Method for measuring distance of diffusion of curing catalyst
A method for measuring a distance of diffusion of a curing catalyst for a thermosetting silicon-containing material includes the steps of: forming a silicon-containing film from a composition containing a thermosetting silicon-containing material, a curing catalyst and a solvent; coating the silicon-containing film with a photosensitive resin composition containing a resin whose solubility in alkaline developer is increased by the action of an acid, an acid generator and a solvent, and subsequently heating to prepare a substrate on which the silicon-containing film and a resin film are formed; irradiating the substrate with a high energy beam or an electron beam to generate an acid and heat-treating the substrate to increase the solubility of the resin in an alkaline developer by the action of the acid in the resin film; dissolving the resin film in an alkaline developer; and measuring a film thickness of the remaining resin.
1. A method for measuring a distance of diffusion of a curing catalyst (Xc) for a thermosetting silicon-containing material (Sx), comprising the steps of:
(1) coating a substrate with a composition for forming a silicon-containing film containing the thermosetting silicon-containing material (Sx), the curing catalyst (Xc), and a solvent (a), and subsequently heating to form a silicon-containing film (Sf),
(2) coating the silicon-containing film (Sf) with a photosensitive resin composition containing a resin (A), an acid generator and a solvent (b), and subsequently heating to remove the solvent (b) to prepare a substrate on which the silicon-containing film (Sf) and a resin film are formed, a solubility of the resin (A) in an alkaline developer being increased by an action of an acid, and the acid generator being to generate an acid by a high energy beam having a wavelength of 300 nm or less or an electron beam,
(3) irradiating the substrate with the high energy beam or the electron beam to decompose the acid generator so as to generate an acid,
(4) heat-treating the substrate to increase the solubility of the resin (A) in an alkaline developer by the action of the acid in the resin film,
(5) dissolving in an alkaline developer the resin film having the increased solubility in the alkaline developer, and
(6) measuring a film thickness of the resin (A) that was not dissolved in the alkaline developer and remained on the silicon-containing film (Sf),
wherein the silicon-containing film (Sf) is formed by the thermosetting silicon-containing material (Sx) newly forming a siloxane bond by the curing catalyst (Xc).
2. The method for measuring a distance of diffusion of a curing catalyst (Xc) for a thermosetting silicon-containing material (Sx) according to claim 1 , wherein a curing catalyst containing nitrogen, sulfur, phosphorus or iodine is used as the curing catalyst (Xc).
3. The method for measuring a distance of diffusion of a curing catalyst (Xc) for a thermosetting silicon-containing material (Sx) according to claim 1 , wherein an onium compound is used as the curing catalyst (Xc).
4. The method for measuring a distance of diffusion of a curing catalyst (Xc) for a thermosetting silicon-containing material (Sx) according to claim 2 , wherein an onium compound is used as the curing catalyst (Xc).