Pneumatic tire having tread with three elastomers
The present invention is directed to a pneumatic tire comprising a vulcanizable rubber composition, the vulcanization rubber composition comprising: 1) 100 parts by weight of elastomer consisting of 25 to 35 phr of a styrene-butadiene rubber, 25 to 35 phr of a polybutadiene, and 35 to 45 phr of a natural rubber or synthetic polyisoprene, wherein the styrene-butadiene rubber is a functionalized solution polymerized styrene-butadiene elastomer having a glass transition temperature Tg(A) ranging from −30 to −10° C. and having at least one functional group; the natural rubber or synthetic polyisoprene has a Tg(B) ranging from −60 to −70° C.; and the polybutadiene is a cis 1,4 polybutadiene having a Tg(C) ranging from −110 to −90° C., wherein Tg(A)−Tg(B)≥25° C., and Tg(B)−Tg(C)≥25° C.; 2) 60 to 80 phr of a prehydrophobated silica; 3) 1 to 10 phr of carbon black; 4) 1 to 3 phr of rubber processing oil; and 5) 5 to 25 phr of at least one hydrocarbon resin having a Tg≥20° C., wherein the weight ratio of hydrocarbon resin to rubber processing oil is greater than 8.
1. A pneumatic tire comprising a vulcanizable rubber composition, the vulcanization rubber composition comprising:
1) 100 parts by weight of elastomer consisting of 25 to 35 phr of a styrene-butadiene rubber, 25 to 35 phr of a polybutadiene, and 35 to 45 phr of a natural rubber or synthetic polyisoprene,
wherein the styrene-butadiene rubber is a functionalized solution polymerized styrene-butadiene elastomer having a glass transition temperature Tg(A) ranging from −30 to −10° C. and having at least one functional group; the natural rubber or synthetic polyisoprene has a Tg(B) ranging from −60 to −70° C.; and the polybutadiene is a cis 1,4 polybutadiene having a Tg(C) ranging from −110 to −90° C.,
wherein Tg(A)−Tg(B)≥25° C., and Tg(B)−Tg(C)≥25° C.;
2) 60 to 80 phr of a prehydrophobated silica;
3) 1 to 10 phr of carbon black;
4) 1 to 3 phr of rubber processing oil; and
5) 5 to 25 phr of at least one hydrocarbon resin having a Tg≥20° C.; wherein the weight ratio of hydrocarbon resin to rubber processing oil is greater than 8.
6) wherein the rubber composition excludes a free silane coupling agent.
2. The pneumatic tire of claim 1 , wherein the functional group comprises at least one of an amino group, a thiol ester group, an alkoxy group, a hydroxyl group, and a silyl group.
3. The pneumatic tire of claim 1 , wherein the functional group includes an amino, an alkoxy, and a silyl group.
4. The pneumatic tire of claim 1 wherein the styrene-butadiene rubber comprises functional groups selected from the group consisting of terminal functional groups, in chain functional groups.
5. The pneumatic tire of claim 1 , wherein the amount hydrocarbon resin ranges from 10 to 20 phr.
6. The pneumatic tire of claim 1 , wherein the amount of carbon black ranges from 1 to 5 phr.
7. The pneumatic tire of claim 1 , wherein the hydrocarbon resin comprises a copolymer of styrene and alphamethylstyrene.
8. The pneumatic tire of claim 1 , wherein the weight ratio of hydrocarbon resin to oil is greater than 12.
9. The pneumatic tire of claim 1 , wherein the prehydrophobated silica comprises an alkoxysilane and an organomercaptoalkoxysilane.
10. A vulcanizable rubber composition comprising:
1) 100 parts by weight of elastomer consisting of 25 to 35 phr of a styrene-butadiene rubber, 25 to 35 phr of a polybutadiene, and 35 to 45 phr of a natural rubber or synthetic polyisoprene,
wherein the styrene-butadiene rubber is a functionalized solution polymerized styrene-butadiene elastomer having a glass transition temperature Tg(A) ranging from −30 to −10° C. and having at least one functional group; the natural rubber or synthetic polyisoprene has a Tg(B) ranging from −60 to −70° C.; and the polybutadiene is a cis 1,4 polybutadiene having a Tg(C) ranging from −110 to −90° C.,
wherein Tg(A)−Tg(B)≥25° C., and Tg(B)−Tg(C)≥25° C.;
2) 60 to 80 phr of a prehydrophobated silica;
3) 1 to 10 phr of carbon black;
4) 1 to 3 phr of rubber processing oil; and
5) 5 to 25 phr of at least one hydrocarbon resin having a Tg≥20° C.; wherein the weight ratio of hydrocarbon resin to rubber processing oil is greater than 8;
wherein the rubber composition excludes a free silane coupling agent.
11. The vulcanizable rubber composition of claim 10 , wherein the functional group comprises at least one of an amino group, a thiol ester group, an alkoxy group, a hydroxyl group, and a silyl group.
12. The vulcanizable rubber composition of claim 10 , wherein the functional group includes an amino, an alkoxy, and a silyl group.
13. The vulcanizable rubber composition of claim 10 wherein the styrene-butadiene rubber comprises functional groups selected from the group consisting of terminal functional groups, in chain functional groups.
14. The vulcanizable rubber composition of claim 10 , wherein the amount hydrocarbon resin ranges from 10 to 20 phr.
15. The vulcanizable rubber composition of claim 10 , wherein the amount of carbon black ranges from 1 to 5 phr.
16. The vulcanizable rubber composition of claim 10 , wherein the hydrocarbon resin comprises a copolymer of styrene and alphamethylstyrene.
17. The vulcanizable rubber composition of claim 10 , wherein the weight ratio of hydrocarbon resin to oil is greater than 12.
18. The vulcanizable rubber composition of claim 10 , wherein the prehydrophobated silica comprises an alkoxysilane and an organomercaptoalkoxysilane.
19. The vulcanizable rubber composition of claim 10 , in the form of at least one item selected from a tire tread, a shoe, a shoe sole, a vibration isolator, a transmission belt, a hose, a conveyor belt, and a track belt.