IP Library › Granted Patent US 11,466,026
Granted Patent B2
US 11,466,026 · App. 16/668,080 · Granted Oct 11, 2022

Organic electroluminescent materials and devices

Inventors: Zhihao Cui (Beijing, CN); Chi Yuen Raymond Kwong (Beijing, CN); Chuanjun Xia (Beijing, CN)
Assignee: BEIJING SUMMER SPROUT TECHNOLOGY CO., LTD.
C07D495/04C07D498/04C07D513/04H01L51/0074H01L51/5206H01L51/5221
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Quick Facts
Patent No.
US 11,466,026
App. No.
16/668,080
Granted
Oct 11, 2022
Kind
B2
Abstract

Organic electroluminescent materials and devices are disclosed. The organic electroluminescent materials are novel benzodithiophene or its analogous structure compounds, which can be used as charge transporting materials, hole injection materials, or the like in an electroluminescent device. These novel compounds can offer excellent performance compared with existing materials, for example, to further improve the voltage, efficiency and/or lifetime of the OLEDs.

Claims (9538)

1. A compound having Formula 1′:

wherein each of X and Y is independently selected from the group consisting of CR″R′″, NR′, O, S and Se;

wherein each of Z 1 and Z 2 is independently selected from the group consisting of O, S and Se;

wherein each of R, R′, R″ and R′″ is independently selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;

wherein each R may be same or different, and at least one of R, R′, R″ and R′″ is a group having at least on electron-withdrawing group; and

wherein adjacent substituents can be optionally joined to form a ring or a fused structure.

2. The compound according to claim 1 , wherein each of X and Y is independently selected from CR″R′″ and NR′, R′, R″ and R′″ are groups having at least one electron-withdrawing group; preferably, R, R′, R″ and R′″ are groups having at least one electron-withdrawing group.

3. The compound according to claim 1 , wherein each of X and Y is independently selected from the group consisting of O, S and Se, and at least one of R groups is a group having at least one electron-withdrawing group; preferably, both R groups are groups having at least one electron-withdrawing group.

4. The compound according to claim 1 , wherein the Hammett's constant of the electron-withdrawing group is ≥0.05, preferably ≥0.3, more preferably ≥0.5.

5. The compound according to claim 4 , wherein the electron-withdrawing group is selected from the group consisting of halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, an aza-aromatic ring group, and any one of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 ring carbon atoms, a heteroalkyl group having 1 to 20 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, an alkoxyl group having 1 to 20 carbon atoms, an aryloxy group having 6 to 30 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, a heteroaryl group having 3 to 30 carbon atoms, an alkylsilyl group having 3 to 20 carbon atoms and an arylsilyl group having 6 to 20 carbon atoms which are substituted with one or more of halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, an aza-aromatic ring group, and combinations thereof;

preferably, the electron-withdrawing group is selected from the group consisting of F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , cyano, isocyano, SCN, OCN, pyrimidinyl, triazinyl, and combinations thereof.

6. The compound according to claim 1 , wherein each of X and Y is independently selected from the group consisting of:

O, S, Se,

wherein R 1 is selected, at each occurrence, identically or differently, from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;

preferably, R 1 is selected, at each occurrence, identically or differently, from the group consisting of F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , cyano, isocyano, SCN, OCN, pentafluorophenyl, 4-cyanotetrafluorophenyl, tetrafluoropyridyl, pyrimidinyl, triazinyl, and combinations thereof;

wherein V and W are selected, at each occurrence, identically or differently, from the group consisting of CR v R w , NR v , O, S and Se;

wherein Ar is selected, at each occurrence, identically or differently, from a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, and a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms;

wherein A, R a , R b , R c , R d , R e , R f , R g , R h , R v and R w are selected, at each occurrence, identically or differently, from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;

wherein A is a group having at least one electron-withdrawing group, and for any one of the structures, when one or more of R a , R b , R c , R d , R e , R f , R g , R h , R v and R w is(are) present, at least one of R a , R b , R c , R d , R e , R f , R g , R h , R v and R w is a group having at least one electron-withdrawing group; preferably, the group having at least one electron-withdrawing group is selected from the group consisting of F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , cyano, isocyano, SCN, OCN, pentafluorophenyl, 4-cyanotetrafluorophenyl, tetrafluoropyridyl, pyrimidinyl, triazinyl, and combinations thereof.

7. The compound according to claim 1 , wherein each of X and Y is independently selected, at each occurrence, identically or differently, from the group consisting of:

O, S, Se,

8. The compound according to claim 1 , wherein each of R groups is independently selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, an unsubstituted alkyl group having 1 to 20 carbon atoms, an unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, an unsubstituted alkoxyl group having 1 to 20 carbon atoms, an unsubstituted alkenyl group having 2 to 20 carbon atoms, an unsubstituted aryl group having 6 to 30 carbon atoms, and an unsubstituted heteroaryl group having 3 to 30 carbon atoms, and any one of an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 3 to 20 ring carbon atoms, an alkoxyl group having 1 to 20 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms and a heteroaryl group having 3 to 30 carbon atoms which are substituted with one or more groups selected from the group consisting of halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, and combinations thereof;

preferably, each of R groups is independently selected from the group consisting of hydrogen, deuterium, methyl, isopropyl, NO 2 , SO 2 CH 3 , SCF 3 , C 2 F 5 , OC 2 F 5 , OCH 3 , p-methylphenyl, diphenylmethylsilyl, phenyl, methoxyphenyl, 2,6-diisopropylphenyl, biphenyl, polyfluorophenyl, difluoropyridyl, nitrophenyl, dimethylthiazolyl, vinyl substituted with one or more of CN and CF 3 , ethynyl substituted with one of CN and CF 3 , dimethylphosphoroso, diphenylphosphoroso, F, CF 3 , OCF 3 , SF 5 , SO 2 CF 3 , cyano, isocyano, SCN, OCN, trifluoromethylphenyl, trifluoromethoxyphenyl, bis(trifluoromethyl)phenyl, bis(trifluoromethoxy)phenyl, 4-cyanotetrafluorophenyl, phenyl or biphenyl substituted with one or more of F, CN and CF 3 , tetrafluoropyridyl, pyrimidinyl, triazinyl, diphenylboranyl, oxaboraanthryl, and combinations thereof.

9. The compound according to claim 8 , wherein X and Y are

10. The compound according to claim 1 , wherein each of R groups is independently selected from the group consisting of:

preferably, the two R groups in Formula 1′ are the same.

11. The compound according to claim 1 , which has the structure represented by Formula 2:

wherein in Formula 2 the structures of the two Z groups are the same, the structures of the two R groups are the same or different, and Z, X, Y and R are correspondingly selected from the atoms or groups as shown in the following table:

NO.

Z

X

Y

R

R

NO.

