Methods for preparing waterborne heat seal coating compositions
Methods for preparing waterborne heat seal coating compositions are disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a first mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the second mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the second mixing apparatus to form the waterborne heat seal coating composition. Methods for preparing waterborne heat seal coating compositions are also disclosed, including (A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a mixing and conveying zone of a mixing apparatus to form a melt blend, (B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the mixing apparatus to form a dispersion, and (C) diluting the dispersion with water in a dilution zone of the mixing apparatus to form the waterborne heat seal coating composition, wherein the length-to-diameter ratio of the extruder mixing apparatus is greater than or equal to 12 to 1. Waterborne heat seal coating compositions prepared according to the disclosed methods are also disclosed.
1. A method for preparing a waterborne heat seal coating composition for use at a heat seal temperature less than 200° F., comprising:
(A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a first mixing apparatus to form a melt blend;
(B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the second mixing apparatus to form a dispersion; and
(C) diluting the dispersion with water in a dilution zone of the second mixing apparatus to form the waterborne heat seal coating composition.
2. The method according to claim 1 , wherein the first mixing apparatus and/or the second mixing apparatus is an extruder.
3. The method according to claim 1 , wherein the first mixing apparatus is an internal batch mixer.
4. The method according to claim 1 , wherein the second mixing apparatus is a rotor stator mixer.
5. The method according to claim 1 , wherein the wax is selected from the group consisting of a paraffin wax, a microcrystalline wax, a high density, low molecular weight polyethylene wax, a polypropylene wax, a thermally degraded wax, a by-product polyethylene wax, a Fischer-Tropsch wax, an oxidized Fischer-Tropsch wax, a functionalized wax, and combinations thereof.
6. The method according to claim 1 , wherein the first mixing apparatus is operated at a temperature in the range of from 120 to 180° C.
7. The method according to claim 1 , wherein the emulsification zone of the second mixing apparatus is operated at a temperature in the range of from 80 to 150° C.
8. The method according to claim 1 , wherein the neutralizing agent is potassium hydroxide.
9. The method according to claim 1 , wherein the surfactant is oleic acid.
10. The method according to claim 1 , wherein the tackifier is a dimerized gum rosin.
11. The method according to claim 1 , wherein the waterborne heat seal coating composition has a degree of neutralization of acid groups in the range of from 25 to 100 mole percent, based on the total acid content of the waterborne heat seal coating composition.
12. The method according to claim 1 , wherein the ethylene vinyl acetate is present in an amount in the range of from 50 to 85 percent by weight, and the tackifier is present in an amount in the range of from 6 to 20 percent by weight based, on the total weight of solids in the waterborne heat seal coating composition.
13. A method for preparing a waterborne heat seal coating composition for use at a heat seal temperature less than 200°, comprising:
(A) melt blending an ethylene vinyl acetate copolymer, a tackifier, and a wax in a mixing and conveying zone of a mixing apparatus to form a melt blend;
(B) contacting the melt blend with an initial aqueous stream comprising a neutralizing agent, water, and a surfactant in an emulsification zone of the mixing apparatus to form a dispersion; and
(C) diluting the dispersion with water in a dilution zone of the mixing apparatus to form the waterborne heat seal coating composition,
wherein the length-to-diameter ratio of the extruder mixing apparatus is greater than or equal to 12 to 1.
14. The method according to claim 13 , wherein the length-to-diameter ratio of the extruder mixing apparatus is from 12 to 1 to 60 to 1.
15. The waterborne heat seal coating composition produced by the method of claim 1 .