Lithium secondary battery negative electrode including protection layer made of conductive fabric, and lithium secondary battery including same
A negative electrode for a lithium secondary battery including a protective layer formed with a conductive fabric, in particular, to a negative electrode for a lithium secondary battery including a conductive fabric formed on at least one surface of the lithium metal layer and having pores, and a lithium secondary battery including the same. The lithium secondary battery including a negative electrode having the conductive fabric as a protective layer that induces uniform reactions within the pores, thus preventing local lithium metal formation on the lithium metal surface, and thereby suppressing dendrite formation on the lithium metal surface, and thereby suppressing dendrite formation and cell volume expansion. In addition thereto, mechanical stability can be maintained even when lithium plating and stripping occurs due to the flexibility and tension/contraction of the conductive fabric.
1. A negative electrode for a lithium secondary battery comprising:
a lithium metal layer;
a protective layer present directly on a first surface of the lithium metal layer; and
a negative electrode current collector present on a second surface of the lithium metal layer opposite the first surface,
wherein the protective layer comprises a conductive fabric with pores formed therein, said conductive fabric comprising a thread-weaved base fabric having a metal material coating on an outer surface of the thread, and a carbon material coating on an outer surface of the metal material coating,
wherein the metal material is one or more selected from the group consisting of nickel (Ni), copper (Cu), aluminum (Al), gold (Au), silver (Ag), zinc (Zn) and tin (Sn), and
wherein the metal material is coated in 30 parts by weight to 70 parts by weight with respect to 100 parts by weight of the base fabric.
2. The negative electrode for a lithium secondary battery of claim 1 , wherein the conductive fabric has a pore size of 1 μm to 10,000 μm.
3. The negative electrode for a lithium secondary battery of claim 1 , wherein the conductive fabric has a porosity of 5% to 50%.
4. The negative electrode for a lithium secondary battery of claim 1 , wherein the conductive fabric has a thickness of 0.01 μm to 50 μm.
5. The negative electrode for a lithium secondary battery of claim 1 , wherein the conductive fabric has a sheet resistance of 0.001 ohmn/sq to 1 ohmn/sq.
6. The negative electrode for a lithium secondary battery of claim 1 , wherein the thread is one or more selected from the group consisting of polyester, polyamide, polyethylene, polyurethane, polypropylene, polyurea, cotton, wool, silk and linen.
7. The negative electrode for a lithium secondary battery of claim 1 , wherein the carbon material is one or more selected from the group consisting of graphite-based material; active carbon-based material; carbon black-based material; carbon nanostructure-based material; and combinations thereof.
8. The negative electrode for a lithium secondary battery of claim 1 , wherein the carbon material is coated in 20 parts by weight to 50 parts by weight with respect to 100 parts by weight of the base fabric.
9. A lithium secondary battery comprising:
a negative electrode;
a positive electrode; and
an electrolyte provided therebetween,
wherein the negative electrode is the negative electrode of claim 1 .
10. The negative electrode for a lithium secondary battery of claim 7 ,
wherein the graphite-based material is natural graphite, artificial graphite, expanded graphite, graphene, Super-P or Super-C,
wherein the carbon black-based material is denka black, ketjen black, channel black, furnace black, thermal black, contact black, lamp black or acetylene black, and
wherein the carbon nanostructure-based material is carbon fiber-based, carbon nanotubes (CNT) or fullerene.
11. The negative electrode for a lithium secondary battery of claim 1 , wherein the conductive fabric further comprises
a metal material coating on an outer surface of the thread, and space between the threads is continuously coated or filled with a carbon material.