Electrochromic element, imaging apparatus and transmittance variable window using the same
The present disclosure includes an effective optical region within a transmittance variable region, and sets the transmittance variable region and the effective optical region so that a shortest distances from a periphery of the transmittance variable region to a periphery of the effective optical region, d 1 and d 2 , are 7.5% or more and 25% or less of a length of the transmittance variable region on a straight line including the shortest distances, L 1 , in a vertical direction.
1. An electrochromic element, comprising:
a first electrode;
a second electrode;
an electrochromic layer disposed between the first electrode and the second electrode; and
the electrochromic element having an effective optical region within a transmittance variable region,
wherein:
when a shortest distance from an end of the effective optical region to an end of the transmittance variable region is d and a length of the transmittance variable region on a straight line including the shortest distance is L in one direction in a plane of the effective optical region, d is 7.5 to 25% of L at both ends of the one direction;
the transmittance variable region includes a color inhomogeneity part; and
the color inhomogeneity part is not in the effective optical region.
2. The electrochromic element according to claim 1 , wherein the effective optical region is a quadrangle, and
the one direction is parallel to one side of the quadrangle.
3. The electrochromic element according to claim 2 , wherein the effective optical region is a square or a rectangle.
4. The electrochromic element according to claim 1 , which is configured such that the one direction is vertical in a use environment of the electrochromic element.
5. The electrochromic element according to claim 1 , wherein d is 15 to 25% of L.
6. The electrochromic element according to claim 1 , comprising metal wiring electroconductive to the first electrode or the second electrode on the outside of the effective optical region in the one direction.
7. The electrochromic element according to claim 1 , wherein a concentration of at least one of the anodic electrochromic compound and the cathodic electrochromic compound is 0.05 mol/L or more.
8. The electrochromic element according to claim 1 , wherein the anodic electrochromic compound is a dihydrophenazine derivative.
9. The electrochromic element according to claim 1 , wherein the cathodic electrochromic compound is a pyridine derivative.
10. An imaging apparatus, comprising:
a lens unit comprising a plurality of lenses;
an imaging element which receives light having passed the lens unit; and
the electrochromic element according to claim 1 disposed on a subject side of the imaging element.
11. A transmittance variable window, comprising:
a pair of transparent protective substrates;
the electrochromic element according to claim 1 disposed between the pair of transparent protective substrates; and
a window frame into which peripheral edges of the transparent protective substrates and the electrochromic element are fitted.
12. The electrochromic element according to claim 1 , wherein an average value of an index of color inhomogeneity d(ΔOD) of the color inhomogeneity part is more than 0.01.
13. The electrochromic element according to claim 1 , wherein the electrochromic layer comprises an anodic electrochromic compound and a cathodic electrochromic compound.
14. An electrochromic element, comprising:
a first electrode;
a second electrode; and
an electrochromic layer disposed between the first electrode and the second electrode,
the electrochromic element having an effective optical region within a transmittance variable region, and comprising a shield part covering a region from an end of the effective optical region to an end of the transmittance variable region along the end of the effective optical region,
wherein:
a shortest distance from the end of the effective optical region to the end of the transmittance variable region in the shield part is 7.5 to 25% of a length of the transmittance variable region on a straight line including the shortest distance;
the shielding region of the electrochromic layer includes a color inhomogeneity part; and
the effective optical region of the electrochromic layer does not include the color inhomogeneity part.
15. The electrochromic element according to claim 14 , wherein the effective optical region is a quadrangle, and
the shield part is disposed along one side of the quadrangle.
16. The electrochromic element according to claim 15 , wherein the effective optical region is a square or a rectangle.
17. The electrochromic element according to claim 14 , wherein the shield part is disposed on the opposite sides so as to sandwich the effective optical region.
18. An imaging apparatus, comprising:
a lens unit comprising a plurality of lenses;
an imaging element that receives light having passed the lens unit; and
the electrochromic element according to claim 14 disposed on a subject side of the imaging element.
19. The electrochromic element according to claim 14 , wherein an average value of an index of color inhomogeneity d(ΔOD) of the color inhomogeneity part is more than 0.01.
20. The electrochromic element according to claim 14 , wherein the electrochromic layer comprises an anodic electrochromic compound and a cathodic electrochromic compound.