Polymerizable composition for optical material and optical material and plastic lens obtainable from same composition
A polymerizable composition for an optical material according to the present invention includes one or two or more compounds selected from the group consisting of component (A): an ester compound having a specific structure and component (B): an ether compound having a specific structure, and a polymerizable compound.
1. A polymerizable composition for an optical material, comprising:
component (A);
component (B); and
a polymerizable compound,
(A) an ester compound represented by General Formula (1)
in General Formula (1), R 1 represents a hydrogen atom, a linear alkyl group having 1 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, a linear hydrocarbon group having 2 to 20 carbon atoms and having one or more unsaturated bonds, or a branched hydrocarbon group having 3 to 20 carbon atoms and having one or more unsaturated bonds, and R 2 represents a polyoxyalkylene group represented by General Formula (2)
—(CH 2 CHR 3 O) n H (2)
in General Formula (2), a plurality of present R 3 may be the same or different and each R 3 represents a hydrogen atom or a methyl group, and n represents an integer of 2 to 20,
(B) an ether compound represented by General Formula (3)
R 4 —O—R 5 (3)
(in General Formula (3), R 4 represents a linear alkyl group having 1 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, a linear hydrocarbon group having 2 to 20 carbon atoms and having one or more unsaturated bonds, or a branched hydrocarbon group having 3 to 20 carbon atoms and having one or more unsaturated bonds, and R 5 represents a linear alkyl group having 1 to 20 carbon atoms, a branched alkyl group having 3 to 20 carbon atoms, or a (poly)oxyalkylene group represented by General Formula (4))
—(CH 2 CHR 6 O) m H (4)
in General Formula (4), a plurality of present R 6 may be the same or different and each R 6 represents a hydrogen atom or a methyl group, and m represents an integer of 1 to 20,
wherein the polymerizable compound is one or two or more types of compounds selected from the group consisting of a polyiso(thio)cyanate compound, a poly(thio)epoxy compound, a polyoxetanyl compound, a polythietanyl compound, a poly(meth)acryloyl compound, a polyalkene compound, an alkyne compound, a poly(thi)ol compound, a polyamine compound, and an acid anhydride.
2. The polymerizable composition for an optical material according to claim 1 , further comprising component (C),
C) (poly)alkylene glycol represented by General Formula (5)
HO(CH 2 CHR 7 O) p H (5)
in General Formula (5), a plurality of present R7 may be the same or different and each R7 represents a hydrogen atom or a methyl group, and p represents an integer of 1 to 20.
3. The polymerizable composition for an optical material according to claim 2 , wherein a total weight of components (A), (B) and (C) in the polymerizable composition for an optical material is 0.01 to 7.5% by weight with respect to 100% by weight of the polymerizable composition for an optical material.
4. The polymerizable composition for an optical material according to claim 2 , wherein component (C) is included in a range of 0.01 to 1% by weight in 100% by weight of the polymerizable composition for an optical material.
5. A molded article obtainable by curing the polymerizable composition for an optical material according to claim 1 .
6. An optical material comprising: the molded article according to claim 5 .
7. A plastic lens comprising: the optical material according to claim 6 .
8. A method for manufacturing an optical material, comprising cast polymerizing the polymerizable composition for an optical material according to claim 1 .