Organic light emitting diode and organic light emitting device including the same
Disclosed is an organic light emitting diode including a first electrode; a second electrode facing the first electrode; and a first emitting material layer, which includes a first host, a second host and a first dopant and disposed between the first and second electrodes. The first host is represented by Formula 1, the second host may be a triazine derivative, and the first dopant may be a red, green or blue dopant.
1. An organic light emitting diode, comprising:
a first electrode;
a second electrode facing the first electrode; and
a first emitting material layer including a first host, a second host and a first dopant, and disposed between the first and second electrodes,
wherein the first host is represented by Formula 1:
wherein X is O or S,
wherein Ar 1 is C10 to C30 aryl, and Ar 2 is C6 to C30 aryl,
wherein each of R 1 to R 3 is independently selected from the group consisting of halogen, C1 to C10 alkyl, C1 to C20 aryl and C3 to C10 cycloalkyl, and
wherein each of a, b and c is independently an integer of 0 to 4.
2. The organic light emitting diode according to claim 1 , wherein the first host is selected from Formula 2:
3. The organic light emitting diode according to claim 1 , wherein the second host is represented by Formula 3-1:
wherein each of Ar 11 and Ar 12 is independently selected from the group consisting of hydrogen and C6 to C30 aryl,
wherein L is C6 to C30 arylene group, and a is 0 or 1,
wherein Ar 13 is represented by Formula 3-2 or Formula 3-3:
wherein in Formula 3-2, R 14 is a heteroaryl, or adjacent two R 14 form a fused ring,
wherein h is an integer of 0 to 4, and
wherein in Formula 3-3, R 15 is a heteroaryl, and X is O or S.
4. The organic light emitting diode according to claim 3 , wherein the second host is selected from Formula 4:
5. The organic light emitting diode according to claim 3 , wherein an energy level of a triplet state of the second host is equal to or lower than an energy level of a triplet state of the first host.
6. The organic light emitting diode according to claim 3 , wherein a percentage by weight of the first host is equal to or greater than a percentage by weight of the second host.
7. The organic light emitting diode according to claim 1 , further comprising:
a hole transporting layer disposed between the first electrode and the first emitting material layer and including a hole transporting material of Formula 6:
wherein each of R 31 to R 33 is independently selected from the group consisting of deuterium, halogen, C1 to C10 alkyl, C3 to C10 cycloalkyl, C6 to C30 aryl, C5 to C30 heteroaryl, trialkylsilyl and triarylsilyl, and each of Ar 31 and Ar 32 is independently selected from the group consisting of C6 to C30 aryl and C5 to C30 heteroaryl, and
wherein each of a, b and c is independently an integer of 0 to 4.
8. The organic light emitting diode according to claim 7 , wherein the hole transporting material is selected from Formula 7:
9. The organic light emitting diode according to claim 7 , wherein the first host has an energy level of a triplet state of 2.6 to 2.8 eV, and the second host has an energy level of a triplet state of 2.4 to 2.8 eV, and
wherein the hole transporting material has an energy level of a triplet state of 2.4 to 3.0 eV.
10. The organic light emitting diode according to claim 1 , wherein the first dopant is a green dopant.
11. The organic light emitting diode according to claim 10 , further comprising:
a second emitting material layer including a third host and a blue dopant and disposed between the first emitting material layer and the second electrode;
a charge generation layer disposed between the first and second emitting material layers; and
a third emitting material layer including a fourth host and a red dopant, the third emitting material layer disposed between the first electrode and the first emitting material layer or between the first emitting material layer and the charge generation layer.
12. The organic light emitting diode according to claim 11 , wherein the first and third emitting material layers contact each other.
13. An organic light emitting device, comprising:
a substrate; and
an organic light emitting diode on or over the substrate, the organic light emitting diode comprising:
a first electrode;
a second electrode facing the first electrode; and
a first emitting material layer including a first host, a second host and a first dopant and disposed between the first and second electrodes,
wherein the first host is represented by Formula 1:
wherein X is O or S,
wherein Ar 1 is C10 to C30 aryl, and Ar 2 is C6 to C30 aryl,
wherein each of R 1 to R 3 is independently selected from the group consisting of halogen, C1 to C10 alkyl, C1 to C20 aryl and C3 to C10 cycloalkyl, and
wherein each of a, b and c is independently an integer of 0 to 4.
14. The organic light emitting device according to claim 13 , wherein the first host is selected from Formula 2:
15. The organic light emitting device according to claim 13 , wherein the second host is represented by Formula 3-1:
wherein each of Ar 11 and Ar 12 is independently selected from the group consisting of hydrogen and C6 to C30 aryl,
wherein L is C6 to C30 arylene group, and a is 0 or 1,
wherein Ar 13 may be represented by Formula 3-2 or Formula 3-3:
wherein in Formula 3-2, R 14 is a heteroaryl, or adjacent two R 14 form a fused ring,
wherein b is an integer of 0 to 4, and
wherein in Formula 3-3, R 15 is a heteroaryl, and X is O or S.
16. The organic light emitting device according to claim 15 , wherein the second host is selected from Formula 4:
17. The organic light emitting device according to claim 15 , wherein an energy level of a triplet state of the second host is equal to or lower than an energy level of a triplet state of the first host.
18. The organic light emitting device according to claim 15 , wherein a percentage by weight of the first host is equal to or greater than a percentage by weight of the second host.
19. The organic light emitting device according to claim 13 , wherein the organic light emitting diode further comprises:
a hole transporting layer disposed between the first electrode and the first emitting material layer and including a hole transporting material of Formula 6:
wherein each of R 31 to R 33 is independently selected from the group consisting of deuterium, halogen, C1 to C10 alkyl, C3 to C10 cycloalkyl, C6 to C30 aryl, C5 to C30 heteroaryl, trialkylsilyl and triarylsilyl, and each of Ar 31 and Ar 32 is independently selected from the group consisting of C6 to C30 aryl and C5 to C30 heteroaryl, and
wherein each of a, b and c is independently an integer of 0 to 4.
20. The organic light emitting device according to claim 19 , wherein the hole transporting material is selected from Formula 7:
21. The organic light emitting device according to claim 19 , wherein the first host has an energy level of a triplet state of 2.6 to 2.8 eV, and the second host has an energy level of a triplet state of 2.4 to 2.8 eV, and
wherein the hole transporting material has an energy level of a triplet state of 2.4 to 3.0 eV.
22. The organic light emitting device according to claim 13 , wherein the first dopant is a green dopant.
23. The organic light emitting device according to claim 22 , wherein the organic light emitting diode further comprises:
a second emitting material layer including a third host and a blue dopant and disposed between the first emitting material layer and the second electrode;
a charge generation layer disposed between the first and second emitting material layers; and
a third emitting material layer including a fourth host and a red dopant, the third emitting material layer disposed between the first electrode and the first emitting material layer or between the first emitting material layer and the charge generation layer.
24. The organic light emitting device according to claim 23 , wherein the first and third emitting material layers contact each other.
25. The organic light emitting device according to claim 23 , wherein a red pixel, a green pixel and a blue pixel are defined on the substrate, and the organic light emitting diode corresponds to each of the red, green and blue pixels, and
wherein the organic light emitting device further comprises:
a color filter layer corresponding to each of the red, green and blue pixels, the color filter layer disposed between the substrate and the organic light emitting diode or over the organic light emitting diode.