Non-aqueous electrolyte for lithium ion battery and lithium ion battery
To solve the problems that the existing non-aqueous electrolyte for lithium ion battery containing fluorinated solvent generates serious gas expansion when improving high-temperature cycle performance and affects high-temperature safety performance of battery. The application provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a compound A and a compound B, wherein the compound A is at least one of compounds represented by the following structural formula I, formula II and formula III; the compound B is a compound represented by the following structural formula IV; formula I: R 1 —COO—R 2 ; formula II: R 3 —OCOO—R 4 . The non-aqueous electrolyte for lithium ion battery provided by the invention contains both the compound A and the compound B, the synergistic effect of compound A and compound B can effectively improve high-temperature cycle performance and high-temperature storage performance of battery, and can also give consideration to low-temperature performance of battery.
1. A non-aqueous electrolyte for lithium ion battery, comprising a compound A and a compound B, wherein the compound A is at least one of compounds represented by the following structural formula I, formula II and formula III; the compound B is a compound represented by the following structural formula IV,
R 1 —COO—R 2 ;formula I:
R 3 —OCOO—R 4 ;formula II:
in formula I, R 1 is a hydrogen atom, a C1-C5 hydrocarbon group or a C1-C5 fluorohydrocarbon group, R 2 is a C1-C5 hydrocarbon group or a C1-C5 fluorohydrocarbon group, and at least one of R 1 and R 2 contains a fluorine atom;
in formula II, R 3 and R 4 are each independently selected from C1-C5 hydrocarbon group or C1-C5 fluorohydrocarbon group, and at least one of R 3 and R 4 contains a fluorine atom;
in formula III, R 5 , R 6 , R 7 and R 8 are each independently selected from hydrogen atom, fluorine atom, C1-C4 hydrocarbon group or C1-C4 fluorohydrocarbon group, and at least one of R 5 , R 6 , R 7 and R 8 contains a fluorine atom;
in formula IV, R 9 , R 10 , R 11 , R 12 , R 13 and R 14 are each independently selected from one of hydrogen atom, fluorine atom or C1-C5 group.
2. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein in formula IV, the C1-C5 group is selected from a hydrocarbon group, fluorinated hydrocarbon group, oxygen-containing hydrocarbon group, silicon-containing hydrocarbon group, and cyano-substituted hydrocarbon group.
3. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein in formula IV, R 9 , R 10 , R 11 , R 12 , R 13 and R 14 are each independently selected from a hydrogen atom, fluorine atom, methyl group, ethyl group, methoxyl group, ethyoxyl group, trimethylsiloxy group, cyano group or trifluoromethyl group.
4. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the compound B comprises one or more of compounds 1-9 represented by the following structural formulae,
5. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the percentage mass content of the compound B is 0.1-5% based on the total mass of the non-aqueous electrolyte for lithium ion battery being 100%.
6. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein, the compound represented by formula I is selected from one or more of H 3 CCOOCH 2 CF 2 H, H 3 CH 2 CCOOCH 2 CF 2 H, HF 2 CH 2 CCOOCH 3 , HF 2 CH 2 CCOOCH 2 CH 3 , HF 2 CH 2 CH 2 CCOOCH 2 CH 3 , H 3 CCOOCH 2 CH 2 CF 2 H, H 3 CH 2 CCOOCH 2 CH 2 CF 2 H, CH 3 COOCH 2 CF 3 , HCOOCH 2 CHF 2 , HCOOCH 2 CF 3 and CH 3 COOCH 2 CF 2 CF 2 H.
7. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the compound represented by formula II is selected from one or more of CH 3 OCOOCH 2 CF 2 H, CH 3 OCOOCH 2 CF 3 , CH 3 OCOOCH 2 CF 2 CF 2 H, HCF 2 CH 2 OCOOCH 2 CH 3 and CF 3 CH 2 OCOOCH 2 CH 3 .
8. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the compound represented by formula III is selected from one or more of compounds 10-13 represented by the following structures,
9. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the percentage mass content of the compound A is less than 80% based on the total mass of the non-aqueous electrolyte for lithium ion battery being 100%.
10. The non-aqueous electrolyte for lithium ion battery of claim 9 , wherein the compound A is at least one of compounds represented by structural formula I, formula II and formula III, and R 5 in formula III is fluorine, R 6 , R 7 and R 8 are each independently selected from hydrogen atom, fluorine atom, C1-C4 hydrocarbon group or C1-C4 fluorohydrocarbon group, and R 6 , R 7 and R 8 cannot be hydrogen atom at the same time; or R 5 is C1-C4 fluorine-containing hydrocarbon group, R 6 , R 7 and R 8 are independently selected from hydrogen atom, fluorine atom, C1-C4 hydrocarbon group or C1-C4 fluorine-containing hydrocarbon group.
11. The non-aqueous electrolyte for lithium ion battery of claim 9 , wherein the compound A is fluoroethylene carbonate, and the percentage mass content of the compound A is greater than 5% and less than or equal to 80% based on the total mass of the non-aqueous electrolyte of the lithium ion battery being 100%.
12. The non-aqueous electrolyte for lithium ion battery of claim 9 , wherein the percentage mass content of the compound A is 10-80%, based on the total mass of the non-aqueous electrolyte of the lithium ion battery being 100%.
13. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the lithium ion non-aqueous electrolyte further comprises at least one of unsaturated cyclic carbonate compounds and sultone compounds.
14. The non-aqueous electrolyte for lithium ion battery of claim 13 , wherein the unsaturated cyclic carbonate compound comprises at least one of vinylene carbonate and vinyl ethylene carbonate;
the sultone compound is selected from at least one of 1,3-propane sultone, 1,4-butane sultone, and 1,3-propene sultone.
15. The non-aqueous electrolyte for lithium ion battery of claim 13 , wherein the percentage mass content of the unsaturated cyclic carbonate compound is 0.1-5% based on the total mass of the non-aqueous electrolyte of the lithium ion battery being 100%; the percentage mass content of the sultone compound is 0.1-5% based on the total mass of the non-aqueous electrolyte of the lithium ion battery being 100%.
16. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the non-aqueous electrolyte for lithium ion battery comprises lithium salt; the lithium salt can be selected from one or more of LiPF 6 , LiBOB and LiBF 4 .
17. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the lithium salt content in the non-aqueous electrolyte for lithium ion battery is 0.1-15%.
18. The non-aqueous electrolyte for lithium ion battery of claim 1 , wherein the non-aqueous electrolyte for lithium ion battery comprises a solvent, and the solvent is selected from at least one of vinyl carbonate, propylene carbonate, butylene carbonate, dimethyl carbonate, diethyl carbonate, methyl ethyl carbonate and methyl propyl carbonate.
19. A lithium ion battery, comprising a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and an electrolyte, wherein the electrolyte is the non-aqueous electrolyte for lithium ion battery of claim 1 .
20. The lithium ion battery of claim 19 , wherein the positive electrode comprises a positive electrode active material, and the positive electrode active material is at least one of LiNi x Co y Mn z L (1-x-y-z) O 2 , LiCo x′ L (1−x′) O 2 , LiNi x″ L′ y′ Mn (2-x″-y′) O 4 and Li z′ MPO 4 , wherein, L is at least one of Al, Sr, Mg, Ti, Ca, Zr, Zn, Si or Fe, 0≤x≤1, 0≤y≤1, 0≤z≤1, 0<x+y+z≤1, 0<x′≤1, 0.3≤x″≤0.6, 0.01≤y′≤0.2, L′ is at least one of Co, Al, Sr, Mg, Ti, Ca, Zr, Zn, Si and Fe; 0.5≤z′≤1, M is at least one of Fe, Mn and Co.