Method for manufacturing polytetrafluoroethylene formed product, and polytetrafluoroethylene formed product
A manufacturing method for a polytetrafluoroethylene formed product according to an aspect of the invention is a manufacturing method for a polytetrafluoroethylene formed product, the method including a step of irradiating a forming material containing a polytetrafluoroethylene as a principal component with ionizing radiation, wherein the polytetrafluoroethylene has a melt viscosity at 380° C. of not greater than 7×10 5 Pa·s.
1. A manufacturing method for a polytetrafluoroethylene formed product, the method comprising an irradiation step of irradiating a forming material containing a homopolymer of polytetrafluoroethylene as a principal component with ionizing radiation under a condition of no oxygen and of a temperature equal to or higher than a crystalline melting point of the polytetrafluoroethylene, wherein
the homopolymer of polytetrafluoroethylene included in the forming material prior to the irradiation step has a melt viscosity at 380° C. of not greater than 7×10 5 Pa·s,
a dose of the ionizing radiation is not less than 50 kGy and not greater than 150 kGy, and
a pencil hardness of the polytetrafluoroethylene formed product is not less than F and the pencil hardness of the polytetrafluoroethylene formed product is not greater than H.
2. The manufacturing method for the polytetrafluoroethylene formed product according to claim 1 , wherein the melt viscosity is not less than 1×10 2 Pa·s.
3. The manufacturing method for the polytetrafluoroethylene formed product according to claim 2 , wherein the melt viscosity is not less than 1×10 5 Pa·s.
4. The manufacturing method for the polytetrafluoroethylene formed product according to claim 1 , wherein the manufacturing method is a manufacturing method for a polytetrafluoroethylene formed product for a sliding member.
5. The manufacturing method for the polytetrafluoroethylene formed product according to claim 1 , further comprising a forming step of forming the forming material, before the irradiation step.
6. The manufacturing method for the polytetrafluoroethylene formed product according to claim 5 , wherein the forming step is carried out by extrusion or injection molding.
7. The manufacturing method for the polytetrafluoroethylene formed product according to claim 5 , wherein the forming step is carried out by coating with the forming material which is powder or an aqueous dispersion.
8. The manufacturing method for the polytetrafluoroethylene formed product according to claim 1 , wherein the polytetrafluoroethylene has a number average molecular weight of not greater than 600 thousand.
9. A polytetrafluoroethylene formed product obtained by the manufacturing method for the polytetrafluoroethylene formed product according to claim 1 .