Dry electrode manufacture with lubricated active material mixture
A method of manufacturing a free-standing electrode film includes preparing a mixture including an electrode active material, a binder, and an additive solution or conductive paste, the additive solution or conductive paste being in an amount less than 5% by weight of the mixture and including a polymer additive and a liquid carrier, as well as a conductive material in the case of a conductive paste. The mixture may have total solid contents greater than 95% by weight. Preparing the mixture may include mixing the additive solution or conductive paste with the electrode active material to lubricate the electrode active material and subsequently adding and mixing in the binder. The method may further include subjecting the mixture to a shear force and, after the mixture has been subjected to the shear force, pressing the mixture into a free-standing film.
1. A method of manufacturing a free-standing electrode film, the method comprising:
preparing a mixture including an electrode active material, polytetrafluoroethylene (PTFE), and an additive solution, the additive solution being in an amount less than 5% by weight of the mixture and including a polymer additive and a liquid carrier, the mixture having total solid contents greater than 95% by weight, said preparing comprising mixing the additive solution with the electrode active material to lubricate the electrode active material and subsequently adding the PTFE;
subjecting the mixture to a shear force; and,
after the mixture has been subjected to the shear force, pressing the mixture into a free-standing film.
2. The method of claim 1 , further comprising mixing the polymer additive with the liquid carrier to produce the additive solution.
3. The method of claim 1 , wherein the polymer additive is 0.5-10% by weight of the additive solution.
4. The method of claim 3 , wherein the polymer additive is 1-5% by weight of the additive solution.
5. The method of claim 1 , wherein the mixture further includes a conductive material, said preparing comprising mixing the additive solution with the electrode active material to lubricate the electrode active material and subsequently adding the PTFE and the conductive material.
6. The method of claim 1 , wherein said pressing includes applying a roller press to the mixture.
7. A method of manufacturing an electrode, the method comprising:
the method of claim 1 ; and
laminating the free-standing film on a current collector.
8. A method of manufacturing a free-standing electrode film, the method comprising:
preparing a mixture including an electrode active material, polytetrafluoroethylene (PTFE), and a conductive paste, the conductive paste being in an amount less than 5% by weight of the mixture and including a polymer additive, a liquid carrier, and a conductive material, the mixture having total solid contents greater than 95% by weight, said preparing comprising mixing the conductive paste with the electrode active material to lubricate the electrode active material and subsequently adding the PTFE;
subjecting the mixture to a shear force; and,
after the mixture has been subjected to the shear force, pressing the mixture into a free-standing film.
9. The method of claim 8 , further comprising mixing the polymer additive, the liquid carrier, and the conductive material to produce the conductive paste.
10. The method of claim 9 , wherein said mixing the polymer additive, the liquid carrier, and the conductive material to produce the conductive paste comprises mixing the polymer additive and the liquid carrier to produce an additive solution and, thereafter, mixing the conductive material into the additive solution.
11. The method of claim 10 , wherein the polymer additive is 0.5-10% by weight of the additive solution.
12. The method of claim 11 , wherein the polymer additive is 1-5% by weight of the additive solution.
13. The method of claim 8 , wherein the conductive material is 1-20% by weight of the conductive paste.
14. The method of claim 13 , wherein the conductive material is 2-15% by weight of the conductive paste.
15. The method of claim 14 , wherein the conductive material is 5-10% by weight of the conductive paste.
16. The method of claim 8 , wherein the mixture further includes a second conductive material other than the conductive material included in the conductive paste, said preparing comprising mixing the conductive paste with the electrode active material to lubricate the electrode active material and subsequently adding the PTFE and the second conductive material.
17. The method of claim 8 , wherein said pressing includes applying a roller press to the mixture.
18. A method of manufacturing an electrode, the method comprising:
the method of claim 8 ; and
laminating the free-standing film on a current collector.
19. A powdery mixture for use in manufacturing a free-standing electrode film, the powdery mixture comprising:
an electrode active material;
polytetrafluoroethylene (PTFE); and
an additive solution in an amount less than 5% by weight of the powdery mixture, the additive solution including a polymer additive and a liquid carrier,
wherein the powdery mixture has total solid contents greater than 95% by weight.
20. The powdery mixture of claim 19 , further comprising a conductive material.
21. The powdery mixture of claim 19 , wherein the polymer additive is 0.5-10% by weight of the additive solution.