IP Library Granted Patent US 11,453,769
Granted Patent B2
US 11,453,769 · App. 16/980,067 · Granted Sep 27, 2022

Modification of virgin and/or recycled construction polymers, using poly vinyl butyral (PVB), or recycled PVB from industrial waste streams and an alloying copolymer

Inventors: Jens Holmegaard (Holte, DK); Frank Mundt (Samsø, DK)
Assignee: SHARK SOLUTIONS APS
C08L27/06C08L29/04C08L29/14C08L2205/03C08L2666/68
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Quick Facts
Patent No.
US 11,453,769
App. No.
16/980,067
Granted
Sep 27, 2022
Kind
B2
Abstract

Plasticizer composition for a construction polymers. The plasticizer composition includes 35-65% (by weight) of polyvinylbutyral and 65-35% (by weight) of one or more alloying copolymers. The construction polymer is e.g. polyvinyl chloride, polypropylene, poly urethane, acryl butadiene styrene or polyethylene and/or mixtures thereof. The resulting polymer construction polymer constitutes 25-90% by weight and the plasticizer composition constitutes 10-75% by weight of the polymer blend composition. The components of the plasticizer composition are non-migrating and provide surprising physical properties of the final polymer composition.

Claims (25)

1. A polymer composition comprising a construction polymer and a plasticizer composition, wherein the construction polymer comprises 25-90% by weight and the plasticizer composition comprises 10-75% by weight of the polymer composition; and wherein said plasticizer composition comprises 35-65% (by weight) of polyvinylbutyral (PVB) and 65-35% (by weight) of one or more alloying copolymers, wherein the one or more alloying copolymers includes an Ethylene vinyl alcohol Copolymer Resin.

2. The polymer composition according to claim 1 , wherein the polyvinylbutyral component is selected from recycled polyvinylbutyral, virgin polyvinylbutyral, and a mixture thereof.

3. The polymer composition according to claim 1 , further comprising one or more other alloying copolymer, wherein the one or more other alloying copolymer is selected from the group comprising:

Ethylene copolymer based compatibilizers;

a modified ethylene acrylate carbon monoxide terpolymer composition comprising ethylene vinyl acetates (EVAs), polyethylenes, metallocene polyethylenes, ionomers, ethylene propylene rubbers, and polypropylenes;

functional polymers working as compatibilization promoter for polar polymers, ethylene vinyl acetate copolymer, and/or mixtures thereof; and

a combination thereof.

4. The polymer composition according to claim 1 , further comprising one or more other alloying copolymer.

5. The polymer composition according to claim 1 , wherein said plasticizer composition comprises 40-60% of PVB with 60-40% by weight of the alloying copolymer(s).

6. The polymer composition according to claim 1 , wherein said plasticizer composition comprises 45-55% by weight of PVB and 55-45% by weight of the alloying copolymer(s).

7. The polymer composition according to claim 1 , wherein the construction polymer is selected from polyvinyl chloride (PVC), polypropylene (PP), poly urethane (PU), acryl butadiene styrene (ABS), polyethylene (PE), and mixtures thereof.

8. The polymer composition according to claim 1 , wherein the plasticizer composition constitutes 30-50% by weight of the polymer composition.

9. The polymer composition according to claim 1 , wherein the construction polymer is selected from virgin polyvinyl chloride (PVC), or recycled polyvinyl chloride (PVC), and a mixture thereof.

10. The polymer composition according to claim 1 , wherein the polymer composition is mixed with at least one further component.

11. The polymer composition according to claim 10 , wherein the at least one further component is selected from a stabilizer, a colorant, an antioxidant, a filler, a UV filter, and a mixture thereof.

12. A method of modifying a construction polymer comprising the steps of:

mixing 25-90% by weight of the construction polymer and 10-75% by weight of a plasticizer composition, wherein the plasticizer composition comprises 35-65% (by weight) of polyvinylbutyral (PVB) and 65-35% (by weight) of one or more alloying copolymers, wherein the one or more alloying copolymers includes an Ethylene vinyl alcohol Copolymer Resin;

heating the mixed construction polymer and plasticizer composition above a melting point; and

shaping the heated mixed construction polymer and plasticizer composition.

13. The method according to claim 12 , wherein the heating is included in the shaping.

14. The method according to claim 12 , wherein the plasticizer composition comprises 45-55% (by weight) of polyvinylbutyral (PVB) and 55-45% (by weight) of an alloying copolymer.

15. The method according to claim 12 , wherein the polymer composition comprises 35-45% by weight of the plasticizer composition and 65-55% by weight of construction polymer.

16. The method according to claim 12 , comprising the step of adding at least one additional additive to the mixture of plasticizer composition and construction polymer when the polymer composition is in a solid or melted state.

17. A method for providing a polymer composition, the polymer composition comprising a construction polymer and a plasticizer composition, wherein the construction polymer comprises 25-90% by weight and the plasticizer composition comprises 10-75% by weight of the polymer composition, and wherein the plasticizer composition comprises 35-65% (by weight) of polyvinylbutyral (PVB) and 65-35% (by weight) of at least one alloying copolymer, wherein the at least one alloying copolymer includes an Ethylene vinyl alcohol Copolymer Resin, the method comprising:

modifying the construction polymer by mixing 25-90% by weight of the construction polymer and 10-75% by weight of the plasticizer composition, heating the mixed construction polymer and plasticizer composition above a melting point and shaping the heated mixed construction polymer and plasticizer composition.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 11, 2020
From: HOLMEGAARD, JENS; MUNDT, FRANK
To: SHARK SOLUTIONS APS
Reel/Frame 053746/0146 →
Priority Claims (2)
DK PA 2018 70168 · Mar 15, 2018 · national
EP 18200170 · Oct 12, 2018 · regional
Continuity (1)
Related Publication 20210024736A1 · Jan 28, 2021
Cited By (2)
US 12,326,002 US 12,649,805