Ferromagnetic powder for magnetic recording and magnetic recording medium
Provided is a ferromagnetic powder for magnetic recording, in which an activation volume is 800 nm 3 to 1,500 nm 3 , an average plate ratio is 2.0 to 5.0, a rare earth atom content is 0.5 atom % to 5.0 atom %, and an aluminum atom content is greater than 10.0 atom % and equal to or smaller than 20.0 atom %, with respect to 100 atom % of iron atom, and the ferromagnetic powder is a plate-shaped hexagonal strontium ferrite powder having a rare earth atom surface layer portion uneven distribution and an aluminum atom surface layer portion uneven distribution, and a magnetic recording medium including this ferromagnetic powder for magnetic recording in a magnetic layer.
1. A ferromagnetic powder,
wherein an activation volume is 800 nm 3 to 1,500 nm 3 ,
an average plate ratio is 2.0 to 5.0,
a rare earth atom content is 0.5 atom % to 5.0 atom %, and an aluminum atom content is greater than 10.0 atom % and equal to or smaller than 20.0 atom %, with respect to 100 atom % of iron atom,
the ferromagnetic powder is a plate-shaped hexagonal strontium ferrite powder having a rare earth atom surface layer portion uneven distribution such that the ratio of rare earth atom surface layer portion content/rare earth atom bulk content is equal to or greater than 1.5 and an aluminum atom surface layer portion uneven distribution such that the ratio of aluminum atom surface layer portion content/aluminum atom bulk content is equal to or greater than 1.5,
the rare earth atom surface layer portion content is the rare earth atom content with respect to 100 atom % of iron atoms in a solution obtained by partially dissolving the ferromagnetic powder under the following partial dissolving condition:
a vessel containing 12 mg of the ferromagnetic powder and 10 ml of hydrochloric acid having a concentration of 1 mol/L is held on a hot plate at a set temperature of 70° C. for 1 hour,
the rare earth atom bulk content is the rare earth atom content with respect to 100 atom % of iron atoms in a solution obtained by dissolving the ferromagnetic powder under the following total dissolving condition:
a vessel containing 12 mg of the ferromagnetic powder and 10 ml of hydrochloric acid having a concentration of 4 mol/L is held on a hot plate at a set temperature of 80° C. for 3 hours,
the aluminum atom surface layer portion content is the aluminum atom content with respect to 100 atom % of iron atoms in a solution obtained by partially dissolving the ferromagnetic powder under the above partial dissolving condition,
the aluminum atom bulk content is the aluminum atom content with respect to 100 atom % of iron atoms in a solution obtained by dissolving the ferromagnetic powder under the above total dissolving condition, and
the ferromagnetic powder is a ferromagnetic powder for magnetic recording.
2. The ferromagnetic powder according to claim 1 ,
wherein the rare earth atom is one or more kinds of rare earth atom selected from the group consisting of a neodymium atom, a samarium atom, an yttrium atom, and a dysprosium atom.
3. The ferromagnetic powder according to claim 1 ,
wherein the activation volume is 800 to 1,250 nm 3 .
4. The ferromagnetic powder according to claim 1 ,
wherein an anisotropy constant Ku is equal to or greater than 2.2×10 5 J/m 3 .
5. The ferromagnetic powder according to claim 1 ,
wherein a mass magnetization us is equal to or greater than 41 A·m 2 /kg.
6. The ferromagnetic powder according to claim 1 ,
wherein the average plate ratio is 2.5 to 4.6.
7. The ferromagnetic powder according to claim 1 ,
wherein the rare earth atom content is 0.5 atom % to 4.5 atom %, with respect to 100 atom % of iron atom.
8. The ferromagnetic powder according to claim 1 ,
wherein the aluminum atom content is greater than 10.0 atom % and equal to or smaller than 18.0 atom %, with respect to 100 atom % of iron atom.
9. A magnetic recording medium comprising:
a non-magnetic support; and
a magnetic layer including a ferromagnetic powder and a binding agent on the non-magnetic support,
wherein
the ferromagnetic powder has an activation volume of 800 nm 3 to 1,500 nm 3 ,
an average plate ratio of 2.0 to 5.0,
a rare earth atom content of 0.5 atom % to 5.0 atom %, and an aluminum atom content of greater than 10.0 atom % and equal to or smaller than 20.0 atom %, with respect to 100 atom % of iron atom,
the ferromagnetic powder is a plate-shaped hexagonal strontium ferrite powder having a rare earth atom surface layer portion uneven distribution such that the ratio of rare earth atom surface layer portion content/rare earth atom bulk content is equal to or greater than 1.5 and an aluminum atom surface layer portion uneven distribution such that the ratio of aluminum atom surface layer portion content/aluminum atom bulk content is equal to or greater than 1.5,
the rare earth atom surface layer portion content is the rare earth atom content with respect to 100 atom % of iron atoms in a solution obtained by partially dissolving the ferromagnetic powder under the following partial dissolving condition:
a vessel containing 12 mg of the ferromagnetic powder and 10 ml of hydrochloric acid having a concentration of 1 mol/L is held on a hot plate at a set temperature of 70° C. for 1 hour,
the rare earth atom bulk content is the rare earth atom content with respect to 100 atom % of iron atoms in a solution obtained by dissolving the ferromagnetic powder under the following total dissolving condition:
a vessel containing 12 mg of the ferromagnetic powder and 10 ml of hydrochloric acid having a concentration of 4 mol/L is held on a hot plate at a set temperature of 80° C. for 3 hours,
the aluminum atom surface layer portion content is the aluminum atom content with respect to 100 atom % of iron atoms in a solution obtained by partially dissolving the ferromagnetic powder under the above partial dissolving condition, and
the aluminum atom bulk content is the aluminum atom content with respect to 100 atom % of iron atoms in a solution obtained by dissolving the ferromagnetic powder under the above total dissolving condition.
10. The magnetic recording medium according to claim 9 ,
wherein the rare earth atom is one or more kinds of rare earth atom selected from the group consisting of a neodymium atom, a samarium atom, an yttrium atom, and a dysprosium atom.
11. The magnetic recording medium according to claim 9 ,
wherein the activation volume is 800 to 1,250 nm 3 .
12. The magnetic recording medium according to claim 9 ,
wherein an anisotropy constant Ku of the plate-shaped hexagonal strontium ferrite powder is equal to or greater than 2.2×10 5 J/m 3 .
13. The magnetic recording medium according to claim 9 ,
wherein a mass magnetization us of the plate-shaped hexagonal strontium ferrite powder is equal to or greater than 41 A·m 2 /kg.
14. The magnetic recording medium according to claim 9 ,
wherein the average plate ratio is 2.5 to 4.6.
15. The magnetic recording medium according to claim 9 ,
wherein the rare earth atom content is 0.5 atom % to 4.5 atom %, with respect to 100 atom % of iron atom.
16. The magnetic recording medium according to claim 9 ,
wherein the aluminum atom content is greater than 10.0 atom % and equal to or smaller than 18.0 atom %, with respect to 100 atom % of iron atom.