Crystallized glass substrate
To provide a crystallized glass substrate including a surface with a compressive stress layer, where a stress depth DOL zero of the compressive stress layer, at which the compressive stress is 0 MPa, is 45 to 200 μm, a compressive stress CS on an outermost surface of the compressive stress layer is 400 to 1400 MPa, and a central stress CT determined by using curve analysis is 55 to 300 MPa.
1. A crystallized glass substrate including a surface with a compressive stress layer, wherein
a stress depth DOL zero of the compressive stress layer is 45 to 200 μm, the stress depth DOL zero being a depth at which a compressive stress is 0 MPa,
a compressive stress CS on an outermost surface of the compressive stress layer is 400 to 1400 MPa, and
a central stress CT determined by using curve analysis is 55 to 300 MPa;
wherein by wt % in terms of oxide, the crystallized glass substrate includes:
40.0% to 70.0% of a SiO 2 component;
11.0% to 25.0% of an Al 2 O 3 component;
5.0% to 19.0% of a Na 2 O component;
0% to 9.0% of a K 2 O component;
1.0% to 18.0% of one or more selected from a MgO component and a ZnO component;
0% to 3.0% of a CaO component;
0.5% to 12.0% of a TiO 2 component, and
0% to 2.0% of a Li 2 O component;
wherein the crystallized glass substrate includes a crystallized glass having a crystal phase containing one or more of MgAl 2 O 4 , MgTi 2 O 4 , MgTi 2 O 5 , Mg 2 TiO 4 , Mg 2 SiO 4 , MgAl 2 Si 2 O 8 , Mg 2 Al 4 Si 5 O 18 , Mg 2 TiO 5 , MgSiO 3 , NaAlSiO 4 , FeAl 2 O 4 , and solid solutions thereof;
wherein an inner size of the outer frame is 151 mm×71 mm, and an inner size of the inner frame is 141 mm×61 mm, a steel ball drop test is constituted by dropping a 130 g stainless steel ball on the crystallized glass substrate placed inside the outer frame and on the inner frame, and the crystallized glass substrate has a breakage height of 60 cm or more.
2. The crystallized glass substrate according to claim 1 , wherein a sum of the stress depths from both surfaces of the crystallized glass substrate, 2×DOL zero , is 10 to 80% of a thickness T of the crystallized glass substrate.
3. The crystallized glass substrate according to claim 1 , wherein a thickness T of the crystallized glass substrate is 0.1 to 1.0 mm.
4. The crystallized glass substrate according to claim 1 , wherein E/ρ, which is a ratio of Young's modulus E (GPa) to a specific gravity ρ, is 31 or more.
5. The crystallized glass substrate according to claim 1 , wherein the compressive stress CS of the outermost surface is 550 to 1400 MPa.
6. The crystallized glass substrate according to claim 1 , wherein the stress depth DOL zero is 70 to 110 μm,
the compressive stress CS of the outermost surface is 550 to 890 MPa,
the central stress CT is 100 to 250 MPa, and
a sum of the compressive stress CS on the outermost surface and the central stress CT is 800 to 1200 MPa.
7. The crystallized glass substrate according to claim 1 , wherein the stress depth DOL zero is 65 to 85 μm,
the compressive stress CS on the outermost surface is 700 to 860 MPa,
the central stress CT is 120 to 240 MPa, and
a thickness T of the crystallized glass substrate is 0.15 to 0.7 mm.