Use of propoxylated surfactant or polymer in foaming applications to control viscoelasticity in highly active liquid formulations
Antimicrobial or non-antimicrobial compositions, sanitizing compositions and other compositions combining use of a propoxylated EO/PO block copolymer surfactant and/or propoxylated polymer in combination with at least one additional anionic and/or nonionic surfactant to provide concentrated compositions having a desired viscoelasticity at an active level of at least 18% are disclosed. Non-antimicrobial applications combining use of a propoxylated surfactant and/or propoxylated polymer in combination with at least one additional anionic and/or nonionic surfactant to provide compositions having a desired viscoelasticity are also disclosed. Methods of using concentrated and use compositions having desired foaming enhancement and stabilization are also disclosed.
1. A kit comprising:
a two-part premix for a concentrated liquid composition comprising a first part and a second part;
wherein the first part comprises propoxylated surfactant comprising an ethylene oxide/propylene oxide (EO/PO) block copolymer surfactant in an amount of between about 1 wt-% to about 50 wt-% of the concentrated liquid composition;
wherein the second part comprises an anionic surfactant and at least one-nonionic surfactant in an amount of at least about 20 wt-% of the concentrated liquid composition, and solvent(s); and
wherein the concentrated liquid composition has a viscosity of less than about 900 cPs and does not include ethanol.
2. The kit of claim 1 , wherein the first part further comprises a propoxylated homopolymer.
3. The kit of claim 1 , wherein the solvent(s) comprises propylene glycol and/or hexylene glycol.
4. The kit of claim 1 , wherein the solvent(s) are present in an amount of between about 1 wt-% and about 30 wt-% of the concentrated liquid composition.
5. The kit of claim 1 , wherein the EO/PO block copolymer surfactant has the following structure (EO) n (PO) m (EO) n or (PO) m (EO) n (PO) m , wherein n is the average number of polymerized ethylene oxide units and m is the average number of polymerized propylene oxide units, and wherein the molecular weight is between about 1000 g/mol and about 15,000 g/mol and with a Ross Miles Foam of greater than or equal to 40 (0.1% @ 50° C.).
6. The kit of claim 1 , wherein the EO/PO block copolymer surfactant has a molecular weight of at least about 3000 g/mol.
7. The kit of claim 1 , wherein the first part further comprises a propoxylated polymer or copolymer comprising one or more of: propoxylated homopolymer; polyethyleneimine derivative propoxylated polymer having a PO group, EO-PO group or PO-EO group; or an extended chain surfactant.
8. The kit of claim 7 , wherein the extended chain surfactant (a) has the formula R—[L]x—[O—CH 2 —CH 2 ]y, wherein R is the lipophilic moiety, a linear or branched, saturated or unsaturated, substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from about 8 to 20 carbon atoms, L is a linking group comprising a block of poly-propylene oxide, a block of poly-ethylene oxide, a block of poly-butylene oxide or a mixture thereof; x is the chain length of the linking group ranging from 2-25; and y is the average degree of ethoxylation ranging from 1-20, and/or (b) is an extended chain anionic surfactant and has the formula R—[L]x—[O—CH 2 —CH 2 ]y M, wherein R is the lipophilic moiety, a linear or branched, saturated or unsaturated, substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from about 8 to 20 carbon atoms, L is a linking group comprising a block of poly-propylene oxide, a block of poly-ethylene oxide, a block of poly-butylene oxide or a mixture thereof; x is the chain length of the linking group ranging from 1-15; y is the average degree of ethoxylation ranging from 1-5, and M is any ionic species.
9. The kit of claim 7 , wherein the propoxylated homopolymer is polypropylene glycol and does not provide surfactant activity.
10. The kit of claim 1 , wherein the first part further comprises the solvent(s).
11. The kit of claim 1 , wherein the anionic surfactant is a C6-C18 alkyl chain length linear or branched carboxylate, sulfate, sulfonate, or a mixture thereof.
12. The kit of claim 1 , wherein the anionic surfactant is comprised of sodium lauryl ether sulfate, sodium lauryl sulfate, alpha olefin sulfonate, alkylbenzene sulfonic acid, or a mixture thereof.
13. The kit of claim 1 , wherein the nonionic surfactant is an alcohol ethoxylate, alcohol alkoxylate, block copolymer, amine oxide, alkylpolyglucoside, or a combination thereof.
14. The kit of claim 1 , wherein the concentrated liquid composition further comprises water and/or one or more additional functional ingredients comprising additional surfactants, solubility modifiers, humectants, metal protecting agents, stabilizing agents, corrosion inhibitors, sequestrants and/or chelating agents, preservatives, sheeting agents, pH modifying components, fragrances and/or dyes, hydrotropes or couplers, and/or buffers.
15. The kit of claim 1 , wherein the concentrated liquid composition has an active concentration of at least about 18%.
16. The kit of claim 1 , wherein the concentrated liquid composition has an active concentration of at least about 30% and has a viscosity less than about 500 cPs.
17. The kit of claim 1 , wherein the concentrated liquid composition further comprises an antimicrobial agent and provides at least a 3 log microbial kill on a treated surface.