Optical transparent adhesive sheet, method for producing optical transparent adhesive sheet, laminated body, and display device with touch panel
The present invention provides an optically clear adhesive sheet with reduced delay bubble generation using a thermosetting polyurethane composition that has excellent flexibility and is capable of giving a thick film. The optically clear adhesive sheet of the present invention is an optically clear adhesive sheet formed of a cured product of a thermosetting polyurethane composition, the optically clear adhesive sheet having a shear storage modulus (G′) at 85° C. of 4.5×10 3 to 5.0×10 4 Pa, a loss tangent (tan δ) at 85° C. of 0.3 to 0.97, and a thickness of 50 to 2000 μm. The optically clear adhesive sheet preferably has an adhesive strength measured by a 180° peel test of 2 N/25 mm or more.
1. An optically clear adhesive sheet comprising
a cured product of a thermosetting polyurethane composition, wherein the thermosetting polyurethane composition contains a polyol component, a polyisocyanate component, a tackifier, and a catalyst,
the polyol component consists of polyols having an olefin skeleton, wherein the polyols having the olefin skeleton are the only polyol component in the thermosetting polyurethane composition,
the polyisocyanate component is a modified polyisocyanate that is obtained by reacting an acyclic aliphatic and/or alicyclic polyisocyanate containing an isocyanate group with an ether compound containing an ethylene oxide unit,
the thermosetting polyurethane composition has an α ratio, which is the number of moles of OH groups derived from the polyol component/the number of moles of NCO groups derived from the polyisocyanate component, of 1.6 to 1.96,
an amount of the catalyst is greater than or equal to 0.001 wt % and less than or equal to 0.1 wt % with respect to a total amount of the polyol component and the polyisocyanate component,
the tackifier is a hydrogenated petroleum resin obtained by hydrogenating a copolymer of dicyclopentadiene and an aromatic compound,
an amount of the tackifier is 1 wt % to 20 wt % with respect to a total amount of the thermosetting polyurethane composition,
the polyols having the olefin skeleton is a polyolefin polyol obtained by hydrogenating a hydroxy group-terminated polyisoprene, both-end hydroxy group-terminated hydrogenated polybutadiene, or polyhydroxy polyolefin oligomer,
a number average molecular weight of the polyol component is 500-3000,
the optically clear adhesive sheet having
a shear storage modulus (G′) at 85° C. of 4.5×10 3 to 5.0×10 4 Pa,
a loss tangent (tan δ) at 85° C. of 0.3 to 0.97, and
a thickness of 50 to 2000 μm.
2. The optically clear adhesive sheet according to claim 1 , which has an adhesive strength measured by a 180° peel test of 2 N/25 mm or more.
3. The optically clear adhesive sheet according to claim 1 ,
wherein the thermosetting polyurethane composition further contains a plasticizer.
4. The optically clear adhesive sheet according to claim 3 ,
wherein the plasticizer contains a carboxylic acid-based plasticizer.
5. A method for producing the optically clear adhesive sheet according to claim 1 , the method comprising the steps of:
preparing the thermosetting polyurethane composition by mixing the polyol component, the polyisocyanate component, the tackifier, and the catalyst with stirring; and
curing the thermosetting polyurethane composition.
6. A laminate comprising:
the optically clear adhesive sheet according to claim 1 ;
a first release liner covering one surface of the optically clear adhesive sheet; and
a second release liner covering the other surface of the optically clear adhesive sheet.
7. A display device with a touchscreen, comprising:
the optically clear adhesive sheet according to claim 1 ;
a display panel; and
a touchscreen.