Nickel catalyst for dry and low temperature steam reforming of methane
This invention relates to a novel nickel catalyst and a novel one-pot solution combustion synthesis of that catalyst for the CO 2 reforming and low temperature steam reformation of methane. The novel nickel catalyst has exceptional activity for dry reforming and steam reforming of methane, and exhibits excellent resilience to deactivation due to carbon formation.
1. A catalyst composition comprising:
a nickel species, and
alumina,
wherein
the catalyst composition is in form of nanoparticulates,
the nickel species comprises NiAl 2 O 4 with Ni, NiO, or a combination of Ni and NiO; wherein the NiAl 2 O 4 is about 70 wt % to about 90 wt % of the nickel species;
the nickel species is dispersed on the surface and in the bulk of the alumina, wherein the nickel species has a higher concentration on the surface of the alumina than in the bulk of the alumina;
wherein the NiAl 2 O 4 is particles of a size from 10 nm to 15 nm;
wherein the NiO is particles of a size from about 15 nm to about 21 nm;
wherein the alumina is nonhierarchical particles of a size from about 18 nm to about 25 nm;
wherein the catalyst composition has a BET surface area of at least 70 m 2 /g;
wherein the nickel species present in the catalyst composition is about 5 wt % to about 10 wt %, of the catalyst composition; and
wherein the catalyst composition is prepared by a solution combustion synthesis (SCS).
2. The catalyst composition of claim 1 , wherein the catalyst composition has a BET surface area of at least 88 m 2 /g.
3. The catalyst composition of claim 1 , wherein the catalyst composition has a BET surface area in the range of 70 m 2 /g to 200 m 2 /g.
4. The catalyst composition of claim 3 , wherein the nickel species is about 5 wt % of the catalyst composition.
5. The catalyst composition of claim 1 , wherein the nickel species is about 5 wt % of the catalyst composition.
6. The catalyst composition of claim 1 , wherein the nickel species dispersed on the surface of the alumina is about 6wt % to about 15 wt % of the nickel species.
7. The catalyst composition of claim 6 , wherein the nickel species dispersed on the surface of the alumina is about 7.75 wt % to about 13.52 wt % of the nickel species.
8. The catalyst composition of claim 7 , wherein the size of NiO particles is 18.281 nm.
9. The catalyst composition of claim 1 , wherein NiAl 2 O 4 is about 70 wt % of the nickel species.
10. The catalyst composition of claim 1 , wherein NiAl 2 O 4 is about 90 wt % of the nickel species in the bulk of the alumina.
11. The catalyst composition of claim 1 , wherein the size of NiO particles about 16 nm to about 18 nm.
12. The catalyst composition of claim 11 , wherein the size of NiO particles is about 18 nm.
13. The catalyst composition of claim 1 , wherein the size of NiAl 2 O 4 particles is about 12 nm.
14. The catalyst composition of claim 13 , wherein the size of NiAl 2 O 4 particles is 11.65 nm.
15. The catalyst composition of claim 13 , wherein the size of the alumina particles is about 22 nm.
16. The catalyst composition of claim 1 , wherein the size of the alumina particles is about 22 nm.
17. The catalyst composition of claim 16 , wherein the size of the alumina particles is 21.539 nm.
18. A method for CO 2 (dry) reformation of methane to hydrogen and/or synthesis gas, comprising
providing a catalyst composition of claim 1 ; and
contacting the catalyst composition with methane and CO 2 at a temperature to produce the hydrogen and/or the synthesis gas.
19. The method of claim 18 , wherein the temperature at the contacting is at least 500° C.
20. The method of claim 18 , wherein the dry reformation reaction occurs at a temperature between 500-900° C.
21. The method of claim 18 , wherein CH 4 and CO 2 are maintained at a molar ratio of about 1:1 in a feed.