Z

X

Y

R

R

Compound 1

O

A1

A1

B1

B1

Compound 2

O

A1

A1

B2

B2

Compound 3

O

A1

A1

B3

B3

Compound 4

O

A1

A1

B4

B4

Compound 5

O

A1

A1

B5

B5

Compound 6

O

A1

A1

B6

B6

Compound 7

O

A1

A1

B7

B7

Compound 8

O

A1

A1

B8

B8

Compound 9

O

A1

A1

B9

B9

Compound

O

A1

A1

B10

B10

10

Compound

O

A1

A1

B11

B11

Compound

O

A1

A1

B12

B12

11

12

Compound

O

A1

A1

B13

B13

Compound

O

A1

A1

B14

B14

13

14

Compound

O

A1

A1

B15

B15

Compound

O

A1

A1

B16

B16

15

16

Compound

O

A1

A1

B17

B17

Compound

O

A1

A1

B18

B18

17

18

Compound

O

A1

A1

B19

B19

Compound

O

A1

A1

B20

B20

19

20

Compound

O

A1

A1

B21

B21

Compound

O

A1

A1

B22

B22

21

22

Compound

O

A1

A1

B23

B23

Compound

O

A1

A1

B24

B24

23

24

Compound

O

A1

A1

B25

B25

Compound

O

A1

A1

B26

B26

25

26

Compound

O

A1

A1

B27

B27

Compound

O

A1

A1

B28

B28

27

28

Compound

O

A1

A1

B29

B29

Compound

O

A1

A1

B30

B30

29

30

Compound

O

A1

A1

B31

B31

Compound

O

A1

A1

B32

B32

31

32

Compound

O

A1

A1

B33

B33

Compound

O

A1

A1

B34

B34

33

34

Compound

O

A1

A1

B35

B35

Compound

O

A1

A1

B36

B36

35

36

Compound

O

A1

A1

B37

B37

Compound

O

A1

A1

B38

B38

37

38

Compound

O

A1

A1

B39

B39

Compound

O

A1

A1

B40

B40

39

40

Compound

O

A1

A1

B41

B41

Compound

O

A1

A1

B42

B42

41

42

Compound

O

A1

A1

B43

B43

Compound

O

A1

A1

B44

B44

43

44

Compound

O

A1

A1

B45

B45

Compound

O

A1

A1

B46

B46

45

46

Compound

O

A1

A1

B47

B47

Compound

O

A1

A1

B48

B48

47

48

Compound

O

A1

A1

B49

B49

Compound

O

A1

A1

B50

B50

49

50

Compound

O

A1

A1

B51

B51

Compound

O

A1

A1

B52

B52

51

52

Compound

O

A1

A1

B53

B53

Compound

O

A1

A1

B54

B54

53

54

Compound

O

A1

A1

B55

B55

Compound

O

A1

A1

B56

B56

55

56

Compound

O

A1

A1

B57

B57

Compound

O

A1

A1

B58

B58

57

58

Compound

O

A1

A1

B59

B59

Compound

O

A1

A1

B60

B60

59

60

Compound

O

A1

A1

B61

B61

Compound

O

A1

A1

B62

B62

61

62

Compound

O

A1

A1

B63

B63

Compound

O

A1

A1

B64

B64

63

64

Compound

O

A1

A1

B65

B65

Compound

O

A1

A1

B66

B66

65

66

Compound

O

A1

A1

B67

B67

Compound

O

A1

A1

B68

B68

67

68

Compound

O

A1

A1

B69

B69

Compound

O

A1

A1

B70

B70

69

70

Compound

O

A1

A1

B71

B71

Compound

O

A1

A1

B72

B72

71

72

Compound

O

A1

A1

B73

B73

Compound

O

A1

A1

B74

B74

73

74

Compound

O

A1

A1

B75

B75

Compound

O

A1

A1

B76

B76

75

76

Compound

O

A1

A1

B77

B77

Compound

O

A1

A1

B78

B78

77

78

Compound

O

A1

A1

B79

B79

Compound

O

A1

A1

B80

B80

79

80

Compound

O

A1

A1

B81

B81

Compound

O

A1

A1

B82

B82

81

82

Compound

O

A1

A1

B83

B83

Compound

O

A1

A1

B84

B84

83

84

Compound

O

A1

A1

B85

B85

Compound

O

A1

A1

B86

B86

85

86

Compound

O

A1

A1

B87

B87

Compound

O

A1

A1

B88

B88

87

88

Compound

S

A1

A1

B1

B1

Compound

S

A1

A1

B2

B2

89

90

Compound

S

A1

A1

B3

B3

Compound

S

A1

A1

B4

B4

91

92

Compound

S

A1

A1

B5

B5

Compound

S

A1

A1

B6

B6

93

94

Compound

S

A1

A1

B7

B7

Compound

S

A1

A1

B8

B8

95

96

Compound

S

A1

A1

B9

B9

Compound

S

A1

A1

B10

B10

97

98

Compound

S

A1

A1

B11

B11

Compound

S

A1

A1

B12

B12

99

100

Compound

S

A1

A1

B13

B13

Compound

S

A1

A1

B14

B14

101

102

Compound

S

A1

A1

B15

B15

Compound

S

A1

A1

B16

B16

103

104

Compound

S

A1

A1

B17

B17

Compound

S

A1

A1

B18

B18

105

106

Compound

S

A1

A1

B19

B19

Compound

S

A1

A1

B20

B20

107

108

Compound

S

A1

A1

B21

B21

Compound

S

A1

A1

B22

B22

109

110

Compound

S

A1

A1

B23

B23

Compound

S

A1

A1

B24

B24

111

112

Compound

S

A1

A1

B25

B25

Compound

S

A1

A1

B26

B26

113

114

Compound

S

A1

A1

B27

B27

Compound

S

A1

A1

B28

B28

115

116

Compound

S

A1

A1

B29

B29

Compound

S

A1

A1

B30

B30

117

118

Compound

S

A1

A1

B31

B31

Compound

S

A1

A1

B32

B32

119

120

Compound

S

A1

A1

B33

B33

Compound

S

A1

A1

B34

B34

121

122

Compound

S

A1

A1

B35

B35

Compound

S

A1

A1

B36

B36

123

124

Compound

S

A1

A1

B37

B37

Compound

S

A1

A1

B38

B38

125

126

Compound

S

A1

A1

B39

B39

Compound

S

A1

A1

B40

B40

127

128

Compound

S

A1

A1

B41

B41

Compound

S

A1

A1

B42

B42

129

130

Compound

S

A1

A1

B43

B43

Compound

S

A1

A1

B44

B44

131

132

Compound

S

A1

A1

B45

B45

Compound

S

A1

A1

B46

B46

133

134

Compound

S

A1

A1

B47

B47

Compound

S

A1

A1

B48

B48

135

136

Compound

S

A1

A1

B49

B49

Compound

S

A1

A1

B50

B50

137

138

Compound

S

A1

A1

B51

B51

Compound

S

A1

A1

B52

B52

139

140

Compound

S

A1

A1

B53

B53

Compound

S

A1

A1

B54

B54

141

142

Compound

S

A1

A1

B55

B55

Compound

S

A1

A1

B56

B56

143

144

Compound

S

A1

A1

B57

B57

Compound

S

A1

A1

B58

B58

145

146

Compound

S

A1

A1

B59

B59

Compound

S

A1

A1

B60

B60

147

148

Compound

S

A1

A1

B61

B61

Compound

S

A1

A1

B62

B62

149

150

Compound

S

A1

A1

B63

B63

Compound

S

A1

A1

B64

B64

151

152

Compound

S

A1

A1

B65

B65

Compound

S

A1

A1

B66

B66

153

154

Compound

S

A1

A1

B67

B67

Compound

S

A1

A1

B68

B68

155

156

Compound

S

A1

A1

B69

B69

Compound

S

A1

A1

B70

B70

157

158

Compound

S

A1

A1

B71

B71

Compound

S

A1

A1

B72

B72

159

160

Compound

S

A1

A1

B73

B73

Compound

S

A1

A1

B74

B74

161

162

Compound

S

A1

A1

B75

B75

Compound

S

A1

A1

B76

B76

163

164

Compound

S

A1

A1

B77

B77

Compound

S

A1

A1

B78

B78

165

166

Compound

S

A1

A1

B79

B79

Compound

S

A1

A1

B80

B80

167

168

Compound

S

A1

A1

B81

B81

Compound

S

A1

A1

B82

B82

169

170

Compound

S

A1

A1

B83

B83

Compound

S

A1

A1

B84

B84

171

172

Compound

S

A1

A1

B85

B85

Compound

S

A1

A1

B86

B86

173

174

Compound

S

A1

A1

B87

B87

Compound

S

A1

A1

B88

B88

175

176

Compound

Se

A1

A1

B1

B1

Compound

Se

A1

A1

B2

B2

177

178

Compound

Se

A1

A1

B3

B3

Compound

Se

A1

A1

B4

B4

179

180

Compound

Se

A1

A1

B5

B5

Compound

Se

A1

A1

B6

B6

181

182

Compound

Se

A1

A1

B7

B7

Compound

Se

A1

A1

B8

B8

183

184

Compound

Se

A1

A1

B9

B9

Compound

Se

A1

A1

B10

B10

185

186

Compound

Se

A1

A1

B11

B11

Compound

Se

A1

A1

B12

B12

187

188

Compound

Se

A1

A1

B13

B13

Compound

Se

A1

A1

B14

B14

189

190

Compound

Se

A1

A1

B15

B15

Compound

Se

A1

A1

B16

B16

191

192

Compound

Se

A1

A1

B17

B17

Compound

Se

A1

A1

B18

B18

193

194

Compound

Se

A1

A1

B19

B19

Compound

Se

A1

A1

B20

B20

195

196

Compound

Se

A1

A1

B21

B21

Compound

Se

A1

A1

B22

B22

197

198

Compound

Se

A1

A1

B23

B23

Compound

Se

A1

A1

B24

B24

199

200

Compound

Se

A1

A1

B25

B25

Compound

Se

A1

A1

B26

B26

201

202

Compound

Se

A1

A1

B27

B27

Compound

Se

A1

A1

B28

B28

203

204

Compound

Se

A1

A1

B29

B29

Compound

Se

A1

A1

B30

B30

205

206

Compound

Se

A1

A1

B31

B31

Compound

Se

A1

A1

B32

B32

207

208

Compound

Se

A1

A1

B33

B33

Compound

Se

A1

A1

B34

B34

209

210

Compound

Se

A1

A1

B35

B35

Compound

Se

A1

A1

B36

B36

211

212

Compound

Se

A1

A1

B37

B37

Compound

Se

A1

A1

B38

B38

213

214

Compound

