Bipolar plates for use in electrochemical cells
The present disclosure is directed towards the design of electrochemical cells for use in high pressure or high differential pressure operations. The electrochemical cells of the present disclosure have non-circular external pressure boundaries, i.e., the cells have non-circular profiles. In such cells, the internal fluid pressure during operation is balanced by the axial tensile forces developed in the bipolar plates, which prevent the external pressure boundaries of the cells from flexing or deforming. That is, the bipolar plates are configured to function as tension members during operation of the cells. To function as an effective tension member, the thickness of a particular bipolar plate is determined based on the yield strength of the material selected for fabricating the bipolar plate, the internal fluid pressure in the flow structure adjacent to the bipolar plate, and the thickness of the adjacent flow structure.
1. An electrochemical cell comprising:
a first electrode, a second electrode, and an electrolyte membrane disposed there between;
a first bipolar plate adjacent the first electrode and a second bipolar plate adjacent the second electrode;
a first flow structure enclosed by the first bipolar plate and the first electrode, the first flow structure including a flow field and a porous gas diffusion layer;
a second flow structure enclosed by the second bipolar plate and the second electrode, the second flow structure including a flow field and a porous gas diffusion layer;
wherein an area of the side of the first flow structure that interfaces with the first electrode is smaller than an area of the side of the second flow structure that interfaces with the second electrode;
wherein the first bipolar plate has a non-circular base geometry and is constructed of two pieces, one of the pieces forms a frame around the first flow structure and the other piece is a generally flat plate, the frame and the flat plate have interlocking features wherein the frame comprises at least one protrusion or indentation to mate with at least one corresponding indentation or protrusion on the flat plate; and
wherein the thickness of the first bipolar plate is equal to or greater than the thickness of the first flow structure multiplied by the ratio of a predetermined fluid pressure in the first flow structure to the yield strength of the first bipolar plate.
2. The electrochemical cell of claim 1 , wherein the electrochemical cell has a non-circular external pressure boundary.
3. The electrochemical cell of claim 2 , wherein the electrochemical cell has a rectangular external pressure boundary.
4. The electrochemical cell of claim 1 , wherein the second flow structure is exposed to lower pressure than the first flow structure during operation of the electrochemical cell.
5. The electrochemical cell of claim 1 , further comprising a seal positioned between the first bipolar plate and the first electrode around the periphery of the first flow structure, wherein the seal is positioned within a perimeter of the side of the second flow structure interfacing with the second electrode.
6. The electrochemical cell of claim 1 , wherein at least one of the first flow structure and the second flow structure comprises a porous substrate.
7. An electrochemical cell comprising:
a first electrode, a second electrode, and an electrolyte membrane disposed there between;
a first bipolar plate adjacent the first electrode and a second bipolar plate adjacent the second electrode;
a first flow structure enclosed by the first bipolar plate and the first electrode;
a second flow structure enclosed by the second bipolar plate and the second electrode;
wherein an area of the side of the first flow structure that interfaces with the first electrode is smaller than an area of the side of the second flow structure that interfaces with the second electrode;
wherein the first bipolar plate and the second bipolar plate are composed of metallic material;
wherein the thickness of the first bipolar plate is equal to or greater than the thickness of the first flow structure multiplied by the ratio of a predetermined fluid pressure in the first flow structure to the yield strength of the first bipolar plate.