Providing carbon dioxide by means of oxygen-based combustion
A method for preparing a carbonaceous product includes providing oxygen, in particular from electrolysis, and providing a fuel. The method also includes combusting the fuel with the oxygen by an oxy-fuel combustion process in order to provide energy, purifying a flue gas produced by the oxy-fuel combustion process, and separating carbon dioxide from the flue gas produced by the oxy-fuel combustion process, wherein energy provided by the oxy-fuel combustion process includes, in particular exclusively, heat which is used as process heat for purifying and/or for synthesising or providing the carbonaceous product. A corresponding system is designed to carry out the described method.
1. A process for producing a carbon-containing product, comprising:
providing oxygen (O2), and a fuel,
combusting the fuel by means of the oxygen (O2) in an oxyfuel process to provide energy,
purifying a flue gas formed by the oxyfuel process, and
separating carbon dioxide (CO2) from the flue gas formed by the oxyfuel process, comprising reacting the oxygen (O2) in the flue gas with hydrogen (H2) to form water (H2O),
wherein the energy provided by the oxyfuel process comprises heat which is utilized as process heat for a CO2-based synthesis that produces the carbon-containing product and that comprises an endothermic reaction.
2. The process as claimed in claim 1 ,
wherein hydrogen (H2) is provided and the carbon dioxide (CO2) which has been separated off is reacted with the hydrogen (H2) in the CO2-based synthesis to give the carbon-containing product.
3. The process as claimed in claim 2 ,
wherein the CO2-based synthesis comprises a reverse water gas shift reaction.
4. The process as claimed in claim 1 ,
wherein the carbon-containing product is a secondary energy carrier.
5. The process as claimed in claim 1 ,
wherein the carbon-containing product is methane, methanol, MTBE, DME, OME, kerosene, gasoline, diesel and/or waxes.
6. The process as claimed in claim 1 ,
wherein the fuel is biomass or biomass-based, and/or a standardized fuel present in pressed form or pellet form.
7. The process as claimed in claim 1 ,
wherein the provision of the oxygen (O2) and/or hydrogen (H2) occurs by means of fluctuating renewable energy and the provision of the energy occurs in a nonfluctuating manner.
8. The process as claimed in claim 2 ,
wherein the provision of the oxygen (O2) and/or the provision of the hydrogen (H2) occurs by means of an electrolysis.
9. The process as claimed in claim 8 ,
wherein the electrolysis is carried out under elevated pressure so that the oxygen (O2) and the hydrogen (H2) are likewise present under elevated pressure or the oxygen (O2) and the hydrogen (H2) are provided in compressed form after they have been produced electrolytically.
10. The process as claimed in claim 1 ,
further comprising a further carbon dioxide purification step subsequent to separating the carbon dioxide (CO2) from the flue gas and comprising reacting the oxygen (O2) in the flue gas with hydrogen (H2) to form water (H2O).
11. The process as claimed in claim 1 ,
wherein the energy provided by the oxyfuel process comprises heat which is utilized for subsequent power-heat coupling.
12. The process as claimed in claim 1 ,
wherein the energy provided by the oxyfuel process comprises electric energy which is obtained as nonfluctuating energy.
13. The process as claimed in claim 1 ,
wherein the oxyfuel process is carried out without flue gas recirculation.
14. The process as claimed in claim 1 ,
wherein a fluidized bed is used for the combustion of the fuel.
15. The process as claimed in claim 1 ,
wherein the energy provided by the oxyfuel process comprises exclusively heat.
16. The process as claimed in claim 3 ,
wherein the carbon-containing product comprises methanol.
17. The process as claimed in claim 12 ,
wherein the energy provided by the oxyfuel process comprises electric energy which is obtained as nonfluctuating energy, by means of a steam power process.
18. The process as claimed in claim 1 , wherein the fuel is combusted in a minimally superstoichiometric amount that is effective to ensure some of the oxygen (O2) remains unburnt and part of the flue gas.