Multicomponent aluminum alloys for applications such as additive manufacturing
Materials, methods and techniques disclosed and contemplated herein relate to multicomponent aluminum alloys. Generally, multicomponent aluminum alloys include aluminum, nickel, zirconium, and rare earth elements, and include L 12 precipitates having an Al 3 X composition. Rare earth elements used in example multicomponent aluminum alloys disclosed and contemplated herein include erbium (Er), zirconium (Zr), yttrium (Y), and ytterbium (Yb). Example multicomponent aluminum alloys disclosed and contemplated herein are particularly suited for use in additive manufacturing operations.
1. An alloy comprising, by weight percentage:
1% to 4.2% nickel;
0.5% to 2.6% erbium;
0.1% to 1.5% zirconium;
0.05% to 0.3% yttrium;
0.1% to 1.2% ytterbium; and
the balance of weight percent comprising aluminum and incidental elements and impurities,
wherein the alloy includes L1 2 precipitates having an Al 3 X composition, where X is at least one of: erbium, zirconium, yttrium, and ytterbium.
2. The alloy according to claim 1 , wherein the alloy includes no more than 0.5% by weight percentage incidental elements and impurities.
3. The alloy according to claim 1 , wherein the alloy does not include scandium.
4. The alloy according to claim 1 , wherein the alloy, after being subjected to an additive manufacturing process and after aging at 300° C. to 425° C., has an ultimate tensile strength of at least 55 ksi at 22° C.
5. The alloy according to claim 1 , wherein the alloy, after being subjected to an additive manufacturing process, has a yield strength of at least 30 ksi at 250° C.
6. The alloy according to claim 1 , wherein the alloy has an L1 2 phase fraction that is 0.5% to 6% by volume fraction.
7. The alloy according to claim 1 , wherein the alloy, after being subjected to an additive manufacturing process and after aging at 300° C. to 425° C., is capable of passing a fatigue test without failure, the fatigue test including a stress amplitude of 15 ksi, a frequency of 50 Hz, an r ratio of −1, and a number of cycles being 10,000,000.
8. The alloy according to claim 1 , wherein after subjecting the alloy to an additive manufacturing process and after aging at 375° C. to 425° C. to produce an aged alloy, the aged alloy has an ultimate tensile strength of at least 20 ksi at 250° C.
9. The alloy according to claim 1 , wherein after subjecting the alloy to an additive manufacturing process and after aging the alloy at a temperature of 350° C. for 24 hours to produce an aged alloy, the aged alloy has an average hardness of at least 120 HV.
10. The alloy according to claim 1 , wherein the alloy comprises, by weight percentage:
2% to 3% nickel;
1.0% to 1.5% erbium;
0.5% to 1.15% zirconium;
0.10% to 0.25% yttrium; and
0.5% to 0.8% ytterbium,
the balance of weight percent comprising aluminum and no more than 0.5 weight percent incidental elements and impurities.
11. An atomized alloy powder usable in additive manufacturing, the atomized alloy powder comprising:
alloy particles comprising, by weight percentage:
1% to 4.2% nickel;
0.5% to 2.6% erbium;
0.1% to 1.5% zirconium;
0.05% to 0.3% yttrium;
0.1% to 1.2% ytterbium; and
the balance of weight percent comprising aluminum and incidental elements and impurities,
wherein the alloy particles include L1 2 precipitates having an Al 3 X composition, where X is at least one of: erbium, zirconium, yttrium, and ytterbium.
12. The atomized alloy powder according to claim 11 , wherein the atomized alloy powder includes no more than 0.5% by weight percentage incidental elements and impurities; and
wherein the atomized alloy powder does not include scandium.
13. The atomized alloy powder according to claim 11 , wherein after subjecting the atomized alloy powder to an additive manufacturing process and after aging at a temperature of 350° C. for 24 hours to produce an aged alloy product, the aged alloy product has an L1 2 phase fraction is 0.5% to 6% by volume fraction at 350° C.
14. The atomized alloy powder according to claim 11 , wherein after subjecting the atomized alloy powder to an additive manufacturing process to generate an alloy product, the alloy product has an ultimate tensile strength of at least 25 ksi at 300° C.
15. The atomized alloy powder according to claim 11 , wherein after subjecting the atomized alloy powder to an additive manufacturing process and after aging at a temperature of 400° C. for 2 hours to produce an aged alloy product, the aged alloy product has an ultimate tensile strength of at least 55 ksi at ambient temperature.
16. The atomized alloy powder according to claim 11 , wherein after subjecting the atomized alloy powder to an additive manufacturing process to generate an alloy product, the alloy product has a yield strength of at least 30 ksi at 250° C.
17. The atomized alloy powder according to claim 11 , wherein after subjecting the alloy to an additive manufacturing process and after aging the alloy at a temperature of 350° C. for 24 hours to produce an aged alloy product, the aged alloy product has an average hardness of at least 120 HV.
18. A method of using an atomized alloy powder in additive manufacturing, the method comprising:
receiving the atomized alloy powder comprising alloy particles, the alloy particles comprising, by weight percentage:
1% to 4.2% nickel;
0.5% to 2.6% erbium;
0.1% to 1.5% zirconium;
0.05% to 0.3% yttrium;
0.1% to 1.2% ytterbium; and
the balance of weight percent comprising aluminum and incidental elements and impurities,
wherein the alloy particles include L1 2 precipitates having an Al 3 X composition, where X is at least one of: erbium, zirconium, yttrium, and ytterbium;
conducting additive manufacturing with the atomized alloy powder to generate a manufactured article; and
aging the manufactured article in a heated container for a period of time.
19. The method according to claim 18 , further comprising:
removing the manufactured article from the heated container; and
cooling the manufactured article at room temperature resulting in an aged manufactured article.
20. The method according to claim 18 , wherein the aged manufactured article has an ultimate tensile strength of at least 55 ksi at 22° C.;
wherein the aged manufactured article is capable of passing a fatigue test without failure, the fatigue test including a stress amplitude of 15 ksi, a frequency of 50 Hz, an r ratio of −1, and a number of cycles being 10,000,000; and
wherein the aged manufactured article has an ultimate tensile strength of at least 20 ksi at 250° C.