IP Library › Granted Patent US 11,566,165
Granted Patent B2
US 11,566,165 · App. 16/883,806 · Granted Jan 31, 2023

Polymers and nanoparticles for flooding

Inventors: S. Sherry Zhu (Waban, MA); Ayrat Gizzatov (Cambridge, MA); Marta Antoniv (Cambridge, MA)
Assignee: Saudi Arabian Oil Company
C09K8/588C08F212/20C08F220/06C08F220/22C08F220/24C08F220/56E21B43/20C09K2208/10
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Quick Facts
Patent No.
US 11,566,165
App. No.
16/883,806
Granted
Jan 31, 2023
Kind
B2
Abstract

A method and compounds for enhanced oil recovery (EOR) including flooding of a mixture of water and one or more of the compounds in a geological formation. The compounds have a fluoroalkyl group.

Claims (13)

1. A method comprising:

pumping a mixture through a wellbore into a geological formation, the mixture comprising a surfactant, salt, water, and a polymer having a fluoroalkyl group; and

flowing the mixture through the geological formation, wherein the pumping and the flowing comprise enhanced oil recovery (EOR) comprising flooding, wherein the flooding of the geological formation increases oil recovery from a reservoir in the geological formation, and wherein the flooding comprises polymer flooding or nanofluid flooding, or both,

wherein the polymer having the fluoroalkyl group comprises a partially-hydrolyzed copolymer of fluoroalkyl acrylate and acrylamide, and the partially-hydrolyzed copolymer of fluoroalkyl acrylate and acrylamide comprises the following polymeric structure:

where R1 is —CH2CF3, —CH(CF3)2, or —C(CF3)3, and where R2 is H or CH3.

2. The method of claim 1 , wherein the salt comprises sodium chloride.

3. The method of claim 1 , wherein the water comprises seawater or brine.

4. A method of enhanced oil recovery (EOR), comprising:

injecting a mixture through a wellbore into a geological formation, the mixture comprising water and a partially-hydrolyzed copolymer of fluoroalkyl acrylate and acrylamide; and

flooding the geological formation with the mixture,

wherein the partially-hydrolyzed copolymer of fluoroalkyl acrylate and acrylamide comprises the following polymeric structure:

where R1 is —CH2CF3, —CH(CF3)2, or —C(CF3)3, and where R2 is H or CH3.

5. The method of claim 4 , wherein the flooding of the geological formation increases oil production of a well.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 3, 2020
From: ZHU, S. SHERRY; GIZZATOV, AYRAT; ANTONIV, MARTA
To: ARAMCO SERVICES COMPANY
Reel/Frame 052827/0368 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 3, 2020
From: ARAMCO SERVICES COMPANY
To: SAUDI ARABIAN UPSTREAM TECHNOLOGY COMPANY
Reel/Frame 052827/0438 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 3, 2020
From: SAUDI ARABIAN UPSTREAM TECHNOLOGY COMPANY
To: SAUDI ARABIAN OIL COMPANY
Reel/Frame 052827/0511 →
Continuity (2)
Provisional Application 62854791 · May 30, 2019
Related Publication 20200377787A1 · Dec 3, 2020
Cited By (2)
US 12,421,444 US 12,540,270