Se

A1

A1

B39

B39

Compound

Se

A1

A1

B40

B40

215

216

Compound

Se

A1

A1

B41

B41

Compound

Se

A1

A1

B42

B42

217

218

Compound

Se

A1

A1

B43

B43

Compound

Se

A1

A1

B44

B44

219

220

Compound

Se

A1

A1

B45

B45

Compound

Se

A1

A1

B46

B46

221

222

Compound

Se

A1

A1

B47

B47

Compound

Se

A1

A1

B48

B48

223

224

Compound

Se

A1

A1

B49

B49

Compound

Se

A1

A1

B50

B50

225

226

Compound

Se

A1

A1

B51

B51

Compound

Se

A1

A1

B52

B52

227

228

Compound

Se

A1

A1

B53

B53

Compound

Se

A1

A1

B54

B54

229

230

Compound

Se

A1

A1

B55

B55

Compound

Se

A1

A1

B56

B56

231

232

Compound

Se

A1

A1

B57

B57

Compound

Se

A1

A1

B58

B58

233

234

Compound

Se

A1

A1

B59

B59

Compound

Se

A1

A1

B60

B60

235

236

Compound

Se

A1

A1

B61

B61

Compound

Se

A1

A1

B62

B62

237

238

Compound

Se

A1

A1

B63

B63

Compound

Se

A1

A1

B64

B64

239

240

Compound

Se

A1

A1

B65

B65

Compound

Se

A1

A1

B66

B66

241

242

Compound

Se

A1

A1

B67

B67

Compound

Se

A1

A1

B68

B68

243

244

Compound

Se

A1

A1

B69

B69

Compound

Se

A1

A1

B70

B70

245

246

Compound

Se

A1

A1

B71

B71

Compound

Se

A1

A1

B72

B72

247

248

Compound

Se

A1

A1

B73

B73

Compound

Se

A1

A1

B74

B74

249

250

Compound

Se

A1

A1

B75

B75

Compound

Se

A1

A1

B76

B76

251

252

Compound

Se

A1

A1

B77

B77

Compound

Se

A1

A1

B78

B78

253

254

Compound

Se

A1

A1

B79

B79

Compound

Se

A1

A1

B80

B80

255

256

Compound

Se

A1

A1

B81

B81

Compound

Se

A1

A1

B82

B82

257

258

Compound

Se

A1

A1

B83

B83

Compound

Se

A1

A1

B84

B84

259

260

Compound

Se

A1

A1

B85

B85

Compound

Se

A1

A1

B86

B86

261

262

Compound

Se

A1

A1

B87

B87

Compound

Se

A1

A1

B88

B88

263

264

Compound

O

A2

A2

B1

B1

Compound

O

A2

A2

B6

B6

265

266

Compound

O

A2

A2

B10

B10

Compound

O

A2

A2

B16

B16

267

268

Compound

O

A2

A2

B25

B25

Compound

O

A2

A2

B28

B28

269

270

Compound

O

A2

A2

B29

B29

Compound

O

A2

A2

B30

B30

271

272

Compound

O

A2

A2

B38

B38

Compound

O

A2

A2

B39

B39

273

274

Compound

O

A2

A2

B40

B40

Compound

O

A2

A2

B41

B41

275

276

Compound

O

A2

A2

B43

B43

Compound

O

A2

A2

B52

B52

277

278

Compound

O

A2

A2

B56

B56

Compound

O

A2

A2

B67

B67

279

280

Compound

O

A2

A2

B68

B68

Compound

O

A2

A2

B69

B69

281

282

Compound

O

A2

A2

B70

B70

Compound

O

A2

A2

B71

B71

283

284

Compound

O

A2

A2

B72

B72

Compound

O

A2

A2

B74

B74

285

286

Compound

O

A2

A2

B79

B79

Compound

O

A2

A2

B80

B80

287

288

Compound

O

A2

A2

B82

B82

Compound

O

A2

A2

B83

B83

289

290

Compound

O

A2

A2

B86

B86

Compound

O

A2

A2

B88

B88

291

292

Compound

S

A2

A2

B1

B1

Compound

S

A2

A2

B6

B6

293

294

Compound

S

A2

A2

B10

B10

Compound

S

A2

A2

B16

B16

295

296

Compound

S

A2

A2

B25

B25

Compound

S

A2

A2

B28

B28

297

298

Compound

S

A2

A2

B29

B29

Compound

S

A2

A2

B30

B30

299

300

Compound

S

A2

A2

B38

B38

Compound

S

A2

A2

B39

B39

301

302

Compound

S

A2

A2

B40

B40

Compound

S

A2

A2

B41

B41

303

304

Compound

S

A2

A2

B43

B43

Compound

S

A2

A2

B52

B52

305

306

Compound

S

A2

A2

B56

B56

Compound

S

A2

A2

B67

B67

307

308

Compound

S

A2

A2

B68

B68

Compound

S

A2

A2

B69

B69

309

310

Compound

S

A2

A2

B70

B70

Compound

S

A2

A2

B71

B71

311

312

Compound

S

A2

A2

B72

B72

Compound

S

A2

A2

B74

B74

313

314

Compound

S

A2

A2

B79

B79

Compound

S

A2

A2

B80

B80

315

316

Compound

S

A2

A2

B82

B82

Compound

S

A2

A2

B83

B83

317

318

Compound

S

A2

A2

B86

B86

Compound

S

A2

A2

B88

B88

319

320

Compound

Se

A2

A2

B1

B1

Compound

Se

A2

A2

B6

B6

321

322

Compound

Se

A2

A2

B10

B10

Compound

Se

A2

A2

B16

B16

323

324

Compound

Se

A2

A2

B25

B25

Compound

Se

A2

A2

B28

B28

325

326

Compound

Se

A2

A2

B29

B29

Compound

Se

A2

A2

B30

B30

327

328

Compound

Se

A2

A2

B38

B38

Compound

Se

A2

A2

B39

B39

329

330

Compound

Se

A2

A2

B40

B40

Compound

Se

A2

A2

B41

B41

331

332

Compound

Se

A2

A2

B43

B43

Compound

Se

A2

A2

B52

B52

333

334

Compound

Se

A2

A2

B56

B56

Compound

Se

A2

A2

B67

B67

335

336

Compound

Se

A2

A2

B68

B68

Compound

Se

A2

A2

B69

B69

337

338

Compound

Se

A2

A2

B70

B70

Compound

Se

A2

A2

B71

B71

339

340

Compound

Se

A2

A2

B72

B72

Compound

Se

A2

A2

B74

B74

341

342

Compound

Se

A2

A2

B79

B79

Compound

Se

A2

A2

B80

B80

343

344

Compound

Se

A2

A2

B82

B82

Compound

Se

A2

A2

B83

B83

345

346

Compound

Se

A2

A2

B86

B86

Compound

Se

A2

A2

B88

B88

347

348

Compound

O

A3

A3

B1

B1

Compound

O

A3

A3

B6

B6

349

350

Compound

O

A3

A3

B10

B10

Compound

O

A3

A3

B16

B16

351

352

Compound

O

A3

A3

B25

B25

Compound

O

A3

A3

B28

B28

353

354

Compound

O

A3

A3

B29

B29

Compound

O

A3

A3

B30

B30

355

356

Compound

O

A3

A3

B38

B38

Compound

O

A3

A3

B39

B39

357

358

Compound

O

A3

A3

B40

B40

Compound

O

A3

A3

B41

B41

359

360

Compound

O

A3

A3

B43

B43

Compound

O

A3

A3

B52

B52

361

362

Compound

O

A3

A3

B56

B56

Compound

O

A3

A3

B67

B67

363

364

Compound

O

A3

A3

B68

B68

Compound

O

A3

A3

B69

B69

365

366

Compound

O

A3

A3

B70

B70

Compound

O

A3

A3

B71

B71

367

368

Compound

O

A3

A3

B72

B72

Compound

O

A3

A3

B74

B74

369

370

Compound

O

A3

A3

B79

B79

Compound

O

A3

A3

B80

B80

371

372

Compound

O

A3

A3

B82

B82

Compound

O

A3

A3

B83

B83

373

374

Compound

O

A3

A3

B86

B86

Compound

O

A3

A3

B88

B88

375

376

Compound

S

A3

A3

B1

B1

Compound

S

A3

A3

B6

B6

377

378

Compound

S

A3

A3

B10

B10

Compound

S

A3

A3

B16

B16

379

380

Compound

S

A3

A3

B25

B25

Compound

S

A3

A3

B28

B28

381

382

Compound

S

A3

A3

B29

B29

Compound

S

A3

A3

B30

B30

383

384

Compound

S

A3

A3

B38

B38

Compound

S

A3

A3

B39

B39

385

386

Compound

S

A3

A3

B40

B40

Compound

S

A3

A3

B41

B41

387

388

Compound

S

A3

A3

B43

B43

Compound

S

A3

A3

B52

B52

389

390

Compound

S

A3

A3

B56

B56

Compound

S

A3

A3

B67

B67

391

392

Compound

S

A3

A3

B68

B68

Compound

S

A3

A3

B69

B69

393

394

Compound

S

A3

A3

B70

B70

Compound

S

A3

A3

B71

B71

395

396

Compound

S

A3

A3

B72

B72

Compound

S

A3

A3

B74

B74

397

398

Compound

S

A3

A3

B79

B79

Compound

S

A3

A3

B80

B80

399

400

Compound

S

A3

A3

B82

B82

Compound

S

A3

A3

B83

B83

401

402

Compound

S

A3

A3

B86

B86

Compound

S

A3

A3

B88

B88

403

404

Compound

Se

A3

A3

B1

B1

Compound

Se

A3

A3

B6

B6

405

406

Compound

Se

A3

A3

B10

B10

Compound

Se

A3

A3

B16

B16

407

408

Compound

Se

A3

A3

B25

B25

Compound

Se

A3

A3

B28

B28

409

410

Compound

Se

A3

A3

B29

B29

Compound

Se

A3

A3

B30

B30

411

412

Compound

Se

A3

A3

B38

B38

Compound

Se

A3

A3

B39

B39

413

414

Compound

Se

A3

A3

B40

B40

Compound

Se

A3

A3

B41

B41

415

416

Compound

Se

A3

A3

B43

B43

Compound

Se

A3

A3

B52

B52

417

418

Compound

Se

A3

A3

B56

B56

Compound

Se

A3

A3

B67

B67

419

420

Compound

Se

A3

A3

B68

B68

Compound

Se

A3

A3

B69

B69

421

422

Compound

Se

A3

A3

B70

B70

Compound

