Hot dipped medium manganese steel and manufacturing method therefor
A hot dipped medium manganese steel and a manufacturing method therefor. The medium manganese steel comprises a steel base plate and a coating on the surface of the steel base plate; the mass percentages of the components in the hot dipped medium manganese steel are: C: 0.1 to 0.3%, Si: 0.1 to 2.0%, Mn: 5 to 12%, Al: 1 to 2%, P≤0.02%, S≤0.02%, N≤0.005%, and the remaining being Fe and unavoidable impurities; the core structure is ferrite and austenite, and the surface layer of the steel base plate is a ferrite layer.
1. A hot dipped medium manganese steel, comprising a steel substrate and a coating on a surface of the steel substrate, wherein the steel substrate of the hot dipped medium manganese steel comprises C: 0.1 to 0.2%, Si: 0.1 to 2.0%, Mn: 5 to 12%, Al: 1 to 2%, P≤0.02%, S≤0.02%, N≤0.005% and a balance Fe and unavoidable impurities based on mass; wherein the steel substrate has a core structure of ferrite and austenite; and wherein the steel substrate has a skin layer which is a ferrite layer, and wherein the hot dipped medium manganese steel has a yield strength of 700-1000 MPa, a tensile strength of 950-1350 MPa, and an elongation at break of at least 27%.
2. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has a thickness of 0.2-5 μm.
3. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has a grain size of ≤5 μm.
4. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has a Mn content lower than that in the steel substrate.
5. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has a Mn content of ≤5%.
6. The hot dipped medium manganese steel according to claim 5 , wherein the ferrite layer has a Mn content of ≤2%.
7. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has an Al content higher than that in the steel substrate.
8. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has an Al content of >1%.
9. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has an Al content of <5%.
10. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer comprises an Al oxide.
11. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has a C content lower than that in the steel substrate.
12. The hot dipped medium manganese steel according to claim 1 , wherein the ferrite layer has a C content of ≤0.1%.
13. The hot dipped medium manganese steel according to claim 1 , wherein the coating has a thickness of 5-200 μm.
14. A method for manufacturing the hot dipped medium manganese steel of claim 1 , comprising the following steps:
1) Manufacturing a strip steel;
2) Primary annealing and pickling
wherein the strip steel is heated on a continuous annealing production line to a soaking temperature of 600 to 750° C. for a soaking time of 30 to 600 s, wherein a mixed gas of N 2 and H 2 is used as an annealing atmosphere which has a He content of 0.5-10% by volume and a dew point of −20 to +20° C.; subsequently, the strip steel is cooled to below 100° C. after the annealing, and pickled with an acid solution having a hydrogen ion concentration of 0.1-5%, wherein the acid solution has a temperature of 50-70° C., and a pickling time is 1 to 10 s; then, the strip steel is rinsed, dried and coiled;
3) Secondary annealing and hot dipping:
wherein the strip steel obtained in step (2) is subjected to secondary annealing and accomplishes hot dipping on a hot dipping production line, wherein the secondary annealing is performed at a soaking temperature of 600-850° C. for a soaking time of 60-360 s in an annealing atmosphere of a mixed gas of N 2 and H 2 , wherein the annealing atmosphere has a H 2 content of 2-10% by volume, and a dew point of −60 to +10° C.; subsequently, the strip steel is cooled to 380 to 500° C., and then immersed in a plating bath to perform the hot dipping, thereby producing the hot dipped medium manganese steel of claim 1 .
15. The method for manufacturing the hot dipped medium manganese steel according to claim 14 , wherein the soaking temperature in step (2) is 600-700° C.
16. The method for manufacturing the hot dipped medium manganese steel according to claim 14 , wherein the soaking time in step (2) is 30-180 s.
17. The method for manufacturing the hot dipped medium manganese steel according to claim 14 , wherein the annealing atmosphere in step (2) has a dew point of −10 to +10° C.
18. The method for manufacturing the hot dipped medium manganese steel according to claim 14 , wherein the plating bath in step (3) comprises, based on mass percentage, 0.1≤Al≤6%, 0<Mg≤5% and a balance of Zn and unavoidable impurities.
19. The method for manufacturing the hot dipped medium manganese steel according to claim 14 , wherein the annealing atmosphere in step (3) has a dew point of −60 to −20° C.
20. The method for manufacturing the hot dipped medium manganese steel according to claim 14 , wherein the plating bath in step (3) has a temperature of 420-480° C.