Material and method for powder bed fusion

1. A particulate material for powder bed fusion,

wherein the particulate material comprises, based on the total weight of the particulate material, 98 to 100 weight percent of a semicrystalline thermoplastic selected from the group consisting of semicrystalline polycarbonates and semicrystalline polyetherimides;

wherein the particulate material comprises particles characterized by a volume-based distribution of equivalent spherical diameters determined by laser diffraction according to ISO 13320:2009, and the distribution exhibits

a Dv50 value in a range of 35 to 85 micrometers, wherein Dv50 is defined as the median equivalent spherical diameter,

a Dv01 value greater than 2 micrometers, wherein Dv01 is defined as the equivalent spherical diameter corresponding to 1 percent of the cumulative undersize distribution,

a Dv99 value less than 115 micrometers, wherein Dv99 is defined as the equivalent spherical diameter corresponding to 99 percent of the cumulative undersize distribution.

2. The particulate material of claim 1 , wherein the volume-based distribution of equivalent spherical diameters exhibits a Dv10 value in a range of 30 to 50 micrometers, and a Dv90 value in a range of 80 to 100 micrometers; wherein Dv10 is defined as the equivalent spherical diameter corresponding to 10 percent of the cumulative undersize distribution, and Dv90 is defined as the equivalent spherical diameter corresponding to 90 percent of the cumulative undersize distribution.

3. The particulate material of claim 1 , wherein the volume-based distribution of equivalent spherical diameters is monomodal.

4. The particulate material of claim 1 , wherein the particles exhibit a sphericity of at least 80 percent, determined according to ISO 9276-6:2008.

5. The particulate material of claim 1 , wherein the particles exhibit a Hausner Ratio in a range of 1.0 to 1.18, determined according to ISO 3953:2011.

6. The particulate material of claim 1 , wherein the semicrystalline thermoplastic is a semicrystalline polycarbonate.

7. The particulate material of claim 6 , wherein the semicrystalline polycarbonate comprises a semicrystalline bisphenol A polycarbonate.

8. The particulate material of claim 1 , wherein the semicrystalline thermoplastic resin is a semicrystalline polyetherimide.

9. The particulate material of claim 8 , wherein the semicrystalline polyetherimide comprises at least 90 weight percent of etherimide units having the structure

10. A method of additive manufacturing, the method comprising:

depositing a first layer comprising the particulate material of claim 1 at a working area;

irradiating the working area with first radiation effective to heat the first layer to a temperature below and within 10° C. of a melting onset temperature of the semicrystalline thermoplastic; and

selectively irradiating a portion of the working area with second radiation effective to heat the first layer to a temperature above a melting point of the semicrystalline thermoplastic.

11. The method of claim 10 , wherein the volume-based distribution of equivalent spherical diameters exhibits a Dv10 value in a range of 30 to 50 micrometers, and a Dv90 value in a range of 80 to 100 micrometers; wherein Dv10 is defined as the equivalent spherical diameter corresponding to 10 percent of the cumulative undersize distribution, and Dv90 is defined as the equivalent spherical diameter corresponding to 90 percent of the cumulative undersize distribution.

12. The method of claim 10 , wherein the particles exhibit a sphericity of at least 80 percent, determined according to ISO 9276-6:2008.

13. The method of claim 10 , wherein the particles exhibit a Hausner Ratio in a range of 1.0 to 1.18, determined according to ISO 3953:2011.

14. The method of claim 10 , wherein the semicrystalline thermoplastic is a semicrystalline polycarbonate.

15. The method of claim 10 , wherein the semicrystalline thermoplastic is a semicrystalline polyetherimide.