Additively manufactured component and production method therefor
A component includes a multiplicity of individual powder particles of Mo, a Mo-based alloy, W or a W-based alloy that have been fused together to give a solid structure by a high-energy beam via an additive manufacturing method. The component has an oxygen content of not more than 0.1 at %. An additive manufacturing method includes producing the powder via the melt phase and providing a carbon content in the region of not less than 0.15 at %. The components are crack-free and have high grain boundary strength.
1. A component, comprising:
a multiplicity of individual powder particles of molybdenum, a molybdenum-based alloy, tungsten or a tungsten-based alloy fused together into a solid structure;
said particles having characteristics of having been fused together by a high-energy beam in an additive manufacturing method; and
the component having an oxygen content of not more than 0.1 at % and a carbon content of not less than 0.08 at %.
2. The component according to claim 1 , wherein the component has a carbon content of not more than 25 at %.
3. The component according to claim 1 , wherein the component has a carbon content in at % of not less than the oxygen content in at %.
4. The component according to claim 1 , which further comprises carbides embedded in a matrix of pure molybdenum or pure tungsten.
5. The component according to claim 1 , which further comprises more than 25 at % of molybdenum carbide or tungsten carbide, based on a total content of carbon.
6. The component according to claim 1 , which further comprises:
a direction of construction;
a fracture area; and
transcrystalline fracture characteristics over at least 50% of said fracture area in a fracture plane parallel to said direction of construction.
7. The component according to claim 1 , which further comprises:
a direction of construction;
a fracture area; and
transcrystalline fracture characteristics over at least 50% of said fracture area in a fracture plane at right angles to said direction of construction.
8. The component according to claim 1 , wherein the component is free of intermetallic phases.
9. The component according to claim 1 , which further comprises a sum total of metallic alloy elements of not more than 2 at %, not including molybdenum as an alloy element in tungsten or tungsten as an alloy element in molybdenum.
10. The component according to claim 1 , which further comprises an average grain aspect ratio value of less than 5 in a plane parallel to a direction of construction.
11. An additive manufacturing method for production of a component, the method comprising the following steps:
providing a starting powder including particles of molybdenum, a molybdenum-based alloy, tungsten or a tungsten-based alloy having been produced by at least one of granulation or a melt phase;
providing the powder with a carbon content in a region of not less than 0.15 at %;
carrying out layer-by-layer fusion of the particles of the starting powder with a high-energy beam; and
providing the component with an oxygen content of not more than 0.1 at % and a carbon content of not less than 0.08 at %.
12. The additive manufacturing method according to claim 11 , which further comprises providing the carbon content of the powder as not more than 25 at %.
13. The additive manufacturing method according to claim 11 , which further comprises carrying out the step of providing the starting powder by including carburization and spheroidization in the melt phase, and carrying out the step of carburization before, during or after the step of spheroidization.
14. The additive manufacturing method according to claim 13 , which further comprises carrying out the spheroidization in the melt phase in a C-containing atmosphere in a plasma.
15. The additive manufacturing method according to claim 11 , which further comprises carrying out the step of providing the starting powder by including granulation of a raw powder to which a carbonaceous substance has been added.
16. The additive manufacturing method according to claim 11 , which further comprises carrying out the step of layer-by-layer fusion by additionally supplying thermal energy to the component to be produced.
17. A method of using a powder, the method comprising the following steps:
producing a multiplicity of individual powder particles of molybdenum, a molybdenum-based alloy, tungsten or a tungsten-based alloy fused together by a high-energy beam into a solid structure by at least one of granulation or a melt phase;
providing the powder with an average carbon content in a region of not less than 0.15 at % for an additive manufacturing method; and
producing a component having an oxygen content of not more than 0.1 at % and a carbon content of not less than 0.08 at %.
18. The method according to claim 17 , which further comprises selecting the additive manufacturing method as selective laser melting, selective electron beam melting or laser metal deposition.