Se

A3

A3

B71

B71

423

424

Compound

Se

A3

A3

B72

B72

Compound

Se

A3

A3

B74

B74

425

426

Compound

Se

A3

A3

B79

B79

Compound

Se

A3

A3

B80

B80

427

428

Compound

Se

A3

A3

B82

B82

Compound

Se

A3

A3

B83

B83

429

430

Compound

Se

A3

A3

B86

B86

Compound

Se

A3

A3

B88

B88

431

432

Compound

O

A4

A4

B1

B1

Compound

O

A4

A4

B6

B6

433

434

Compound

O

A4

A4

B10

B10

Compound

O

A4

A4

B16

B16

435

436

Compound

O

A4

A4

B25

B25

Compound

O

A4

A4

B28

B28

437

438

Compound

O

A4

A4

B29

B29

Compound

O

A4

A4

B30

B30

439

440

Compound

O

A4

A4

B38

B38

Compound

O

A4

A4

B39

B39

441

442

Compound

O

A4

A4

B40

B40

Compound

O

A4

A4

B41

B41

443

444

Compound

O

A4

A4

B43

B43

Compound

O

A4

A4

B52

B52

445

446

Compound

O

A4

A4

B56

B56

Compound

O

A4

A4

B67

B67

447

448

Compound

O

A4

A4

B68

B68

Compound

O

A4

A4

B69

B69

449

450

Compound

O

A4

A4

B70

B70

Compound

O

A4

A4

B71

B71

451

452

Compound

O

A4

A4

B72

B72

Compound

O

A4

A4

B74

B74

453

454

Compound

O

A4

A4

B79

B79

Compound

O

A4

A4

B80

B80

455

456

Compound

O

A4

A4

B82

B82

Compound

O

A4

A4

B83

B83

457

458

Compound

O

A4

A4

B86

B86

Compound

O

A4

A4

B88

B88

459

460

Compound

S

A4

A4

B1

B1

Compound

S

A4

A4

B6

B6

461

462

Compound

S

A4

A4

B10

B10

Compound

S

A4

A4

B16

B16

463

464

Compound

S

A4

A4

B25

B25

Compound

S

A4

A4

B28

B28

465

466

Compound

S

A4

A4

B29

B29

Compound

S

A4

A4

B30

B30

467

468

Compound

S

A4

A4

B38

B38

Compound

S

A4

A4

B39

B39

469

470

Compound

S

A4

A4

B40

B40

Compound

S

A4

A4

B41

B41

471

472

Compound

S

A4

A4

B43

B43

Compound

S

A4

A4

B52

B52

473

474

Compound

S

A4

A4

B56

B56

Compound

S

A4

A4

B67

B67

475

476

Compound

S

A4

A4

B68

B68

Compound

S

A4

A4

B69

B69

477

478

Compound

S

A4

A4

B70

B70

Compound

S

A4

A4

B71

B71

479

480

Compound

S

A4

A4

B72

B72

Compound

S

A4

A4

B74

B74

481

482

Compound

S

A4

A4

B79

B79

Compound

S

A4

A4

B80

B80

483

484

Compound

S

A4

A4

B82

B82

Compound

S

A4

A4

B83

B83

485

486

Compound

S

A4

A4

B86

B86

Compound

S

A4

A4

B88

B88

487

488

Compound

Se

A4

A4

B1

B1

Compound

Se

A4

A4

B6

B6

489

490

Compound

Se

A4

A4

B10

B10

Compound

Se

A4

A4

B16

B16

491

492

Compound

Se

A4

A4

B25

B25

Compound

Se

A4

A4

B28

B28

493

494

Compound

Se

A4

A4

B29

B29

Compound

Se

A4

A4

B30

B30

495

496

Compound

Se

A4

A4

B38

B38

Compound

Se

A4

A4

B39

B39

497

498

Compound

Se

A4

A4

B40

B40

Compound

Se

A4

A4

B41

B41

499

500

Compound

Se

A4

A4

B43

B43

Compound

Se

A4

A4

B52

B52

501

502

Compound

Se

A4

A4

B56

B56

Compound

Se

A4

A4

B67

B67

503

504

Compound

Se

A4

A4

B68

B68

Compound

Se

A4

A4

B69

B69

505

506

Compound

Se

A4

A4

B70

B70

Compound

Se

A4

A4

B71

B71

507

508

Compound

Se

A4

A4

B72

B72

Compound

Se

A4

A4

B74

B74

509

510

Compound

Se

A4

A4

B79

B79

Compound

Se

A4

A4

B80

B80

511

512

Compound

Se

A4

A4

B82

B82

Compound

Se

A4

A4

B83

B83

513

514

Compound

Se

A4

A4

B86

B86

Compound

Se

A4

A4

B88

B88

515

516

Compound

O

A5

A5

B1

B1

Compound

O

A5

A5

B6

B6

517

518

Compound

O

A5

A5

B10

B10

Compound

O

A5

A5

B16

B16

519

520

Compound

O

A5

A5

B25

B25

Compound

O

A5

A5

B28

B28

521

522

Compound

O

A5

A5

B29

B29

Compound

O

A5

A5

B30

B30

523

524

Compound

O

A5

A5

B38

B38

Compound

O

A5

A5

B39

B39

525

526

Compound

O

A5

A5

B40

B40

Compound

O

A5

A5

B41

B41

527

528

Compound

O

A5

A5

B43

B43

Compound

O

A5

A5

B52

B52

529

530

Compound

O

A5

A5

B56

B56

Compound

O

A5

A5

B67

B67

531

532

Compound

O

A5

A5

B68

B68

Compound

O

A5

A5

B69

B69

533

534

Compound

O

A5

A5

B70

B70

Compound

O

A5

A5

B71

B71

535

536

Compound

O

A5

A5

B72

B72

Compound

O

A5

A5

B74

B74

537

538

Compound

O

A5

A5

B79

B79

Compound

O

A5

A5

B80

B80

539

540

Compound

O

A5

A5

B82

B82

Compound

O

A5

A5

B83

B83

541

542

Compound

O

A5

A5

B86

B86

Compound

O

A5

A5

B88

B88

543

544

Compound

S

A5

A5

B1

B1

Compound

S

A5

A5

B6

B6

545

546

Compound

S

A5

A5

B10

B10

Compound

S

A5

A5

B16

B16

547

548

Compound

S

A5

A5

B25

B25

Compound

S

A5

A5

B28

B28

549

550

Compound

S

A5

A5

B29

B29

Compound

S

A5

A5

B30

B30

551

552

Compound

S

A5

A5

B38

B38

Compound

S

A5

A5

B39

B39

553

554

Compound

S

A5

A5

B40

B40

Compound

S

A5

A5

B41

B41

555

556

Compound

S

A5

A5

B43

B43

Compound

S

A5

A5

B52

B52

557

558

Compound

S

A5

A5

B56

B56

Compound

S

A5

A5

B67

B67

559

560

Compound

S

A5

A5

B68

B68

Compound

S

A5

A5

B69

B69

561

562

Compound

S

A5

A5

B70

B70

Compound

S

A5

A5

B71

B71

563

564

Compound

S

A5

A5

B72

B72

Compound

S

A5

A5

B74

B74

565

566

Compound

S

A5

A5

B79

B79

Compound

S

A5

A5

B80

B80

567

568

Compound

S

A5

A5

B82

B82

Compound

S

A5

A5

B83

B83

569

570

Compound

S

A5

A5

B86

B86

Compound

S

A5

A5

B88

B88

571

572

Compound

Se

A5

A5

B1

B1

Compound

Se

A5

A5

B6

B6

573

574

Compound

Se

A5

A5

B10

B10

Compound

Se

A5

A5

B16

B16

575

576

Compound

Se

A5

A5

B25

B25

Compound

Se

A5

A5

B28

B28

577

578

Compound

Se

A5

A5

B29

B29

Compound

Se

A5

A5

B30

B30

579

580

Compound

Se

A5

A5

B38

B38

Compound

Se

A5

A5

B39

B39

581

582

Compound

Se

A5

A5

B40

B40

Compound

Se

A5

A5

B41

B41

583

584

Compound

Se

A5

A5

B43

B43

Compound

Se

A5

A5

B52

B52

585

586

Compound

Se

A5

A5

B56

B56

Compound

Se

A5

A5

B67

B67

587

588

Compound

Se

A5

A5

B68

B68

Compound

Se

A5

A5

B69

B69

589

590

Compound

Se

A5

A5

B70

B70

Compound

Se

A5

A5

B71

B71

591

592

Compound

Se

A5

A5

B72

B72

Compound

Se

A5

A5

B74

B74

593

594

Compound

Se

A5

A5

B79

B79

Compound

Se

A5

A5

B80

B80

595

596

Compound

Se

A5

A5

B82

B82

Compound

Se

A5

A5

B83

B83

597

598

Compound

Se

A5

A5

B86

B86

Compound

Se

A5

A5

B88

B88

599

600

Compound

O

A6

A6

B1

B1

Compound

O

A6

A6

B6

B6

601

602

Compound

O

A6

A6

B10

B10

Compound

O

A6

A6

B16

B16

603

604

Compound

O

A6

A6

B25

B25

Compound

O

A6

A6

B28

B28

605

606

Compound

O

A6

A6

B29

B29

Compound

O

A6

A6

B30

B30

607

608

Compound

O

A6

A6

B38

B38

Compound

O

A6

A6

B39

B39

609

610

Compound

O

A6

A6

B40

B40

Compound

O

A6

A6

B41

B41

611

612

Compound

O

A6

A6

B43

B43

Compound

O

A6

A6

B52

B52

613

614

Compound

O

A6

A6

B56

B56

Compound

O

A6

A6

B67

B67

615

616

Compound

O

A6

A6

B68

B68

Compound

O

A6

A6

B69

B69

617

618

Compound

O

A6

A6

B70

B70

Compound

O

A6

A6

B71

B71

619

620

Compound

O

A6

A6

B72

B72

Compound

O

A6

A6

B74

B74

621

622

Compound

O

A6

A6

B79

B79

Compound

O

A6

A6

B80

B80

623

624

Compound

O

A6

A6

B82

B82

Compound

O

A6

A6

B83

B83

625

626

Compound

O

A6

A6

B86

B86

Compound

O

A6

A6

B88

B88

627

628

Compound

S

A6

A6

B1

B1

Compound

S

A6

A6

B6

B6

629

630

Compound

S

A6

A6

B10

B10

Compound

S

A6

A6

B16

B16

631

632

Compound

S

A6

A6

B25

B25

Compound

