IP Library › Granted Patent US 11,459,514
Granted Patent B2
US 11,459,514 · App. 15/850,658 · Granted Oct 4, 2022

Hydrocracking process and device with reduction of polynuclear aromatic compounds

Inventor: Nicolas Pupat (Houilles, FR)
Assignee: AXENS
C10G55/08B01D3/06B01D3/143B01D3/343B01D3/38C10G7/06C10G47/00C10G47/24C10G49/22C10G2300/1096C10G2300/202C10G2400/02C10G2400/06C10G2400/16C10G2400/30
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Quick Facts
Patent No.
US 11,459,514
App. No.
15/850,658
Granted
Oct 4, 2022
Kind
B2
Abstract

In the hydrocracking process in accordance with the invention, which comprises a hydrocracking section, a high pressure hot separator and a fractionation section, upstream of the fractionation section, a stripper or reboiler column type separation column is added which treats at least a portion of the heavy effluent obtained from the high pressure hot separator. All or a portion of the bottom fraction from said column, which is rich in polynuclear aromatic compounds, is purged. At least a portion of the bottom fraction obtained from the fractionation section, which is constituted by unconverted products, is recycled to the reaction section.

Claims (12)

1. A process for hydrocracking a feed, said feed comprising 20% to 100% by volume of compounds having a boiling temperature of more than 340° C., a sulphur content in the range 0.01% to 5% by weight, a nitrogen content of more than 500 ppm by weight, a cumulative nickel and vanadium content of less than 2 ppm by weight and an asphaltenes content of less than 3000 ppm by weight, said process consisting of:

a) hydrocracking said feed, at a temperature of more than 200° C., a pressure of more than 1 MPa, a space velocity in the range 0.1 to 20 h −1 and a volume ratio, in litre of hydrogen/litre of feed, in the range 80 to 5000, obtaining a hydrocracked effluent,

b) separating the effluent obtained from hydrocracking in a) carried out in a hot separation zone comprising a high pressure hot separator, said pressure being more than 0.5 MPa and less than the pressure employed in hydrocracking in a), and the temperature being in the range 200° C. to 450° C., and optionally a medium pressure hot separator at a pressure below 4.5 MPa and at a temperature in the range 200° C. to 450° C., obtaining a gaseous effluent from the head of the high pressure hot separator and a heavy effluent from the bottom of the high pressure hot separator,

c) sending the gaseous effluent obtained from b) at the head of the high pressure hot separator directly to a cold separation zone comprising a high pressure cold separator at a temperature in the range 0° C. to 200° C., and at a pressure of more than 0.5 MPa and less than the pressure employed in b), and obtaining a gaseous effluent from the head of the high pressure cold separator and a heavy effluent from the bottom of the high pressure cold separator,

d) separating the heavy effluent obtained from b), carried out in a separation column that is a stripper or a reboiler column, obtaining a gaseous effluent from the head of said column and a residue from the bottom of the column, and at least a portion of said residue, concentrated in HPNA, is eliminated by purge,

e) fractionating the heavy effluent obtained from c) and of the gaseous effluent obtained in d) in a fractionation section, and obtaining at least one naphtha fraction, at least one gas oil fraction, and a residue and recycling said residue, in part or in its entirety, to hydrocracking in a).

2. The process as claimed in claim 1 , in which the feed to a) is a hydrorefined feed.

3. The process as claimed in claim 1 , wherein in b) the heavy effluent obtained from the high pressure hot separator is treated in the medium pressure hot separator at a pressure below 4.5 MPa and at a temperature in the range 200° C. to 450° C., and a gaseous effluent and a heavy effluent are obtained, said heavy effluent being sent to d).

4. The process as claimed in claim 1 , in which the high pressure cold separator is a flash drum, a stripper or a simple distillation column, and at a pressure which is lower than the pressure of b) by 0.1 MPa to 1.0 MPa.

5. The process as claimed in claim 3 , separating in the cold separation zone the heavy effluent at a pressure of less than 4.5 MPa and at a temperature in the range 0° C. to 200° C., obtaining a gaseous effluent and a heavy effluent which are sent to step e).

6. The process as claimed in claim 1 , in which the separation d) is carried out by stripping using a gas that is hydrogen or steam at a pressure in the range 0.1 MPa to 2.0 MPa.

7. The process as claimed in claim 1 , in which the fractionation section employed in e) comprises one or more distillation columns in which the pressure is in the range 0.01 MPa to 0.5 MPa.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2018
From: PUPAT, NICOLAS
To: AXENS
Reel/Frame 045421/0432 →
Priority Claims (1)
FR 1663096 · Dec 22, 2016 · national
Continuity (1)
Related Publication 20180187101A1 · Jul 5, 2018
Cited By (4)
US 12,281,266 US 12,404,462 US 12,528,998 US 12,559,689