Zwitterionic and glucoside surfactant formulations for fire-fighting foam applications
A composition having water and first and second surfactants having the formulas below. The values m and y are non-negative integers, and n and x are positive integers. R is a zwitterionic group. R′ is a siloxane group. A foam of the composition may be used to extinguish a fire.
1. A composition comprising:
a first surfactant having the formula:
a second surfactant having the formula:
and
water;
wherein m, x, and y are independently selected non-negative integers;
wherein n is a positive integer;
wherein R is a zwitterionic group; and
wherein R′ is a siloxane group.
2. The composition of claim 1 , wherein the first surfactant has the formula:
3. The composition of claim 1 , wherein R is a sulfobetaine group or a chlorobetaine group.
4. The composition of claim 1 , wherein m is from 0 to 20.
5. The composition of claim 1 , wherein n is from 1 to 20.
6. The composition of claim 1 , wherein x is from 0 to 4.
7. The composition of claim 1 , wherein y is from 0 to 5.
8. The composition of claim 1 , wherein the composition comprises more than one of the first surfactant or the second surfactant having different values of m, n, x, or y.
9. The composition of claim 1 , wherein first surfactant and the second surfactant have a wt. % ratio of 0.03 to 5.
10. The composition of claim 1 , wherein the composition further comprises:
a solvent having the formula:
wherein p and z are positive integers.
11. The composition of claim 10 , wherein p is from 1 to 8.
12. The composition of claim 10 , wherein z is from 1 to 6.
13. A method comprising:
mixing the composition of claim 1 with air to form a foam.
14. The method of claim 13 , further comprising:
applying the foam to a fire.
15. The method of claim 13 , further comprising:
applying the foam to a fire in an amount sufficient to extinguish the fire.
16. A method comprising:
mixing a first surfactant, a second surfactant, and water to form a composition;
wherein the first surfactant has the formula:
wherein the second surfactant has the formula:
and
water;
wherein m, x, and y are independently selected non-negative integers;
wherein n is a positive integer;
wherein R is a zwitterionic group; and
wherein R′ is a siloxane group.
17. The method of claim 16 , wherein the first surfactant has the formula:
18. The method of claim 16 , wherein the composition further comprises:
a solvent having the formula:
wherein p and z are positive integers.