S

A6

A6

B28

B28

633

634

Compound

S

A6

A6

B29

B29

Compound

S

A6

A6

B30

B30

635

636

Compound

S

A6

A6

B38

B38

Compound

S

A6

A6

B39

B39

637

638

Compound

S

A6

A6

B40

B40

Compound

S

A6

A6

B41

B41

639

640

Compound

S

A6

A6

B43

B43

Compound

S

A6

A6

B52

B52

641

642

Compound

S

A6

A6

B56

B56

Compound

S

A6

A6

B67

B67

643

644

Compound

S

A6

A6

B68

B68

Compound

S

A6

A6

B69

B69

645

646

Compound

S

A6

A6

B70

B70

Compound

S

A6

A6

B71

B71

647

648

Compound

S

A6

A6

B72

B72

Compound

S

A6

A6

B74

B74

649

650

Compound

S

A6

A6

B79

B79

Compound

S

A6

A6

B80

B80

651

652

Compound

S

A6

A6

B82

B82

Compound

S

A6

A6

B83

B83

653

654

Compound

S

A6

A6

B86

B86

Compound

S

A6

A6

B88

B88

655

656

Compound

Se

A6

A6

B1

B1

Compound

Se

A6

A6

B6

B6

657

658

Compound

Se

A6

A6

B10

B10

Compound

Se

A6

A6

B16

B16

659

660

Compound

Se

A6

A6

B25

B25

Compound

Se

A6

A6

B28

B28

661

662

Compound

Se

A6

A6

B29

B29

Compound

Se

A6

A6

B30

B30

663

664

Compound

Se

A6

A6

B38

B38

Compound

Se

A6

A6

B39

B39

665

666

Compound

Se

A6

A6

B40

B40

Compound

Se

A6

A6

B41

B41

667

668

Compound

Se

A6

A6

B43

B43

Compound

Se

A6

A6

B52

B52

669

670

Compound

Se

A6

A6

B56

B56

Compound

Se

A6

A6

B67

B67

671

672

Compound

Se

A6

A6

B68

B68

Compound

Se

A6

A6

B69

B69

673

674

Compound

Se

A6

A6

B70

B70

Compound

Se

A6

A6

B71

B71

675

676

Compound

Se

A6

A6

B72

B72

Compound

Se

A6

A6

B74

B74

677

678

Compound

Se

A6

A6

B79

B79

Compound

Se

A6

A6

B80

B80

679

680

Compound

Se

A6

A6

B82

B82

Compound

Se

A6

A6

B83

B83

681

682

Compound

Se

A6

A6

B86

B86

Compound

Se

A6

A6

B88

B88

683

684

Compound

O

A7

A7

B1

B1

Compound

O

A7

A7

B6

B6

685

686

Compound

O

A7

A7

B10

B10

Compound

O

A7

A7

B16

B16

687

688

Compound

O

A7

A7

B25

B25

Compound

O

A7

A7

B28

B28

689

690

Compound

O

A7

A7

B29

B29

Compound

O

A7

A7

B30

B30

691

692

Compound

O

A7

A7

B38

B38

Compound

O

A7

A7

B39

B39

693

694

Compound

O

A7

A7

B40

B40

Compound

O

A7

A7

B41

B41

695

696

Compound

O

A7

A7

B43

B43

Compound

O

A7

A7

B52

B52

697

698

Compound

O

A7

A7

B56

B56

Compound

O

A7

A7

B67

B67

699

700

Compound

O

A7

A7

B68

B68

Compound

O

A7

A7

B69

B69

701

702

Compound

O

A7

A7

B70

B70

Compound

O

A7

A7

B71

B71

703

704

Compound

O

A7

A7

B72

B72

Compound

O

A7

A7

B74

B74

705

706

Compound

O

A7

A7

B79

B79

Compound

O

A7

A7

B80

B80

707

708

Compound

O

A7

A7

B82

B82

Compound

O

A7

A7

B83

B83

709

710

Compound

O

A7

A7

B86

B86

Compound

O

A7

A7

B88

B88

711

712

Compound

S

A7

A7

B1

B1

Compound

S

A7

A7

B6

B6

713

714

Compound

S

A7

A7

B10

B10

Compound

S

A7

A7

B16

B16

715

716

Compound

S

A7

A7

B25

B25

Compound

S

A7

A7

B28

B28

717

718

Compound

S

A7

A7

B29

B29

Compound

S

A7

A7

B30

B30

719

720

Compound

S

A7

A7

B38

B38

Compound

S

A7

A7

B39

B39

721

722

Compound

S

A7

A7

B40

B40

Compound

S

A7

A7

B41

B41

723

724

Compound

S

A7

A7

B43

B43

Compound

S

A7

A7

B52

B52

725

726

Compound

S

A7

A7

B56

B56

Compound

S

A7

A7

B67

B67

727

728

Compound

S

A7

A7

B68

B68

Compound

S

A7

A7

B69

B69

729

730

Compound

S

A7

A7

B70

B70

Compound

S

A7

A7

B71

B71

731

732

Compound

S

A7

A7

B72

B72

Compound

S

A7

A7

B74

B74

733

734

Compound

S

A7

A7

B79

B79

Compound

S

A7

A7

B80

B80

735

736

Compound

S

A7

A7

B82

B82

Compound

S

A7

A7

B83

B83

737

738

Compound

S

A7

A7

B86

B86

Compound

S

A7

A7

B88

B88

739

740

Compound

Se

A7

A7

B1

B1

Compound

Se

A7

A7

B6

B6

741

742

Compound

Se

A7

A7

B10

B10

Compound

Se

A7

A7

B16

B16

743

744

Compound

Se

A7

A7

B25

B25

Compound

Se

A7

A7

B28

B28

745

746

Compound

Se

A7

A7

B29

B29

Compound

Se

A7

A7

B30

B30

747

748

Compound

Se

A7

A7

B38

B38

Compound

Se

A7

A7

B39

B39

749

750

Compound

Se

A7

A7

B40

B40

Compound

Se

A7

A7

B41

B41

751

752

Compound

Se

A7

A7

B43

B43

Compound

Se

A7

A7

B52

B52

753

754

Compound

Se

A7

A7

B56

B56

Compound

Se

A7

A7

B67

B67

755

756

Compound

Se

A7

A7

B68

B68

Compound

Se

A7

A7

B69

B69

757

758

Compound

Se

A7

A7

B70

B70

Compound

Se

A7

A7

B71

B71

759

760

Compound

Se

A7

A7

B72

B72

Compound

Se

A7

A7

B74

B74

761

762

Compound

Se

A7

A7

B79

B79

Compound

Se

A7

A7

B80

B80

763

764

Compound

Se

A7

A7

B82

B82

Compound

Se

A7

A7

B83

B83

765

766

Compound

Se

A7

A7

B86

B86

Compound

Se

A7

A7

B88

B88

767

768

Compound

O

O

O

B1

B1

Compound

O

O

O

B6

B6

769

770

Compound

O

O

O

B10

B10

Compound

O

O

O

B22

B22

771

772

Compound

O

O

O

B25

B25

Compound

O

O

O

B28

B28

773

774

Compound

O

O

O

B29

B29

Compound

O

O

O

B30

B30

775

776

Compound

O

O

O

B38

B38

Compound

O

O

O

B39

B39

777

778

Compound

O

O

O

B40

B40

Compound

O

O

O

B41

B41

779

780

Compound

O

O

O

B43

B43

Compound

O

O

O

B52

B52

781

782

Compound

O

O

O

B56

B56

Compound

O

O

O

B67

B67

783

784

Compound

O

O

O

B68

B68

Compound

O

O

O

B69

B69

785

786

Compound

O

O

O

B70

B70

Compound

O

O

O

B71

B71

787

788

Compound

O

O

O

B72

B72

Compound

O

O

O

B74

B74

789

790

Compound

O

O

O

B79

B79

Compound

O

O

O

B80

B80

791

792

Compound

O

O

O

B82

B82

Compound

O

O

O

B83

B83

793

794

Compound

O

O

O

B86

B86

Compound

O

O

O

B88

B88

795

796

Compound

S

O

O

B1

B1

Compound

S

O

O

B6

B6

797

798

Compound

S

O

O

B10

B10

Compound

S

O

O

B22

B22

799

800

Compound

S

O

O

B25

B25

Compound

S

O

O

B28

B28

801

802

Compound

S

O

O

B29

B29

Compound

S

O

O

B30

B30

803

804

Compound

S

O

O

B38

B38

Compound

S

O

O

B39

B39

805

806

Compound

S

O

O

B40

B40

Compound

S

O

O

B41

B41

807

808

Compound

S

O

O

B43

B43

Compound

S

O

O

B52

B52

809

810

Compound

S

O

O

B56

B56

Compound

S

O

O

B67

B67

811

812

Compound

S

O

O

B68

B68

Compound

S

O

O

B69

B69

813

814

Compound

S

O

O

B70

B70

Compound

S

O

O

B71

B71

815

816

Compound

S

O

O

B72

B72

Compound

S

O

O

B74

B74

817

818

Compound

S

O

O

B79

B79

Compound

S

O

O

B80

B80

819

820

Compound

S

O

O

B82

B82

Compound

S

O

O

B83

B83

821

822

Compound

S

O

O

B86

B86

Compound

S

O

O

B88

B88

823

824

Compound

Se

O

O

B1

B1

Compound

Se

O

O

B6

B6

825

826

Compound

Se

O

O

B10

B10

Compound

Se

O

O

B22

B22

827

828

Compound

Se

O

O

B25

B25

Compound

Se

O

O

B28

B28

829

830

Compound

Se

O

O

B29

B29

Compound

Se

O

O

B30

B30

831

832

Compound

Se

O

O

B38

B38

Compound

Se

O

O

B39

B39

833

834

Compound

Se

O

O

B40

B40

Compound

Se

O

O

B41

B41

835

836

Compound

Se

O

O

B43

B43

Compound

Se

O

O

B52

B52

837

838

Compound

Se

O

O

B56

B56

Compound

Se

O

O

B67

B67

839

840

Compound

Se

O

O

B68

B68

Compound

Se

O

O

B69

B69

841

842

Compound

Se

O

O

B70

B70

Compound

Se

O

O

B71

B71

843

844

Compound

Se

O

O

B72

B72

Compound

Se

O

O

B74

B74

845

846

Compound

Se

O

O

B79

B79

