Aromatic polycarbonate resin, method for producing same, and aromatic dihydroxy compound

1. An aromatic polycarbonate resin, comprising a structural unit represented by the following Formula (1), that is derived from an aromatic dihydroxy starting compound and a carbonate-forming starting compound,

wherein:

a hydrolysate obtained by hydrolysis of the aromatic polycarbonate resin comprises aromatic dihydroxy compounds represented by the following Formulae (2) and (3);

a content of the aromatic dihydroxy compound represented by the following Formula (2) in the hydrolysate is 250 ppm by mass or less with respect to that of the aromatic dihydroxy compound represented by the following Formula (3); and

R 1 represents an alkyl group having 1 to 24 carbon atoms; R 2 and R 3 each independently represent a monovalent hydrocarbon group having 1 to 15 carbon atoms; and a and b each independently represent an integer of 0 to 4.

2. The aromatic polycarbonate resin according to claim 1 , having a viscosity-average molecular weight of 9,000 or higher.

3. The aromatic polycarbonate resin according to claim 1 , wherein the content of the aromatic dihydroxy compound represented by the Formula (2) in the hydrolysate is not less than 1 ppm by mass with respect to that of the aromatic dihydroxy compound represented by the Formula (3).

4. The aromatic polycarbonate resin according to claim 1 , wherein, in the Formulae (1) to (3), R 1 represents an alkyl group having 6 to 24 carbon atoms.

5. A method of producing the aromatic polycarbonate resin according to claim 1 , the method comprising the polymerization step of polymerizing the aromatic dihydroxy compound and the carbonate-forming compound in the presence of an alkali catalyst.

6. The method of producing the aromatic polycarbonate resin according to claim 5 , wherein the polymerization step is performed by a transesterification method.

7. The method of producing the aromatic polycarbonate resin according to claim 6 , wherein, in the polymerization step, a transesterification catalyst is deactivated after a transesterification reaction, without substantial solidification of the resulting aromatic polycarbonate resin.

8. The method of producing the aromatic polycarbonate resin according to claim 7 , wherein, in the polymerization step, a deactivator is added in an amount of not less than 3 equivalents and 50 equivalents or less with respect to the transesterification catalyst.

9. An aromatic dihydroxy compound, comprising aromatic dihydroxy compounds represented by the following Formulae (2) and (3),

wherein the content of the aromatic dihydroxy compound represented by Formula (2) is 250 ppm by mass or less:

wherein, R 1 represents an alkyl group having 1 to 24 carbon atoms; R 2 and R 3 each independently represent a monovalent hydrocarbon group having 1 to 15 carbon atoms; and a and b each independently represent an integer of 0 to 4.

10. The aromatic dihydroxy compound according to claim 9 , wherein the content of the aromatic dihydroxy compound represented by the Formula (2) is not less than 1 ppm by mass.

11. The aromatic dihydroxy compound according to claim 9 , wherein, in the Formulae (2) and (3), R 1 represents an alkyl group having 6 to 24 carbon atoms.

12. An aromatic polycarbonate resin composition, comprising the aromatic polycarbonate resin according to claim 1 ,

wherein the aromatic polycarbonate resin composition further comprises an aromatic polycarbonate resin composed of carbonate structural units derived from 2,2-bis(4-hydroxyphenyl)propane.

13. A method of producing an aromatic polycarbonate resin comprising a structural unit represented by the following Formula (1), the method comprising the step of polymerizing an aromatic dihydroxy starting compound and a carbonate-forming starting compound, wherein:

a hydrolysate obtained by hydrolysis of the aromatic polycarbonate resin comprises aromatic dihydroxy compounds represented by the following Formulae (2) and (3), and a content of the aromatic dihydroxy compound represented by the following Formula (2) in the hydrolysate is 250 ppm by mass or less with respect to that of the aromatic dihydroxy compound represented by the following Formula (3), and

R 1 represents an alkyl group having 1 to 24 carbon atoms; R 2 and R 3 each independently represent a monovalent hydrocarbon group having 1 to 15 carbon atoms; and a and b each independently represent an integer of 0 to 4.

14. The aromatic polycarbonate resin according to claim 1 , wherein R 1 is n-undecyl.

15. The aromatic polycarbonate resin according to claim 1 , wherein R 2 and R 3 are each hydrogen.

16. The aromatic polycarbonate resin according to claim 1 , wherein the aromatic dihydroxy compound represented by Formula (3) is 1,1-bis(4-hydroxyphenyl)dodecane.

17. The aromatic polycarbonate resin according to claim 1 , wherein the the aromatic dihydroxy compound represented by Formula (2) present in the hydrolysate is 100 ppm by mass or less.

18. The method of claim 13 , wherein R 1 is n-undecyl.

19. The method of claim 13 , wherein the aromatic dihydroxy compound represented by Formula (3) is 1,1-bis(4-hydroxyphenyl)dodecane.

20. The method of claim 13 , wherein the hydrolysis of the aromatic polycarbonate resin comprises:

dissolving the aromatic polycarbonate resin in a liquid mixture of dicyclomethan, methanol, and aqueous sodium hydroxide solution to form a mixture; and

heating the mixture at 75° C. for 30 minutes.