Reduced volume electrochlorination cells and methods of manufacturing same
An electrochemical cell includes a housing having an inlet, an outlet, and a central axis and an anode-cathode pair disposed concentrically within the housing about the central axis and defining an active area between an anode and a cathode of the anode-cathode pair. An active surface area of at least one of the anode and the cathode has a surface area greater than a surface area of an internal surface of the housing. The anode-cathode pair is configured and arranged to direct all fluid passing through the electrochemical cell axially through the active area.
1. An electrochemical cell comprising:
a housing having an inlet, an outlet, and a central axis;
an anode-cathode pair disposed substantially concentrically within the housing about the central axis and defining an active area between an anode and a cathode of the anode-cathode pair, an active surface area of at least one of the anode and the cathode having a surface area greater than a surface area of an internal surface of the housing, the anode-cathode pair configured and arranged to direct all fluid passing through the electrochemical cell axially through the active area; and
an electrical connector in electrical communication with one of the anode and the cathode, the electrical connector including at least two materials having different degrees of resistance to chemical attack by an electrolyte solution, the at least two materials including a first material and a second material, a fluid permeable body being formed of the first material, the electrical connector including one of:
a plate of the second material coupled to the fluid permeable body formed of the first material with one or more mechanical fasteners;
a plate of the second material coupled to the fluid permeable body formed of the first material with a compression fit;
a plate of the second material coupled to the fluid permeable body formed of the first material with threads formed in an edge of the fluid permeable body formed of the first material; or
a body formed of the second material coupled to the fluid permeable body formed of the first material with threads formed in a cylindrical portion of the body formed of the second material.
2. The electrochemical cell of claim 1 , comprising the plate of the second material coupled to the fluid permeable body formed of the first material with the one or more mechanical fasteners.
3. The electrochemical cell of claim 1 , comprising the plate of the second material coupled to the fluid permeable body formed of the first material with the compression fit.
4. The electrochemical cell of claim 1 , comprising the plate of the second material coupled to the fluid permeable body formed of the first material with the threads formed in the edge of the fluid permeable body formed of the first material.
5. The electrochemical cell of claim 1 , comprising the body formed of the second material coupled to the fluid permeable body formed of the first material with the threads formed in the cylindrical portion of the body formed of the second material.
6. The electrochemical cell of claim 1 , further comprising a body formed of the second material welded to the fluid permeable body formed of the first material.
7. An electrochemical cell comprising:
a cathode and an anode disposed in a housing and defining a gap therebetween, each of the cathode and anode including arcuate portions, an active surface area of the anode being greater than a surface area of an internal surface of the housing and an active surface area of the cathode being greater than a surface area of an internal surface of the housing, the cathode and anode configured and arranged to direct all fluid passing through the electrochemical cell axially through the gap; and
an electrical connector in electrical communication with one of the anode and the cathode, the electrical connector including at least two materials having different degrees of resistance to chemical attack by an electrolyte solution, the at least two materials including a first material and a second material, a fluid permeable body being formed of the first material, the electrical connector including one of:
a plate of the second material coupled to the fluid permeable body formed of the first material with one or more mechanical fasteners;
a plate of the second material coupled to the fluid permeable body formed of the first material with a compression fit;
a plate of the second material coupled to the fluid permeable body formed of the first material with threads formed in an edge of the fluid permeable body formed of the first material; or
a body formed of the second material coupled to the fluid permeable body formed of the first material with threads formed in a cylindrical portion of the body formed of the second material.
8. The electrochemical cell of claim 7 , wherein the anode includes a plurality of plates extending from an arcuate base and the cathode includes a plurality of plates extending from an arcuate base, the plurality of plates of the anode interleaved with the plurality of plates of the cathode.
9. An electrochemical cell comprising:
a cathode and an anode disposed in a housing and defining a gap therebetween, each of the cathode and anode including a portion conforming to respective portions of an internal surface of the housing, an active surface area of the anode being greater than a surface area of an internal surface of the housing and an active surface area of the cathode being greater than a surface area of an internal surface of the housing, the cathode and anode configured and arranged to direct all fluid passing through the electrochemical cell axially through the gap; and
an electrical connector in electrical communication with one of the anode and the cathode, the electrical connector including at least two materials having different degrees of resistance to chemical attack by an electrolyte solution, the at least two materials including a first material and a second material, a fluid permeable body being formed of the first material, the electrical connector including one of:
a plate of the second material coupled to the fluid permeable body formed of the first material with one or more mechanical fasteners;
a plate of the second material coupled to the fluid permeable body formed of the first material with a compression fit;
a plate of the second material coupled to the fluid permeable body formed of the first material with threads formed in an edge of the fluid permeable body formed of the first material; or
a body formed of the second material coupled to the fluid permeable body formed of the first material with threads formed in a cylindrical portion of the body formed of the second material.
10. The electrochemical cell of claim 9 , wherein at least one of the anode and the cathode includes a corrugated portion.