Compound

Se

O

O

B80

B80

847

848

Compound

Se

O

O

B82

B82

Compound

Se

O

O

B83

B83

849

850

Compound

Se

O

O

B86

B86

Compound

Se

O

O

B88

B88

851

852

Compound

O

S

S

B1

B1

Compound

O

O

O

B6

B6

853

854

Compound

O

S

S

B10

B10

Compound

O

S

S

B22

B22

855

856

Compound

O

S

S

B25

B25

Compound

O

S

S

B28

B28

857

858

Compound

O

S

S

B29

B29

Compound

O

S

S

B30

B30

859

860

Compound

O

S

S

B38

B38

Compound

O

S

S

B39

B39

861

862

Compound

O

S

S

B40

B40

Compound

O

S

S

B41

B41

863

864

Compound

O

S

S

B43

B43

Compound

O

S

S

B52

B52

865

866

Compound

O

S

S

B56

B56

Compound

O

S

S

B67

B67

867

868

Compound

O

S

S

B68

B68

Compound

O

S

S

B69

B69

869

870

Compound

O

S

S

B70

B70

Compound

O

S

S

B71

B71

871

872

Compound

O

S

S

B72

B72

Compound

O

S

S

B74

B74

873

874

Compound

O

S

S

B79

B79

Compound

O

S

S

B80

B80

875

876

Compound

O

S

S

B82

B82

Compound

O

S

S

B83

B83

877

878

Compound

O

S

S

B86

B86

Compound

O

S

S

B88

B88

879

880

Compound

S

S

S

B1

B1

Compound

S

S

S

B6

B6

881

882

Compound

S

S

S

B10

B10

Compound

S

S

S

B22

B22

883

884

Compound

S

S

S

B25

B25

Compound

S

S

S

B28

B28

885

886

Compound

S

S

S

B29

B29

Compound

S

S

S

B30

B30

887

888

Compound

S

S

S

B38

B38

Compound

S

S

S

B39

B39

889

890

Compound

S

S

S

B40

B40

Compound

S

S

S

B41

B41

891

892

Compound

S

S

S

B43

B43

Compound

S

S

S

B52

B52

893

894

Compound

S

S

S

B56

B56

Compound

S

S

S

B67

B67

895

896

Compound

S

S

S

B68

B68

Compound

S

S

S

B69

B69

897

898

Compound

S

S

S

B70

B70

Compound

S

S

S

B71

B71

899

900

Compound

S

S

S

B72

B72

Compound

S

S

S

B74

B74

901

902

Compound

S

S

S

B79

B79

Compound

S

S

S

B80

B80

903

904

Compound

S

S

S

B82

B82

Compound

S

S

S

B83

B83

905

906

Compound

S

S

S

B86

B86

Compound

S

S

S

B88

B88

907

908

Compound

Se

S

S

B1

B1

Compound

Se

S

S

B6

B6

909

910

Compound

Se

S

S

B10

B10

Compound

Se

S

S

B22

B22

911

912

Compound

Se

S

S

B25

B25

Compound

Se

S

S

B28

B28

913

914

Compound

Se

S

S

B29

B29

Compound

Se

S

S

B30

B30

915

916

Compound

Se

S

S

B38

B38

Compound

Se

S

S

B39

B39

917

918

Compound

Se

S

S

B40

B40

Compound

Se

S

S

B41

B41

919

920

Compound

Se

S

S

B43

B43

Compound

Se

S

S

B52

B52

921

922

Compound

Se

S

S

B56

B56

Compound

Se

S

S

B67

B67

923

924

Compound

Se

S

S

B68

B68

Compound

Se

S

S

B69

B69

925

926

Compound

Se

S

S

B70

B70

Compound

Se

S

S

B71

B71

927

928

Compound

Se

S

S

B72

B72

Compound

Se

S

S

B74

B74

929

930

Compound

Se

S

S

B79

B79

Compound

Se

S

S

B80

B80

931

932

Compound

Se

S

S

B82

B82

Compound

Se

S

S

B83

B83

933

934

Compound

Se

S

S

B86

B86

Compound

Se

S

S

B88

B88

935

936

Compound

O

Se

Se

B1

B1

Compound

O

Se

Se

B6

B6

937

938

Compound

O

Se

Se

B10

B10

Compound

O

Se

Se

B22

B22

939

940

Compound

O

Se

Se

B25

B25

Compound

O

Se

Se

B28

B28

941

942

Compound

O

Se

Se

B29

B29

Compound

O

Se

Se

B30

B30

943

944

Compound

O

Se

Se

B38

B38

Compound

O

Se

Se

B39

B39

945

946

Compound

O

Se

Se

B40

B40

Compound

O

Se

Se

B41

B41

947

948

Compound

O

Se

Se

B43

B43

Compound

O

Se

Se

B52

B52

949

950

Compound

O

Se

Se

B56

B56

Compound

O

Se

Se

B67

B67

951

952

Compound

O

Se

Se

B68

B68

Compound

O

Se

Se

B69

B69

953

954

Compound

O

Se

Se

B70

B70

Compound

O

Se

Se

B71

B71

955

956

Compound

O

Se

Se

B72

B72

Compound

O

Se

Se

B74

B74

957

958

Compound

O

Se

Se

B79

B79

Compound

O

Se

Se

B80

B80

959

960

Compound

O

Se

Se

B82

B82

Compound

O

Se

Se

B83

B83

961

962

Compound

O

Se

Se

B86

B86

Compound

O

Se

Se

B88

B88

963

964

Compound

S

Se

Se

B1

B1

Compound

S

Se

Se

B6

B6

965

966

Compound

S

Se

Se

B10

B10

Compound

S

Se

Se

B22

B22

967

968

Compound

S

Se

Se

B25

B25

Compound

S

Se

Se

B28

B28

969

970

Compound

S

Se

Se

B29

B29

Compound

S

Se

Se

B30

B30

971

972

Compound

S

Se

Se

B38

B38

Compound

S

Se

Se

B39

B39

973

974

Compound

S

Se

Se

B40

B40

Compound

S

Se

Se

B41

B41

975

976

Compound

S

Se

Se

B43

B43

Compound

S

Se

Se

B52

B52

977

978

Compound

S

Se

Se

B56

B56

Compound

S

Se

Se

B67

B67

979

980

Compound

S

Se

Se

B68

B68

Compound

S

Se

Se

B69

B69

981

982

Compound

S

Se

Se

B70

B70

Compound

S

Se

Se

B71

B71

983

984

Compound

S

Se

Se

B72

B72

Compound

S

Se

Se

B74

B74

985

986

Compound

S

Se

Se

B79

B79

Compound

S

Se

Se

B80

B80

987

988

Compound

S

Se

Se

B82

B82

Compound

S

Se

Se

B83

B83

989

990

Compound

S

Se

Se

B86

B86

Compound

S

Se

Se

B88

B88

991

992

Compound

Se

Se

Se

B1

B1

Compound

Se

Se

Se

B6

B6

993

994

Compound

Se

Se

Se

B10

B10

Compound

Se

Se

Se

B22

B22

995

996

Compound

Se

Se

Se

B25

B25

Compound

Se

Se

Se

B28

B28

997

998

Compound

Se

Se

Se

B29

B29

Compound

Se

Se

Se

B30

B30

999

1000

Compound

Se

Se

Se

B38

B38

Compound

Se

Se

Se

B39

B39

1001

1002

Compound

Se

Se

Se

B40

B40

Compound

Se

Se

Se

B41

B41

1003

1004

Compound

Se

Se

Se

B43

B43

Compound

Se

Se

Se

B52

B52

1005

1006

Compound

Se

Se

Se

B56

B56

Compound

Se

Se

Se

B67

B67

1007

1008

Compound

Se

Se

Se

B68

B68

Compound

Se

Se

Se

B69

B69

1009

1010

Compound

Se

Se

Se

B70

B70

Compound

Se

Se

Se

B71

B71

1011

1012

Compound

Se

Se

Se

B72

B72

Compound

Se

Se

Se

B74

B74

1013

1014

Compound

Se

Se

Se

B79

B79

Compound

Se

Se

Se

B80

B80

1015

1016

Compound

Se

Se

Se

B82

B82

Compound

Se

Se

Se

B83

B83

1017

1018

Compound

Se

Se

Se

B86

B86

Compound

Se

Se

Se

B88

B88

1019

1020

Compound

O

A1

A1

B1

B6

Compound

O

A1

A1

B2

B6

1021

1022

Compound

O

A1

A1

B25

B26

Compound

O

A1

A1

B27

B28

1023

1024

Compound

O

A1

A1

B29

B30

Compound

O

A1

A1

B39

B40

1025

1026

Compound

O

A1

A1

B54

B41

Compound

O

A1

A1

B54

B52

1027

1028

Compound

O

A1

A1

B52

B56

Compound

O

A1

A1

B55

B56

1029

1030

Compound

O

A1

A1

B64

B56

Compound

O

A1

A1

B68

B69

1031

1032

Compound

O

A1

A1

B69

B70

Compound

O

A1

A1

B71

B72

1033

1034

Compound

O

A1

A1

B68

B80

Compound

O

A1

A1

B68

B83

1035

1036

Compound

S

A1

A1

B1

B6

Compound

S

A1

A1

B2

B6

1037

1038

Compound

S

A1

A1

B25

B26

Compound

S

A1

A1

B27

B28

1039

1040

Compound

S

A1

A1

B29

B30

Compound

S

A1

A1

B39

B40

1041

1042

Compound

S

A1

A1

B54

B41

Compound

S

A1

A1

B54

B52

1043

1044

Compound

S

A1

A1

B52

B56

Compound

S

A1

A1

B55

B56

1045

1046

Compound

S

A1

A1

B64

B56

Compound

S

A1

A1

B68

B69

1047

1048

Compound

S

A1

A1

B69

B70

Compound

S

A1

A1

B71

B72

1049

1050

Compound

S

A1

A1

B68

B80

Compound

S

A1

A1

B68

B83

1051

1052

Compound

Se

A1

A1

B1

B6

Compound

Se

A1

A1

B2

B6

1053

1054

Compound

Se

A1

A1

B25

B26

Compound

Se

A1

A1

B27

B28

1055

1056

Compound

Se

A1

A1

B29

B30

Compound

Se

A1

A1

B39

B40

1057

1058

Compound

Se

A1

A1

B54

B41

Compound

Se

A1

A1

B54

B52

1059

1060

Compound

