Adhesive resin composition, method for bonding adherends, and adhesive resin film
The present invention provides an adhesive resin composition that has excellent adhesiveness and durability, a method for bonding adherends, and an adhesive resin film More specifically, the present invention relates to an adhesive resin composition containing more than 50 parts by mass and 99.5 parts by mass or less in a solid content of an acid-modified polyolefin resin having a melting point of 50 to 100° C., 0.5 parts by mass or more and less than 50 parts by mass in a solid content of an epoxy resin having a novolac structure, and an organic solvent; a method for bonding adherends including forming an adhesive layer on a first adherend by applying the adhesive resin composition and drying, and then bonding a second adherend to the adhesive layer by laminating the second adherend on the adhesive layer; and an adhesive resin film including a first adhesive layer, a substrate layer, and a second adhesive layer in that order, in which any one or both of the first adhesive layer and the second adhesive layer include(s) the adhesive resin composition.
1. An adhesive resin film comprising a first surface layer, a first adhesive layer, a substrate layer, a second adhesive layer, and a second surface layer in that order, wherein
at least one of said first surface layer and said second surface layer contains an acid-modified polyolefin resin, and
at least one of said first adhesive layer and said second adhesive layer contains an adhesive resin composition,
wherein said adhesive resin composition consists essentially of:
70 parts by mass or more and 99.5 parts by mass or less of an acid-modified polyolefin resin (A) having a melting point of 50 to 100° C.;
0.5 parts by mass or more and 30 parts by mass or less of an epoxy resin (B) having a novolac structure; and
an organic solvent (C),
wherein said epoxy resin (B) having a novolac structure is a bisphenol A novolac epoxy resin having an epoxy equivalent of 100 to 300, and
the acid-modified polyolefin resin (A) and the epoxy resin (B) having a novolac structure are the only solid components in said adhesive resin composition.
2. The adhesive resin film according to claim 1 , wherein said acid- modified polyolefin resin (A) has a methyl group and an ethyl group on a side chain.
3. The adhesive resin film according to claim 1 , wherein
in dynamic viscoelasticity measurement, the adhesive resin film formed including said adhesive resin composition has a storage modulus value at 60° C. of 1.0×10 6 or more and a storage modulus value at 150° C. of 1.0×10 4 or more.
4. The adhesive resin film according to claim 1 , wherein the at least one of said first surface layer and said second surface layer further contains a compound having an epoxy group or an oxazoline group, wherein
said compound having an epoxy group or an oxazoline group is contained in an amount of 1 to 20% by mass with respect to said acid-modified polyolefin resin.