IP Library Granted Patent US 11,467,510
Granted Patent B2
US 11,467,510 · App. 16/989,991 · Granted Oct 11, 2022

Toner

Inventors: Yuhei Terui (Numazu, JP); Yoshihiro Nakagawa (Numazu, JP); Junya Asaoka (Mishima, JP); Yuu Sasano (Susono, JP); Koki Inoue (Numazu, JP); Kenta Katayama (Kashiwa, JP)
Assignee: CANON KABUSHIKI KAISHA
G03G9/0825C08L83/04G03G9/0821G03G9/08711G03G9/08773
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Quick Facts
Patent No.
US 11,467,510
App. No.
16/989,991
Granted
Oct 11, 2022
Kind
B2
Abstract

Provided is a toner containing a toner particle comprising a binder resin and an organosilicon polymer, wherein the organosilicon polymer contains an organosilicon polymer particle, the organosilicon polymer particle has a structure represented by the following formula (1): R 1 —SiO 3/2   (1) in formula (1), R 1 is a C 1-4 alkyl group, and in cross-sectional observation of the toner particle by transmission electron microscopy, the organosilicon polymer particle is present in a region extending up to 80% of the distance A from the centroid out of the total distance A from the centroid of the toner particle cross-section to the contour of the cross-section, and the particle diameter of the organosilicon polymer particle is from 10 nm to 200 nm.

Claims (14)

1. A toner, comprising:

a toner particle that contains a binder resin and an organosilicon polymer;

the organosilicon polymer comprising an organosilicon polymer particle having a particle diameter of 10-200 nm, the organosilicon polymer particle having a structure represented by formula (1)

R 1 —SiO 3/2   (1)

where R 1 is a C 14 alkyl group, wherein

a ratio of a peak area of the structure represented by formula (1) to a total peak area of the organosilicon polymer in 29 Si-NMR measurement of a tetrahydrofuran-insoluble component of the toner particle is 0.60 to 0.90,

the organosilicon polymer particle is contained in the tetrahydrofuran-insoluble component, and

the organosilicon polymer particle is present in a region extending up to 80% of distance A from the centroid of the toner particle cross-section in cross-sectional observation of the toner particle by transmission electron microscopy, where A is the distance from the centroid to the cross-section contour.

2. The toner according to claim 1 , wherein the content of the organosilicon polymer is 0.05 to 5.00 mass % of the toner particle.

3. The toner according to claim 1 , wherein |SPb−SPs|≤1.0 when SPb is the SP value of the binder resin and SPs is the SP value of the organosilicon polymer particle.

4. The toner according to claim 1 , wherein the toner particle comprises the organosilicon polymer on the toner particle surface.

5. The toner according to claim 1 , wherein the toner particle comprises an organosilicon polymer having a structure represented by formula (1) on its surface.

6. The toner according to claim 1 , wherein the content of the organosilicon polymer particle is 0.05 to 1.50 mass % of the toner particle.

7. The toner according to claim 1 , wherein R 1 is a C 1-2 alkyl group.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 8, 2020
From: TERUI, YUHEI; NAKAGAWA, YOSHIHIRO; ASAOKA, JUNYA; SASANO, YUU; INOUE, KOKI; KATAYAMA, KENTA
To: CANON KABUSHIKI KAISHA
Reel/Frame 054583/0899 →
Priority Claims (1)
JP JP2019-156504 · Aug 29, 2019 · national
Continuity (1)
Related Publication 20210063901A1 · Mar 4, 2021
Cited By (1)
US 12,429,788