Se

A1

A1

B52

B56

Compound

Se

A1

A1

B55

B56

1061

1062

Compound

Se

A1

A1

B64

B56

Compound

Se

A1

A1

B68

B69

1063

1064

Compound

Se

A1

A1

B69

B70

Compound

Se

A1

A1

B71

B72

1065

1066

Compound

Se

A1

A1

B68

B80

Compound

Se

A1

A1

B68

B83

1067

1068

Compound

O

A2

A2

B1

B6

Compound

O

A2

A2

B2

B6

1069

1070

Compound

O

A2

A2

B25

B26

Compound

O

A2

A2

B27

B28

1071

1072

Compound

O

A2

A2

B29

B30

Compound

O

A2

A2

B39

B40

1073

1074

Compound

O

A2

A2

B54

B41

Compound

O

A2

A2

B54

B52

1075

1076

Compound

O

A2

A2

B52

B56

Compound

O

A2

A2

B55

B56

1077

1078

Compound

O

A2

A2

B64

B56

Compound

O

A2

A2

B68

B69

1079

1080

Compound

O

A2

A2

B69

B70

Compound

O

A2

A2

B71

B72

1081

1082

Compound

O

A2

A2

B68

B80

Compound

O

A2

A2

B68

B83

1083

1084

Compound

S

A2

A2

B1

B6

Compound

S

A2

A2

B2

B6

1085

1086

Compound

S

A2

A2

B25

B26

Compound

S

A2

A2

B27

B28

1087

1088

Compound

S

A2

A2

B29

B30

Compound

S

A2

A2

B39

B40

1089

1090

Compound

S

A2

A2

B54

B41

Compound

S

A2

A2

B54

B52

1091

1092

Compound

S

A2

A2

B52

B56

Compound

S

A2

A2

B55

B56

1093

1094

Compound

S

A2

A2

B64

B56

Compound

S

A2

A2

B68

B69

1095

1096

Compound

S

A2

A2

B69

B70

Compound

S

A2

A2

B71

B72

1097

1098

Compound

S

A2

A2

B68

B80

Compound

S

A2

A2

B68

B83

1099

1100

Compound

Se

A2

A2

B1

B6

Compound

Se

A2

A2

B2

B6

1101

1102

Compound

Se

A2

A2

B25

B26

Compound

Se

A2

A2

B27

B28

1103

1104

Compound

Se

A2

A2

B29

B30

Compound

Se

A2

A2

B39

B40

1105

1106

Compound

Se

A2

A2

B54

B41

Compound

Se

A2

A2

B54

B52

1107

1108

Compound

Se

A2

A2

B52

B56

Compound

Se

A2

A2

B55

B56

1109

1110

Compound

Se

A2

A2

B64

B56

Compound

Se

A2

A2

B68

B69

1111

1112

Compound

Se

A2

A2

B69

B70

Compound

Se

A2

A2

B71

B72

1113

1114

Compound

Se

A2

A2

B68

B80

Compound

Se

A2

A2

B68

B83

1115

1116

Compound

O

A3

A3

B1

B1

Compound

O

A3

A3

B6

B6

1117

1118

Compound

O

A3

A3

B25

B25

Compound

O

A3

A3

B28

B28

1119

1120

Compound

O

A3

A3

B29

B29

Compound

O

A3

A3

B30

B30

1121

1122

Compound

O

A3

A3

B56

B56

Compound

O

A3

A3

B67

B67

1123

1124

Compound

O

A3

A3

B68

B68

Compound

O

A3

A3

B69

B69

1125

1126

Compound

O

A3

A3

B70

B70

Compound

O

A3

A3

B71

B71

1127

1128

Compound

O

A3

A3

B72

B72

Compound

O

A3

A3

B74

B74

1129

1130

Compound

O

A3

A3

B80

B80

Compound

O

A3

A3

B83

B83

1131

1132

Compound

S

A3

A3

B1

B1

Compound

S

A3

A3

B6

B6

1133

1134

Compound

S

A3

A3

B25

B25

Compound

S

A3

A3

B28

B28

1135

1136

Compound

S

A3

A3

B29

B29

Compound

S

A3

A3

B30

B30

1137

1138

Compound

S

A3

A3

B56

B56

Compound

S

A3

A3

B67

B67

1139

1140

Compound

S

A3

A3

B68

B68

Compound

S

A3

A3

B69

B69

1141

1142

Compound

S

A3

A3

B70

B70

Compound

S

A3

A3

B71

B71

1143

1144

Compound

S

A3

A3

B72

B72

Compound

S

A3

A3

B74

B74

1145

1146

Compound

S

A3

A3

B80

B80

Compound

S

A3

A3

B83

B83

1147

1148

Compound

Se

A3

A3

B1

B1

Compound

Se

A3

A3

B6

B6

1149

1150

Compound

Se

A3

A3

B25

B25

Compound

Se

A3

A3

B28

B28

1151

1152

Compound

Se

A3

A3

B29

B29

Compound

Se

A3

A3

B30

B30

1153

1154

Compound

Se

A3

A3

B56

B56

Compound

Se

A3

A3

B67

B67

1155

1156

Compound

Se

A3

A3

B68

B68

Compound

Se

A3

A3

B69

B69

1157

1158

Compound

Se

A3

A3

B70

B70

Compound

Se

A3

A3

B71

B71

1159

1160

Compound

Se

A3

A3

B72

B72

Compound

Se

A3

A3

B74

B74

1161

1162

Compound

Se

A3

A3

B80

B80

Compound

Se

A3

A3

B83

B83

1163

1164

Compound

O

O

A1

B1

B1

Compound

O

O

A1

B6

B6

1165

1166

Compound

O

O

A1

B25

B25

Compound

O

O

A1

B28

B28

1167

1168

Compound

O

O

A1

B29

B29

Compound

O

O

A1

B30

B30

1169

1170

Compound

O

O

A1

B56

B56

Compound

O

O

A1

B67

B67

1171

1172

Compound

O

O

A1

B68

B68

Compound

O

O

A1

B69

B69

1173

1174

Compound

O

O

A1

B70

B70

Compound

O

O

A1

B71

B71

1175

1176

Compound

O

O

A1

B72

B72

Compound

O

O

A1

B74

B74

1177

1178

Compound

O

O

A1

B80

B80

Compound

O

O

A1

B83

B83

1179

1180

Compound

S

O

A1

B1

B1

Compound

S

O

A1

B6

B6

1181

1182

Compound

S

O

A1

B25

B25

Compound

S

O

A1

B28

B28

1183

1184

Compound

S

O

A1

B29

B29

Compound

S

O

A1

B30

B30

1185

1186

Compound

S

O

A1

B56

B56

Compound

S

O

A1

B67

B67

1187

1188

Compound

S

O

A1

B68

B68

Compound

S

O

A1

B69

B69

1189

1190

Compound

S

O

A1

B70

B70

Compound

S

O

A1

B71

B71

1191

1192

Compound

S

O

A1

B72

B72

Compound

S

O

A1

B74

B74

1193

1194

Compound

S

O

A1

B80

B80

Compound

S

O

A1

B83

B83

1195

1196

Compound

Se

O

A1

B1

B1

Compound

Se

O

A1

B6

B6

1197

1198

Compound

Se

O

A1

B25

B25

Compound

Se

O

A1

B28

B28

1199

1200

Compound

Se

O

A1

B29

B29

Compound

Se

O

A1

B30

B30

1201

1202

Compound

Se

O

A1

B56

B56

Compound

Se

O

A1

B67

B67

1203

1204

Compound

Se

O

A1

B68

B68

Compound

Se

O

A1

B69

B69

1205

1206

Compound

Se

O

A1

B70

B70

Compound

Se

O

A1

B71

B71

1207

1208

Compound

Se

O

A1

B72

B72

Compound

Se

O

A1

B74

B74

1209

1210

Compound

Se

O

A1

B80

B80

Compound

Se

O

A1

B83

B83

1211

1212

Compound

O

A1

A2

B1

B1

Compound

O

A1

A2

B6

B6

1213

1214

Compound

O

A1

A2

B25

B25

Compound

O

A1

A2

B28

B28

1215

1216

Compound

O

A1

A2

B29

B29

Compound

O

A1

A2

B30

B30

1217

1218

Compound

O

A1

A2

B56

B56

Compound

O

A1

A2

B67

B67

1219

1220

Compound

O

A1

A2

B68

B68

Compound

O

A1

A2

B69

B69

1221

1222

Compound

O

A1

A2

B70

B70

Compound

O

A1

A2

B71

B71

1223

1224

Compound

O

A1

A2

B72

B72

Compound

O

A1

A2

B74

B74

1225

1226

Compound

O

A1

A2

B80

B80

Compound

O

A1

A2

B83

B83

1227

1228

Compound

S

A1

A2

B1

B1

Compound

S

A1

A2

B6

B6

1229

1230

Compound

S

A1

A2

B25

B25

Compound

S

A1

A2

B28

B28

1231

1232

Compound

S

A1

A2

B29

B29

Compound

S

A1

A2

B30

B30

1233

1234

Compound

S

A1

A2

B56

B56

Compound

S

A1

A2

B67

B67

1235

1236

Compound

S

A1

A2

B68

B68

Compound

S

A1

A2

B69

B69

1237

1238

Compound

S

A1

A2

B70

B70

Compound

S

A1

A2

B71

B71

1239

1240

Compound

S

A1

A2

B72

B72

Compound

S

A1

A2

B74

B74

1241

1242

Compound

S

A1

A2

B80

B80

Compound

S

A1

A2

B83

B83

1243

1244

Compound

Se

A1

A2

B1

B1

Compound

Se

A1

A2

B6

B6

1245

1246

Compound

Se

A1

A2

B25

B25

Compound

Se

A1

A2

B28

B28

1247

1248

Compound

Se

A1

A2

B29

B29

Compound

Se

A1

A2

B30

B30

1249

1250

Compound

Se

A1

A2

B56

B56

Compound

Se

A1

A2

B67

B67

1251

1252

Compound

Se

A1

A2

B68

B68

Compound

Se

A1

A2

B69

B69

1253

1254

Compound

Se

A1

A2

B70

B70

Compound

Se

A1

A2

B71

B71

1255

1256

Compound

Se

A1

A2

B72

B72

Compound

Se

A1

A2

B74

B74

1257

1258

Compound

Se

A1

A2

B80

B80

Compound

Se

A1

A2

B83

B83

1259

1260

Compound

O

A1

A3

B1

B1

Compound

O

A1

A3

B6

B6

1261

1262

Compound

O

A1

A3

B25

B25

Compound

O

A1

A3

B28

B28

1263

1264

Compound

O

A1

A3

B29

B29

Compound

O

A1

A3

B30

B30

1265

1266

