Elimination of surfacing film and primer from composite substrates
Co-curable epoxy-based composite materials coated with co-curable polyurethane-based coating materials to form co-curable and co-cured polyurethane coated epoxy-based composite materials, with the polyurethane-based coating materials comprising UV-stabilizer agents and cure control agents are disclosed, along with components and large structures comprising the co-cured materials.
1. A co-curable epoxy-based composite material comprising:
at least one layer of a co-curable polyurethane-based coating material, said co-curable polyurethane-based coating material configured to be disposed directly onto the co-curable epoxy-based composite material to form co-curable epoxy-based composite material coated with a co-curable polyurethane-based coating material layer, said co-curable polyurethane-based coating material layer comprising:
an amount of a UV-stabilizer agent; and
an amount of a curing control agent;
wherein the co-curable polyurethane-based coating material layer at a thickness ranging from about 2 mils to about 3 mils comprises a UV transmittance value of 0% over a UV wavelength range of from about 200 nm to about 800 nm and comprises a Tg ranging from about 50° F. to about 250° F.
2. The co-curable epoxy-based composite material of claim 1 , wherein the UV-stabilizer agent and the curing control agent are incorporated into the co-curable polyurethane-based coating material layer.
3. The co-curable epoxy-based composite material of claim 1 , wherein the co-curable epoxy-based composite material comprises at least one of: a carbon fiber-reinforced epoxy material, a glass-fiber reinforced epoxy material, a boron fiber-reinforced epoxy material; an aramid fiber-reinforced material; and combinations thereof.
4. The co-curable epoxy-based composite material of claim 1 , wherein the co-curable epoxy-based composite material is configured to co-cure with the co-curable polyurethane-based coating material layer at a temperature ranging from about 250° F. to about 370° F.
5. The co-curable epoxy-based composite material of claim 1 , further comprising:
at least one tack layer configured to be in contact with the co-curable polyurethane-based coating material layer.
6. The co-curable epoxy-based composite material of claim 1 , further comprising:
at least one scrim layer disposed onto the co-curable polyurethane-based coating material layer.
7. The co-curable epoxy-based composite material of claim 1 , further comprising:
at least one scrim layer disposed onto the co-curable polyurethane-based coating material layer; and
at least one tack layer configured to be in contact with the co-curable polyurethane-based coating material layer.
8. The co-curable epoxy-based composite material of claim 1 :
wherein the co-curable epoxy-based composite material does not comprise an intervening surfacing layer between the co-curable polyurethane-based coating material layer and the co-curable epoxy-based coating material; and
wherein the co-curable epoxy-based composite material does not comprise an intervening primer layer between the co-curable polyurethane-based coating material layer and the co-curable epoxy-based composite material.
9. The co-curable epoxy-based composite material of claim 1 , wherein the co-curable polyurethane-based coating material layer is applied as a film to the co-curable epoxy-based composite material.
10. A composite component comprising the co-curable epoxy-based composite material of claim 1 .
11. A co-cured polyurethane-coated epoxy-based composite material comprising:
a co-cured polyurethane-based coating material; and
a co-cured epoxy-based composite material, to form a co-cured polyurethane-coated epoxy-based composite material, said co-curable polyurethane-based coating material layer comprising an amount of a UV stabilizer agent;
wherein the co-cured polyurethane-based coating material layer comprises a UV transmittance value of 0% when the co-cured polyurethane-based coating material layer comprises an average thickness ranging from about 2 mils to about 3 mils.
12. The co-cured epoxy-based composite material of claim 11 , wherein the co-curable epoxy-based composite material does not comprise an intervening surfacing layer between the co-cured polyurethane-based coating material layer and the co-cured epoxy-based coating material; and
wherein the co-cured epoxy-based composite material does not comprise an intervening primer layer between the co-cured polyurethane-based coating material layer and the co-cured epoxy-based composite material.
13. The co-cured epoxy-based composite material of claim 11 , wherein the co-cured polyurethane-based coating material layer has an electrical resistance value greater than 1000 kΩ.
14. A composite component comprising the co-cured epoxy-based composite material of claim 11 .
15. A vehicle comprising the composite component of claim 14 , said vehicle selected from the group consisting of:
a manned aircraft, an unmanned aircraft, a manned spacecraft, an unmanned spacecraft, a manned rotorcraft, an unmanned rotorcraft, a manned terrestrial vehicle, an unmanned terrestrial vehicle; a manned surface water borne vehicle, an unmanned waterborne vehicle, a manned sub-surface water borne vehicle, a satellite, and combinations thereof.
16. A method comprising:
applying a co-curable polyurethane-based coating layer directly to a co-curable epoxy-based composite material;
forming a co-curable polyurethane-coated epoxy-based composite material, said co-curable polyurethane-based coating layer comprising:
a UV-stabilizer agent; and
a curing control agent;
wherein the co-curable polyurethane-based coating material layer at a thickness ranging from about 2 mils to about 3 mils comprises a UV transmittance value of 0% over a UV wavelength range of from about 200 nm to about 800 nm and comprises a Tg ranging from about 50° F. to about 250° F.
17. The method of claim 16 , wherein in the step of applying the polyurethane-based coating material layer to the co-curable epoxy-based composite material, further comprising:
applying the co-curable polyurethane-based coating material layer as a film.
18. The method of claim 16 , further comprising;
applying at least one tack material layer onto at least one of:
the co-curable polyurethane-based coating material layer and the co-curable epoxy-based composite material.
19. The method of claim 16 , further comprising:
applying at least one scrim layer onto at least one of: the co-curable polyurethane-based coating material layer and the co-curable epoxy-based composite material.
20. A method of forming a co-cured epoxy-based composite material comprising:
providing a co-curable epoxy-based composite material coated with a co-curable polyurethane-based coating material layer, said co-curable polyurethane-based coating material layer comprising:
a UV-inhibiting agent;
a curing control agent; and
co-curing the co-curable polyurethane-based coating material layer and the co-curable epoxy-based composite material at a co-curing temperature ranging from about 250° F. to about 370° F. to form a co-cured polyurethane-coated epoxy-based composite material;
wherein the co-curable polyurethane-based coating material layer at a thickness ranging from about 2 mils to about 3 mils comprises a UV transmittance value of 0% over a UV wavelength range of from about 200 nm to about 800 nm and comprises a Tg ranging from about 50° F. to about 250° F.