Electroacoustic transduction film and manufacturing method thereof, electroacoustic transducer, flexible display, vocal cord microphone, sensor for musical instrument
Provided are an electroacoustic transduction film capable of reproducing a sound with a sufficient sound volume at a high conversion efficiency, a manufacturing method thereof, an electroacoustic transducer, a flexible display, a vocal cord microphone, and a sensor for a musical instrument. The electroacoustic transduction film includes: a polymer composite piezoelectric body in which piezoelectric body particles are dispersed in a viscoelastic matrix formed of a polymer material having viscoelasticity at a normal temperature; two thin film electrodes laminated on both surfaces of the polymer composite piezoelectric body; and two protective layers respectively laminated on the two thin film electrodes, in which an intensity ratio α 1 =(002) plane peak intensity/((002) plane peak intensity+(200) plane peak intensity) between a (002) plane peak intensity and a (200) plane peak intensity derived from the piezoelectric body particles in a case where the polymer composite piezoelectric body is evaluated by an X-ray diffraction method is more than or equal to 0.6 and less than 1.
1. An electroacoustic transduction film comprising:
a polymer composite piezoelectric body in which piezoelectric body particles are dispersed in a viscoelastic matrix formed of a polymer material having viscoelasticity at a normal temperature;
two thin film electrodes laminated on both surfaces of the polymer composite piezoelectric body; and
two protective layers respectively laminated on the two thin film electrodes,
wherein an intensity ratio α1=(002) plane peak intensity/((002) plane peak intensity+(200) plane peak intensity) between a (002) plane peak intensity and a (200) plane peak intensity derived from the piezoelectric body particles in a case where the polymer composite piezoelectric body is evaluated by an X-ray diffraction method is more than or equal to 0.6 and less than 1.
2. The electroacoustic transduction film according to claim 1 ,
wherein the intensity ratio α1 is more than or equal to 0.67 and less than or equal to 0.75.
3. The electroacoustic transduction film according to claim 1 ,
wherein a relative permittivity of the polymer material is more than or equal to 10 at 25° C.
4. The electroacoustic transduction film according to claim 3 ,
wherein the piezoelectric body particles are formed of ceramics particles having a perovskite type or wurtzite type crystal structure.
5. The electroacoustic transduction film according to claim 1 ,
wherein the piezoelectric body particles are formed of ceramics particles having a perovskite type or wurtzite type crystal structure.
6. The electroacoustic transduction film according to claim 1 ,
wherein the piezoelectric body particles are formed of ceramics particles having at least one of lead zirconate titanate (PZT), lead lanthanum zirconate titanate (PLZT), barium titanate (BaTiO3), zinc oxide (ZnO), and a solid solution (BFBT) of barium titanate and bismuth ferrite (BiFe3).
7. An electroacoustic transducer comprising:
the electroacoustic transduction film according to claim 1 .
8. A flexible display comprising:
the electroacoustic transduction film according to claim 1 attached to a surface of the flexible display having flexibility, the surface being opposite to an image display surface.