IP Library › Granted Patent US 11,448,033
Granted Patent B2
US 11,448,033 · App. 16/635,919 · Granted Sep 20, 2022

Delay coating for wellbore isolation device

Inventors: Michael Linley Fripp (Carrollton, TX); Xiaoguang Allan Zhong (Plano, TX); Kejia Yang (Dallas, TX); Walter Voit (Dallas, TX); Nelson Yan Loo Lee (Singapore, SG); Yong Dai Tan (Singapore, SG); Bing Hong Chee (Singapore, SG); Ee Wen Wong (Singapore, SG)
Assignees: HALLIBURTON ENERGY SERVICES, INC.; BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM
E21B33/1208C09K8/502C09K8/5086E21B33/1243
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Quick Facts
Patent No.
US 11,448,033
App. No.
16/635,919
Granted
Sep 20, 2022
Kind
B2
Abstract

A wellbore isolation device includes a mandrel, a sealing element disposed around at least a portion of the mandrel, and a delay coating disposed on at least a portion of an outer surface of the sealing element. The sealing element includes a swellable material and the delay coating covers a cross-linked polymer. The delay coating is configured to swell or degrade in a wellbore fluid.

Claims (35)

1. A wellbore isolation device comprising:

a mandrel;

a sealing element disposed around at least a portion of the mandrel, wherein the sealing element comprises a swellable material; and

a delay coating disposed on at least a portion of an outer surface of the sealing element, wherein the delay coating comprises a cross-linked polymer, and the delay coating is configured to swell or degrade in a wellbore fluid;

wherein the delay coating comprises a thiol polymer comprising a swellable functional group selected from a polyethylene glycol-based hydrogel, an aerogel, poly(lactic acid), poly(glycolic acid), poly(vinyl alcohol), and/or poly(N-isopropylacrylamide).

2. The wellbore isolation device according to claim 1 , wherein the delay coating has a glass transition temperature of from 80° F. to 180° F.

3. The wellbore isolation device according to claim 1 , wherein the delay coating has a dissolution rate in water of 0.01 mm/day to 1.0 mm/day at a temperature of 200° F.

4. The wellbore isolation device according to claim 1 , wherein the delay coating has a dissolution rate in water of 0.05 mm/day to 0.75 mm/day at a temperature of 200° F.

5. The wellbore isolation device according to claim 1 , wherein the cross-linked polymer is cross-linked by exposure to at least one of ultraviolet radiation, infrared radiation, or microwave radiation.

6. The wellbore isolation device according to claim 1 , wherein the delay coating is a tape wound around the outer surface of the sealing element.

7. The wellbore isolation device according to claim 6 , wherein the cross-linked polymer is cross-linked by exposure to at least one of ultraviolet radiation, infrared radiation, or microwave radiation.

8. The wellbore isolation device according to claim 1 , wherein the swellable functional group comprises a polyethylene glycol-based hydrogel or an aerogel.

9. The wellbore isolation device according to claim 1 , wherein the swellable functional group comprises poly(lactic acid).

10. The wellbore isolation device according to claim 1 , wherein the swellable functional group comprises poly(glycolic acid).

11. A method of isolating a portion of a wellbore comprising:

disposing a tubular string comprising a wellbore isolation device incorporated therein within a wellbore in a subterranean formation, wherein the wellbore isolation device comprises:

a cylindrical sealing element with an internal bore, wherein the sealing element comprises a swellable material that is configured to swell in a first wellbore fluid; and

a delay coating disposed on at least a portion of an outer surface of the sealing element, wherein the delay coating comprises a cross-linked polymer and is configured to swell or degrade in a second wellbore fluid,

introducing the second wellbore fluid within the wellbore to cause the delay coating to swell or degrade; and

introducing the first wellbore fluid within the wellbore to cause the sealing element to swell such that the sealing element exhibits a radial expansion,

wherein the second wellbore fluid may be the same or different from the first wellbore fluid; and

wherein the delay coating comprises a thiol polymer comprising a swellable functional group selected from a polyethylene glycol-based hydrogel, an aerogel, poly(lactic acid), poly(glycolic acid), poly(vinyl alcohol), and/or poly(N-isopropylacrylamide).

12. The method according to claim 11 , wherein the delay coating is disposed on an entire outer surface of the sealing element and provides a fluid-tight seal between the outer surface of the sealing element and the wellbore.

13. The method according to claim 11 , wherein the delay coating has a glass transition temperature of from 80° F. to 180° F.

14. The method according to claim 11 , wherein the first wellbore fluid is different from the second wellbore fluid.

15. The wellbore isolation device according to claim 11 , wherein the swellable functional group comprises a polyethylene glycol-based hydrogel or an aerogel.

16. A method of manufacturing a wellbore isolation device comprising:

disposing a sealing element around at least a portion of a cylindrical mandrel, wherein the sealing element comprises a swellable material; and

disposing a delay coating on at least a portion of an outer surface of the sealing element, wherein the delay coating comprises a cross-linked polymer and is configured to swell or degrade in a wellbore fluid,

wherein disposing the delay coating comprises spraying a first liquid onto the outer surface of the sealing element, wherein the first liquid comprises a cross-linkable polymer, and then spraying a second liquid onto the first liquid to cure the first liquid,

wherein the delay coating comprises a thiol polymer comprising a swellable functional group selected from a polyethylene glycol-based hydrogel, an aerogel, poly(lactic acid), poly(glycolic acid), poly(vinyl alcohol), and/or poly(N-isopropylacrylamide).

17. The method according to claim 16 , further comprising cross-linking the cross-linkable polymer.

18. The method according to claim 17 , wherein cross-linking the cross-linkable polymer comprises: exposing the first and second liquids to at least one of ultraviolet radiation, infrared radiation, or microwave radiation.

19. The method according to claim 16 , wherein disposing the delay coating comprises: winding a tape comprising the cross-linked polymer around the sealing element.

20. The method according to claim 16 , wherein the second liquid comprises a catalyst, a cross-linking agent, and/or a hardener.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 6, 2022
From: FRIPP, MICHAEL LINLEY; ZHONG, XIAOGUANG ALLAN; LEE, NELSON YAN LOO; TAN, YONG DAI; CHEE, BING HONG; WONG, EE WEN
To: HALLIBURTON ENERGY SERVICES, INC.
Reel/Frame 059839/0815 →
Continuity (1)
Related Publication 20210156220A1 · May 27, 2021
Cited By (1)
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