Compound

O

A1

A3

B56

B56

Compound

O

A1

A3

B67

B67

1267

1268

Compound

O

A1

A3

B68

B68

Compound

O

A1

A3

B69

B69

1269

1270

Compound

O

A1

A3

B70

B70

Compound

O

A1

A3

B71

B71

1271

1272

Compound

O

A1

A3

B72

B72

Compound

O

A1

A3

B74

B74

1273

1274

Compound

O

A1

A3

B80

B80

Compound

O

A1

A3

B83

B83

1275

1276

Compound

S

A1

A3

B1

B1

Compound

S

A1

A3

B6

B6

1277

1278

Compound

S

A1

A3

B25

B25

Compound

S

A1

A3

B28

B28

1279

1280

Compound

S

A1

A3

B29

B29

Compound

S

A1

A3

B30

B30

1281

1282

Compound

S

A1

A3

B56

B56

Compound

S

A1

A3

B67

B67

1283

1284

Compound

S

A1

A3

B68

B68

Compound

S

A1

A3

B69

B69

1285

1286

Compound

S

A1

A3

B70

B70

Compound

S

A1

A3

B71

B71

1287

1288

Compound

S

A1

A3

B72

B72

Compound

S

A1

A3

B74

B74

1289

1290

Compound

S

A1

A3

B80

B80

Compound

S

A1

A3

B83

B83

1291

1292

Compound

Se

A1

A3

B1

B1

Compound

Se

A1

A3

B6

B6

1293

1294

Compound

Se

A1

A3

B25

B25

Compound

Se

A1

A3

B28

B28

1295

1296

Compound

Se

A1

A3

B29

B29

Compound

Se

A1

A3

B30

B30

1297

1298

Compound

Se

A1

A3

B56

B56

Compound

Se

A1

A3

B67

B67

1299

1300

Compound

Se

A1

A3

B68

B68

Compound

Se

A1

A3

B69

B69

1301

1302

Compound

Se

A1

A3

B70

B70

Compound

Se

A1

A3

B71

B71

1303

1304

Compound

Se

A1

A3

B72

B72

Compound

Se

A1

A3

B74

B74

1305

1306

Compound

Se

A1

A3

B80

B80

Compound

Se

A1

A3

B83

B83

1307

1308

Compound

O

A2

A6

B1

B1

Compound

O

A2

A6

B6

B6

1309

1310

Compound

O

A2

A6

B25

B25

Compound

O

A2

A6

B28

B28

1311

1312

Compound

O

A2

A6

B29

B29

Compound

O

A2

A6

B30

B30

1313

1314

Compound

O

A2

A6

B56

B56

Compound

O

A2

A6

B67

B67

1315

1316

Compound

O

A2

A6

B68

B68

Compound

O

A2

A6

B69

B69

1317

1318

Compound

O

A2

A6

B70

B70

Compound

O

A2

A6

B71

B71

1319

1320

Compound

O

A2

A6

B72

B72

Compound

O

A2

A6

B74

B74

1321

1322

Compound

O

A2

A6

B80

B80

Compound

O

A2

A6

B83

B83

1323

1324

Compound

S

A2

A6

B1

B1

Compound

S

A2

A6

B6

B6

1325

1326

Compound

S

A2

A6

B25

B25

Compound

S

A2

A6

B28

B28

1327

1328

Compound

S

A2

A6

B29

B29

Compound

S

A2

A6

B30

B30

1329

1330

Compound

S

A2

A6

B56

B56

Compound

S

A2

A6

B67

B67

1331

1332

Compound

S

A2

A6

B68

B68

Compound

S

A2

A6

B69

B69

1333

1334

Compound

S

A2

A6

B70

B70

Compound

S

A2

A6

B71

B71

1335

1336

Compound

S

A2

A6

B72

B72

Compound

S

A2

A6

B74

B74

1337

1338

Compound

S

A2

A6

B80

B80

Compound

S

A2

A6

B83

B83

1339

1340

Compound

Se

A2

A6

B1

B1

Compound

Se

A2

A6

B6

B6

1341

1342

Compound

Se

A2

A6

B25

B25

Compound

Se

A2

A6

B28

B28

1343

1344

Compound

Se

A2

A6

B29

B29

Compound

Se

A2

A6

B30

B30

1345

1346

Compound

Se

A2

A6

B56

B56

Compound

Se

A2

A6

B67

B67

1347

1348

Compound

Se

A2

A6

B68

B68

Compound

Se

A2

A6

B69

B69

1349

1350

Compound

Se

A2

A6

B70

B70

Compound

Se

A2

A6

B71

B71

1351

1352

Compound

Se

A2

A6

B72

B72

Compound

Se

A2

A6

B74

B74

1353

1354

Compound

Se

A2

A6

B80

B80

Compound

Se

A2

A6

B83

B83.

1355

1356

12. An electroluminescent device comprising:

an anode,

a cathode, and

an organic layer disposed between the anode and the cathode, wherein the organic layer comprises a compound having Formula 1′:

wherein each of X and Y is independently selected from the group consisting of CR″R′″, NR′, O, S and Se;

wherein each of Z 1 and Z 2 is independently selected from the group consisting of O, S and Se;

wherein each of R, R′, R″ and R′″ is independently selected from the group consisting of hydrogen, deuterium, halogen, nitroso, nitro, acyl, carbonyl, a carboxylic acid group, an ester group, cyano, isocyano, SCN, OCN, SF 5 , boranyl, sulfinyl, sulfonyl, phosphoroso, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 ring carbon atoms, a substituted or unsubstituted heteroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted arylalkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 20 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 20 carbon atoms, and combinations thereof;

wherein each R may be same or different, and at least one of R, R′, R″ and R′″ is a group having at least one electron-withdrawing group; and

wherein adjacent substituents can be optionally joined to form a ring or a fused structure.

13. The electroluminescent device according to claim 12 , wherein the organic layer is a hole injection layer, and the hole injection layer is formed from the compound alone.

14. The electroluminescent device according to claim 12 , wherein the organic layer is a hole injection layer, and the hole injection layer is formed from the compound comprising a dopant which comprises at least one hole transporting material; wherein the hole transporting material comprises a compound having a triarylamine unit, a spirobifluorene compound, a pentacene compound, an oligothiophene compound, an oligophenyl compound, an oligophenylene vinyl compound, an oligofluorene compound, a porphyrin complex or a metal phthalocyanine complex, wherein the molar doping ratio of the compound to the hole transporting material is from 10000:1 to 1:10000; preferably, the molar doping ratio of the compound to the hole transporting material is from 10:1 to 1:100.

15. The electroluminescent device according to claim 12 , wherein the electroluminescent device comprises a plurality of stacks disposed between the anode and the cathode, wherein the stacks comprise a first light-emitting layer and a second light-emitting layer, wherein the first stack comprises a first light-emitting layer, and the second stack comprises a second light-emitting layer, and a charge generation layer is disposed between the first stack and the second stack, wherein the charge generation layer comprises a p-type charge generation layer and an n-type charge generation layer;

wherein the p-type charge generation layer comprises a compound having Formula 1′; preferably, the p-type charge generation layer may further comprises at least one hole transporting material and is formed by doping the compound with at least one hole transporting material, wherein the hole transporting material comprises a compound having a triarylamine unit, a spirobifluorene compound, a pentacene compound, an oligothiophene compound, an oligophenyl compound, an oligophenylene vinyl compound, an oligofluorene compound, a porphyrin complex or a metal phthalocyanine complex, wherein the molar doping ratio of the compound to the hole transporting material is from 10000:1 to 1:10000; preferably, the molar doping ratio of the compound to the hole transporting material is from 10:1 to 1:100.

16. The electroluminescent device according to claim 15 , wherein the charge generation layer further includes a buffer layer disposed between the p-type charge generation layer and the n-type charge generation layer, wherein the buffer layer comprises the compound.

17. A compound formulation comprising the compound of claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 31, 2019
From: CUI, ZHIHAO; KWONG, CHI YUEN RAYMOND; XIA, CHUANJUN
To: BEIJING SUMMER SPROUT TECHNOLOGY CO., LTD.
Reel/Frame 050874/0529 →
Continuity (3)
Continuation In Part 16215673 · Dec 11, 2018
Provisional Application 62597941 · Dec 13, 2017
Related Publication 20200062778A1 · Feb 27, 2020