, lithium nickel cobalt aluminum oxide and lithium titanium oxide.
9. The electrode according to claim 3 , the metal sulfide-based molecule is selected from the group consisting of TiS 2 and MoS 2 .
10. The electrode according to claim 3 , wherein a weight ratio of the polymer binder:the active material is 1:1 to 1000.
11. The electrode according to claim 3 , wherein the active material has a particle size of 0.001 μm to 100 μm.
12. A lithium secondary battery comprising a lithium metal oxide-based molecule in the electrode according to claim 3 .