Inorganic composite for rubber reinforcement, method for preparing the same, and rubber composition for tires comprising the same
The present disclosure relates to an inorganic composite, a method for producing the same, and a rubber composition for tires including the same. The inorganic composite according to the present disclosure is easy to handle, thereby improving safety of operators and productivity. Moreover, the inorganic composite makes it possible to uniformly disperse the inorganic particles in a rubber composition and to enhance the reinforcing effect. The rubber composition including the inorganic composite can be suitably used for eco-friendly tires requiring high efficiency and high fuel efficiency characteristics.
1. An inorganic composite, comprising composite secondary particles formed by agglomeration of silica primary particles and amorphous aluminosilicate primary particles, wherein the amorphous aluminosilicate primary particles have a composition represented by the following Chemical Formula 1:
M x/n [(AlO 2 ) x ,(SiO 2 ) y ]· m (H 2 O) [Chemical Formula 1]
wherein, in Chemical Formula 1,
M is an element selected from the group consisting of Li, Na, K, Rb, Cs, Be, and Fr, or ions thereof;
x>0, y>0, n>0, and m≥0;
1.0≤y/x≤10.0; and
0.01≤x/n≤1.2,
wherein the secondary particles comprise 65 to 95 wt % of the silica primary particles and 5 to 35 wt % of the amorphous aluminosilicate primary particles, and
wherein a volume of micropores having a pore size of less than 2 nm in the silica primary particles is 0.005 cm 3 /g to 0.05 cm 3 /g, and a volume of micropores having a pore size of less than 2 nm in the amorphous aluminosilicate primary particles is 0.001 cm 3 /g to 0.05 cm 3 /g.
2. The inorganic composite of claim 1 ,
wherein the silica primary particles have an average particle diameter of 10 to 100 nm, a Brunauer-Emmett-Teller surface area (S BET ) of 100 to 250 m 2 /g, and an external specific surface area (S EXT ) of 100 to 200 m 2 /g according to an analysis of nitrogen adsorption/desorption.
3. The inorganic composite of claim 1 ,
wherein the amorphous aluminosilicate primary particles have an average particle diameter of 10 to 50 nm, a Brunauer-Emmett-Teller surface area (S BET ) of 80 to 250 m 2 /g, and an external specific surface area (S EXT ) of 60 to 200 m 2 /g according to an analysis of nitrogen adsorption/desorption.
4. The inorganic composite of claim 1 ,
wherein the silica primary particles and the amorphous aluminosilicate primary particles have a ratio (S EXT /S BET ) of an external specific surface area (S EXT ) to a Bruner-Emmet-Teller surface area (S BE T) according to an analysis of nitrogen adsorption/desorption that is 0.8 to 1.0, respectively.
5. The inorganic composite of claim 1 ,
wherein the silica primary particles and the amorphous aluminosilicate primary particles have a volume of micropores (V micro ) having a pore size of less than 2 nm calculated from a micro, Bruner-Emmet-Teller surface area (S BET ) according to an analysis of nitrogen adsorption/desorption by a t-plot method that is less than 0.05 cm 3 /g.
6. The inorganic composite of claim 1 ,
wherein the secondary particles have an average particle diameter of 1 to 100 μm.
7. The inorganic composite of claim 1 , a number average primary particle diameter of the silica primary particles is 20 nm or more and 25 nm or less, a number average primary particle diameter of the amorphous aluminosilicate primary particles is 20 nm or more and 25 nm or less.
8. The inorganic composite of claim 7 , wherein the average particle diameter of the secondary particles is 25 μm or less.
9. A method for preparing the inorganic composite of claim 1 , comprising:
preparing an aqueous solution in which the silica primary particles and the amorphous aluminosilicate primary particles are dispersed; and
spray-drying the aqueous solution at a spraying rate of 0.1 to 0.5 L/h at a temperature of 150 to 250° C. to form the secondary particles.
10. The method for preparing the inorganic composite of claim 9 , wherein the aqueous solution comprises 65 to 95 wt % of the silica primary particles and 5 to 35 wt% of the amorphous aluminosilicate primary particles in solid content.
11. A rubber composition for tires comprising the inorganic composite of claim 1 and at least one diene elastomer.
12. The rubber composition for tires of claim 11 ,
wherein the diene elastomer is at least one compound selected from the group consisting of a natural rubber, polybutadiene, polyisoprene, a butadiene/styrene copolymer, a butadiene/isoprene copolymer, a butadiene/acrylonitrile copolymer, an isoprene/styrene copolymer, and a butadiene/styrene/isoprene copolymer.