In-line, coated, biaxially oriented polypropylene film and method for the production thereof
The invention relates to a biaxially oriented polypropylene film (BOPP) comprising layers (A) to (D), wherein layers (B) to (D) contain biaxially oriented polypropylene and layer (A) contains polyurethane and nanoparticles and has a layer thickness of 25 to 300 nm, layer (B) contains polymers with functional groups that are capable of forming covalent bonds with polyurethane and is directly connected to layer (A), layer (C) has at least a layer thickness of 50% of the total thickness of the film, and layer (D) represents an outer layer of the film containing an anti-blocking agent. The invention also relates to a method for producing films of this type.
1. A polypropylene film comprising 4 layers (A) to (D), which are arranged in order from (A) to (D), wherein layers (B) to (D) comprise biaxially oriented polypropylene and wherein
layer (A) contains polyurethane and nanoparticles and has a layer thickness of 25 to 300 nm,
layer (B) further contains polymers with functional groups that are capable of forming covalent bonds with polyurethane and is directly connected to layer (A),
layer (C) has at least a layer thickness of 50% of the total thickness of the film, and
layer (D) represents an outer layer of the film and comprises an anti-blocking agent.
2. The polypropylene film according to claim 1 , wherein layer (A) has a layer thickness in the range of 50 to 150 nm.
3. The polypropylene film according to claim 1 , wherein layer (A) has nanoparticles of amorphous silicon dioxide.
4. The polypropylene film according to claim 1 , wherein layer (A) has nanoparticles of which the average particle size is in the range of 20 to 150 nm.
5. The polypropylene film according to claim 1 , wherein layer (A) contains 0.5 to 20% by weight nanoparticles.
6. The polypropylene film according to claim 1 , wherein layer (B) comprises a maleic-acid-anhydride-modified polypropylene.
7. The polypropylene film according to claim 1 , wherein layer (B) does not contain any anti-blocking agent.
8. The polypropylene film according to claim 1 , further comprises a metal layer or metal oxide layer that is directly connected to the surface of layer (A).
9. The polypropylene film according to claim 1 , wherein it has an aluminium oxide layer or silicon dioxide layer that is directly connected to the surface of layer (A).
10. A foodstuff packaging comprising a film according to claim 1 .
11. A method for producing a film according to claim 1 , comprising the steps of:
providing a sheet that is monoaxially stretched in the longitudinal direction and comprises layers (B) to (D), wherein layers (B) to (D) comprise biaxially oriented polypropylene and wherein
layer (A) contains polyurethane and nanoparticles and has a layer thickness of 25 to 300 nm,
layer (B) further contains polymers with functional groups that are capable of forming covalent bonds with polyurethane and is directly connected to layer (A),
layer (C) has at least a layer thickness of 50% of the total thickness of the film,
layer (D) represents an outer layer of the film and comprises an anti-blocking agent, and wherein layers (B) and (D) are outer layers of the sheet,
applying a layer of a liquid dispersion containing polyurethane and nanoparticles to layer (B),
drying the liquid dispersion to produce layer (A),
stretching the sheet in the transverse direction to produce a biaxially oriented film.
12. The method for producing a film according to claim 11 , comprising the steps of:
providing a sheet comprising layers (B) to (D) which are non-oriented and layers (B) and (D) are outer layers of the sheet,
applying a liquid dispersion containing polyurethane and nanoparticles to layer (B),
drying the liquid dispersion by heating to produce layer (A),
simultaneously stretching the sheet in the longitudinal direction and transverse direction to produce a biaxially oriented film.
13. The method according to claim 11 , wherein the surface of layer (B) is subjected to a corona treatment, before the liquid dispersion is applied.
14. The method according to claim 11 , wherein the liquid dispersion is applied to layer (B) by reverse gravure kiss coating.
15. The method according to claim 11 , wherein a wet layer formed by the liquid dispersion on layer (B) has a mass of 3 to 20 g/m 2 and particularly preferably 6 to 10 g/m 2 .
16. The method according to claim 11 , wherein the liquid dispersion is an aqueous dispersion.
17. The method according to claim 11 , wherein the stretching ratio in the longitudinal direction is in the range of 2 to 8.
18. The method according to claim 11 , wherein the stretching ratio in the transverse direction is in the range of 4 to 14.