IP Library › Granted Patent US 11,535,803
Granted Patent B2
US 11,535,803 · App. 16/633,273 · Granted Dec 27, 2022

Method for purifying natural gas using an economizer

Inventors: Paul Terrien (Newton, MA); Pascal Marty (Bry sur marne, FR); Yong Ding (Waban, MA)
Assignees: L'Air Liquide, Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude; Air Liquide Advanced Technologies U.S. LLC
C10L3/104B01D53/002B01D53/226B01D53/229F25J3/067C10L2290/06C10L2290/548F25J2205/40F25J2205/80
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Quick Facts
Patent No.
US 11,535,803
App. No.
16/633,273
Granted
Dec 27, 2022
Kind
B2
Abstract

A process for purifying a gaseous feed stream of natural gas including methane, CO 2 and heavy hydrocarbons including step a): cooling the gaseous feed stream in a heat exchanger; step b): introducing the cooled stream into a phase-separating chamber to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gaseous stream; step c): separating the gaseous stream obtained from step b) in a first membrane producing at least one CO 2 -enriched permeate stream and a residual stream enriched in methane; step d): introducing the residual stream obtained from step c) into a phase-separator to produce a liquid stream and a gaseous stream; step e): heating the gaseous stream obtained from step d) by introducing it into the heat exchanger used in step a) counter-currentwise with the feed stream thereby producing a gaseous stream depleted in CO 2 and enriched in methane.

Claims (13)

1. A process for purifying a gaseous feed stream of natural gas comprising methane, CO 2 and hydrocarbons containing at least two carbon atoms, comprising the following steps:

Step a): cooling the gaseous feed stream in a heat exchanger;

Step b): introducing stream obtained from step a) into a phase-separating chamber to produce a liquid stream depleted in methane and enriched in hydrocarbons containing more than three carbon atoms and a gaseous stream;

Step c): separating the gaseous stream obtained from step b) in a first membrane permeation unit including at least one main membrane separation stage from which emerges at least one CO 2 -enriched gaseous first permeate stream and a partially condensed first residual stream depleted in CO 2 and enriched in methane;

Step d): introducing the first residual stream obtained from step c) into a phase-separating chamber to produce at least two phases, a liquid stream including at least 0.5 mol % of hydrocarbons containing at least three carbon atoms initially contained in the feed stream, and a gaseous stream;

Step e): heating the gaseous stream obtained from step d) by introducing it into the heat exchanger used in step a) counter-currentwise relative to the feed stream so as to produce a gaseous stream depleted in CO 2 and enriched in methane relative to the feed stream; and

Step f): introducing the gaseous stream obtained from step e) into a second membrane separation unit, from which emerges at least one gaseous second permeate stream enriched in CO 2 and a gaseous second residual stream depleted in CO 2 and enriched in methane.

2. The process as claimed in in claim 1 , wherein the second residual stream contains less than 8 mol % of CO 2 and more than 80 mol % of methane.

3. The process as claimed in claim 1 , wherein the gaseous stream obtained from step d) undergoes Joule-Thomson expansion prior to step e).

4. The process as claimed in claim 1 , wherein the feed stream to be purified comprises at least 15 mol % of CO 2 .

5. The process as claimed in claim 1 , wherein the gaseous stream obtained from step e) is heated by introducing it into a heating means so as to produce a gaseous stream prior to step f).

6. The process as claimed in claim 1 , wherein the liquid stream obtained from step b) is introduced into the heat exchanger used in step a) counter-currentwise relative to the feed stream.

7. The process as claimed in claim 1 , wherein the liquid stream obtained from step d) is mixed with the liquid stream obtained from step b) before being introduced into the heat exchanger used in step a) counter-currentwise relative to the feed stream.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 3, 2026
From: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLC
To: L'AIR LIQUIDE, SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
Reel/Frame 076064/0658 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2021
From: MARTY, PASCAL
To: L'AIR LIQUIDE, SOCIÉTÉ ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCÉDÉS GEORGES CLAUDE
Reel/Frame 054914/0834 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2021
From: DING, YONG; TERRIEN, PAUL
To: AIR LIQUIDE ADVANCED TECHNOLOGIES U.S. LLC
Reel/Frame 054915/0291 →
Priority Claims (1)
FR 1757154 · Jul 27, 2017 · national
Continuity (1)
Related Publication 20210130720A1 · May 6, 2021