Electroluminescent device and display device comprising thereof
An electroluminescent device includes a first electrode and a second electrode facing each other, and a light emitting layer disposed between the first electrode and the second electrode, where the light emitting layer includes a first light emitting layer including a first quantum dot and a second light emitting layer including a second quantum dot and an n-type metal oxide.
1. An electroluminescent device, comprising
a first electrode and a second electrode facing each other; and
a light emitting layer disposed between the first electrode and the second electrode;
wherein the light emitting layer comprises a first light emitting layer disposed on the first electrode and comprising a first quantum dot, and a second light emitting layer disposed on the second electrode and comprising a second quantum dot and an n-type metal oxide.
2. The electroluminescent device of claim 1 , wherein
the second quantum dot emits first light in a predetermined wavelength region, and
the n-type metal oxide is included in an amount of greater than about 0 percentages by weight (wt %) and less than or equal to about 20 wt % based on a total weight of the second light emitting layer.
3. The electroluminescent device of claim 1 , wherein the n-type metal oxide comprises an oxide of a metal comprising zinc (Zn), magnesium (Mg), tin (Sn) zirconium (Zr), titanium (Ti), aluminum (Al), or a combination thereof.
4. The electroluminescent device of claim 1 , wherein the n-type metal oxide is dispersed in the second light emitting layer.
5. The electroluminescent device of claim 1 , wherein the n-type metal oxide comprises a hydrophobic organic material attached to at least a portion of a surface of the n-type metal oxide.
6. The electroluminescent device of claim 1 , wherein an average particle diameter of the n-type metal oxide is about 1 nanometers (nm) to about 10 nm.
7. The electroluminescent device of claim 1 , wherein the first light emitting layer further comprises a p-type semiconductor.
8. The electroluminescent device of claim 7 , wherein the p-type semiconductor comprises a p-type monomolecular organic semiconductor, a p-type oxide semiconductor, or a combination thereof.
9. The electroluminescent device of claim 7 , wherein the p-type semiconductor is included in an amount of greater than about 0 wt % and less than or equal to about 20 wt % based on a total weight of the first light emitting layer.
10. The electroluminescent device of claim 1 , wherein the light emitting layer has a charge balance factor of greater than about 0.20 and less than about 0.56, which is a ratio of a hole transport capability to an electron transport capability.
11. The electroluminescent device of claim 1 , wherein the light emitting layer has a thickness of about 10 nm to about 60 nm.
12. The electroluminescent device of claim 1 , wherein at least one of the first quantum dot and the second quantum dot comprise a core comprising a first semiconductor nanocrystal and a shell comprising a second semiconductor nanocrystal having a composition different from the first semiconductor nanocrystal and disposed on the core.
13. The electroluminescent device of claim 1 , wherein a ligand comprising a moiety derived from metal halide compound, a moiety derived from carboxylic acid-base compound, a moiety derived from thiol compound, or a combination thereof is attached to at least one of the first quantum dot and the second quantum dot.
14. The electroluminescent device of claim 1 , further comprising:
a hole transport layer disposed between the first electrode and the light emitting layer.
15. The electroluminescent device of claim 14 , wherein
the hole transport layer comprises a poly(3,4-ethylenedioxythiophene) derivative, a poly(styrenesulfonate) derivative, a poly-N-vinylcarbazole derivative, a polyphenylenevinylene derivative, a polyparaphenylenevinylene derivative, a polymethacrylate derivative, a polyarylamine derivative, a polyaniline derivative, a polypyrrole derivative, a poly(9,9-dioctylfluorene) derivative, a poly(spiro-bifluorene) derivative, tris(4-carbazol-9-yl phenyl)amine (TCTA), N,N′-diphenyl-N,N′-bis(3-methylphenyl)-(1,1′-biphenyl)-4,4′-diamine (TPD), N,N′-di(naphthalen-1-yl)-N—N′-diphenyl-benzidine (NPB), tris(3-methylphenylphenylamino)-triphenylamine (m-MTDATA), poly[N,N′-bis(4-butylphenyl)-N,N′-bis(phenyl)benzidine, NiO, MoO 3 , or a combination thereof.
16. The electroluminescent device of claim 1 , further comprising an electron transport layer disposed between the second electrode and the light emitting layer.
17. The electroluminescent device of claim 16 , wherein the electron transport layer comprises an inorganic material nanoparticle, a quinolone compound, a triazine-based compound, a quinoline-based compound, a triazole-based compound, a naphthalene-based compound, or a combination thereof.
18. The electroluminescent device of claim 17 , wherein the inorganic material nanoparticle comprises a salt of a metal comprising zinc (Zn), magnesium (Mg), tin (Sn) zirconium (Zr), titanium (Ti), aluminum (Al), or a combination thereof.
19. The electroluminescent device of claim 1 , further comprising:
a hole transport layer disposed between the first electrode and the first light emitting layer and comprising an organic material, and
an electron transport layer disposed between the second electrode and the second light emitting layer and comprising an inorganic material, and wherein the first light emitting layer comprises a p-type organic material.
20. A display device comprising the electroluminescent device of claim 1 .