Copolymer, rubber composition, and method of preparing the same
Disclosed is a copolymer including a first part including an aromatic vinyl-based monomer and a conjugated diene-based monomer; and a second part including an aromatic vinyl-based monomer and a conjugated diene-based monomer, wherein the content of the aromatic vinyl-based monomer is 35 to 45% by weight based on a total weight of the copolymer, and the copolymer satisfies Equation 1 below: V 1 >V 2 <Equation 1> wherein V 1 is a vinyl content in the first part, and V 2 is a vinyl content in the second part.
1. A copolymer, comprising:
a first part comprising an aromatic vinyl-based monomer and a conjugated diene-based monomer; and
a second part comprising an aromatic vinyl-based monomer and a conjugated diene-based monomer,
wherein the content of the aromatic vinyl-based monomer is 38 to 42% by weight based on a total weight of the copolymer, and
the copolymer satisfies Equation 1 below:
V 1 >V 2 <Equation 1>
wherein V 1 is a vinyl content in the first part, and
V 2 is a vinyl content in the second part;
wherein V 1 is 35 to 38% by weight, and V 2 is 19 to 28% by weight;
wherein a total vinyl content in the copolymer is 26 to 33% by weight, and
wherein the copolymer has a molecular weight distribution of 1.0 to 1.2.
2. The copolymer according to claim 1 , wherein a content of the aromatic vinyl-based monomer of the first part is 15 to 45% by weight, and
a content of the aromatic vinyl-based monomer of the second part is 35 to 65% by weight.
3. The copolymer according to claim 1 , wherein a weight ratio of the first part to the second part is 1:0.5 to 1.5.
4. The copolymer according to claim 1 , wherein the copolymer has a weight average molecular weight of 100,000 to 250,000.
5. The copolymer according to claim 1 , wherein a content of an aromatic vinyl-based block in the copolymer is 1% by weight or less.
6. The copolymer according to claim 1 , wherein at least a portion of the copolymer is modified with one selected from the group consisting of piperidine, 1-[(4-ethylphenyl)methyl]-pyrrolidine, 1-(4-vinylbenzyl)pyrrolidine, N1-(3-(dimethylamino)propyl)-N3,N3-dimethyl-N1-(4-vinylbenzyl)propane-1,3-diamine, N1-(3-(dimethylamino)propyl)-N3,N3-dimethyl-N1-(4-vinylphenethyl)propane1,3-diamine, N1-(2-(dimethylamino)ethyl)-N2,N2-dimethyl-N1-(4-vinylbenzyl)ethane-1,2-diamine; N1-(3-(diethylamino)propyl)-N3,N3-diethyl-N1-(4-vinylbenzyl)propane-1,3-diamine, triethoxysilylpropyldiethylamine, 3-glycidoxypropyldimethyldimethoxysilane, dimethyldichlorosilane, trimethylchlorosilane, methyldichlorosilane, methyltrichlorosilane, phenyltrichlorosilane, vinyltrichlorosilane, and a combination of two or more thereof.
7. A rubber composition, comprising:
the copolymer according to claim 1 ; and
a conjugated diene-based polymer.
8. The rubber composition according to claim 7 , wherein the polymer is high-cis-1,4-polybutadiene or natural rubber.
9. The rubber composition according to claim 7 , wherein a weight ratio of the copolymer to the polymer is 1 to 5:1.