Composite crystal flooring and manufacturing method thereof
Embodiments of the present disclosure disclose a composite crystal flooring. The composite crystal flooring may have a multi-layer structure. The composite crystal flooring may include a substrate layer. The substrate layer may include at least a first structural layer, a second structural layer, and a third structural layer. The second structural layer may be located between the first structural layer and the third structural layer. A foaming density of the second structural layer may be less than 1.1 grams per cubic millimeter. Components of the second structural layer may include polyvinyl chloride, one or more inorganic fillers, at least one foaming agent, at least one foaming regulator, at least one lubricating agent, and at least one stabilizer. The one or more inorganic fillers may include modified fly ash, hollow glass microbeads, and composite calcium. The composite crystal flooring with a low density may have good thermal stability and rigidity.
1. A composite crystal flooring, having a multi-layer structure, comprising:
a substrate layer, the substrate layer including at least a first structural layer, a second structural layer, and a third structural layer, the second structural layer being located between the first structural layer and the third structural layer, wherein
a foaming density of the second structural layer is less than 1.1 grams per cubic millimeter, and
components of the second structural layer includes polyvinyl chloride, one or more inorganic fillers, at least one foaming agent, at least one foaming regulator, at least one lubricating agent, and at least one stabilizer; wherein
the one or more inorganic fillers include 81 to 89 parts by weight of modified fly ash, 3 to 7 parts by weight of hollow glass microbeads, and 8 to 12 parts by weight of composite calcium.
2. The composite crystal flooring of claim 1 , wherein the components of the second structural layer include 90 to 110 parts by weight of the polyvinyl chloride, 100 to 200 parts by weight of the one or more inorganic fillers, 1.6 to 2.1 parts by weight of the at least one foaming agent, 12 to 15 parts by weight of the at least one foaming regulator, 1.7 to 2.1 parts by weight of the at least one lubricating agent, and 6.0 to 8.0 parts by weight of the at least one stabilizer.
3. The composite crystal flooring of claim 2 , wherein the at least one lubricating agent includes an internal lubricating agent and an external lubricating agent; wherein
the internal lubricating agent includes stearic acid, parts by weight of the stearic acid being within a range of 0.9 to 1.1; and
the external lubricating agent includes polyethylene wax, parts by weight of the polyethylene wax being within a range of 0.8 to 1.0.
4. The composite crystal flooring of claim 1 , wherein the modified fly ash includes microbeads, a weight content of the microbeads in the modified fly ash being within a range of 40% to 60%, and a mesh number of the modified fly ash being within a range of 325 to 400.
5. The composite crystal flooring of claim 1 , wherein components of the composite calcium include at least heavy calcium carbonate and light calcium carbonate, a mesh number of the heavy calcium carbonate being within a range of 800 to 1250, a mesh number of the light calcium carbonate being within a range of 800 to 1250, a weight content of the heavy calcium carbonate being within a range of 60% to 80%, and a weight content of the light calcium carbonate being within a range of 20% to 40%.
6. The composite crystal flooring of claim 1 , wherein the at least one foaming agent includes a yellow foaming agent and a white foaming agent, the yellow foaming agent including azodicarbonamide, and the white foaming agent including sodium bicarbonate.
7. The composite crystal flooring of claim 1 , wherein the at least one foaming regulator includes acrylics.
8. The composite crystal flooring of claim 1 , wherein when a temperature change is less than 80 degrees centigrade, a degree of deformation of the first structural layer and a degree of deformation of the third structural layer are less than 0.065%.
9. The composite crystal flooring of claim 1 , wherein components of the first structural layer includes polyvinyl chloride, one or more inorganic fillers, at least one lubricating agent, at least one stabilizer, acrylonitrile butadiene styrene (ABS) resin, and at least one plasticizer; wherein
components of the one or more inorganic fillers of the first structural layer include at least one of heavy calcium carbonate or the hollow glass microbeads, wherein a ratio of parts by weight of the hollow glass microbeads to parts by weight of the one or more inorganic fillers is not greater than 35%.
10. The composite crystal flooring of claim 9 , wherein the first structural layer includes 90 to 110 parts by weight of the polyvinyl chloride, 270 to 330 parts by weight of the one or more inorganic fillers, 0.8 to 2.6 parts by weight of the at least one lubricating agent, 3.0 to 6.0 parts by weight of the at least one stabilizer, 8 to 10 parts by weight of the ABS resin, and 5 to 15 parts by weight of the at least one plasticizer.
11. The composite crystal flooring of claim 1 , wherein components of the third structural layer includes polyvinyl chloride, one or more inorganic fillers, at least one lubricating agent, at least one stabilizer, acrylonitrile butadiene styrene (ABS) resin, and at least one plasticizer; wherein
components of the one or more inorganic fillers of the third structural layer include at least one of heavy calcium carbonate or the hollow glass microbeads, wherein a ratio of parts by weight of the hollow glass microbeads to parts by weight of the one or more inorganic fillers is not greater than 35%.
12. The composite crystal flooring of claim 11 , wherein the third structural layer includes 90 to 110 parts by weight of the polyvinyl chloride, 270 to 330 parts by weight of the one or more inorganic fillers, 0.8 to 2.6 parts by weight of the at least one lubricating agent, 3.0 to 6.0 parts by weight of the at least one stabilizer, 8 to 10 parts by weight of the ABS resin, and 5 to 15 parts by weight of the at least one plasticizer.
13. The composite crystal flooring of claim 1 , wherein the composite crystal flooring further includes a decorative layer disposed on the substrate layer, the decorative layer including at least one of an ultraviolet (UV) coating layer, a wear-resistant layer, or a color film layer.
14. The composite crystal flooring of claim 1 , wherein a density of the composite crystal flooring is within a range of 1.285 to 1.45 grams per cubic millimeter.
15. The composite crystal flooring of claim 1 , wherein when a temperature returns to 23±2 degrees centigrade after the composite crystal flooring is heated at 80 degrees centigrade for 6 hours, a thermal dimensional change rate of the composite crystal flooring is with a range of 0.065% to 0.15%.
16. A method for manufacturing the composite crystal flooring of claim 1 , comprising:
pretreating raw materials of the first structural layer, the second structural layer, and the third structural layer, respectively;
sending the pretreated raw materials of the first structural layer, the second structural layer, and the third structural layer into a coextrusion extruder; and
forming a semi-manufactured product of the substrate layer by coextruding and foaming the pretreated raw materials.
17. The method for manufacturing the composite crystal flooring of claim 16 , wherein the method further includes performing a cooling and pre-sizing treatment on the semi-manufactured product of the substrate layer.
18. The method for manufacturing the composite crystal flooring of claim 16 , wherein the method further includes:
heating the substrate layer to a third preset temperature using infrared after the substrate layer is treated by a set of calendaring rollers.
19. The method for manufacturing the composite crystal flooring of claim 18 , wherein the method further includes:
obtaining the composite crystal flooring by rolling the substrate layer heated to the third preset temperature using infrared, the color film layer, and the wear-resistant layer using the calendaring rollers through one-step forming.