Silver ink for 3D printing and 3D printing method using same
The present invention relates to silver ink for printing a three dimensional microstructure and a 3D printing method using the same. The present invention provides a method for printing a 3-dimensional silver structure pattern, the method including: a step of providing a nozzle with liquid ink including capped silver nanoparticles and exhibiting Newtonian fluid behavior; a step of forming, at a predetermined point on a substrate, a meniscus of the liquid ink with ink extruded from the nozzle; a step of allowing the ink of the nozzle to be extruded by means of the surface tension of the meniscus while moving the nozzle along a path in a direction perpendicular to the substrate, in a direction parallel to the substrate, or according to a combination of said directions; and a step of forming a silver structure pattern corresponding to the movement path of the nozzle by evaporating a solvent from the extruded ink from the region closer to the substrate. The present invention can provide a 3D printing method based on direct ink printing that is suitable for application to 3D printing electronic technology.
1. A method of printing a three-dimensional (3D) silver structure pattern with a printing pen including a nozzle, the method comprising:
providing the nozzle with liquid ink including capped silver nanoparticles and exhibiting Newtonian fluid behavior;
forming, at a predetermined point on a substrate, a meniscus of the liquid ink between the substrate and the nozzle with ink extruded from the nozzle;
allowing the ink of the nozzle to be extruded by means of surface tension of the meniscus while moving the nozzle along a path in a direction vertical to the substrate, in a direction parallel to the substrate, or according to a combination of the directions; and
forming a silver structure pattern corresponding to the movement path of the nozzle by evaporating a solvent in the extruded ink from the region closer to the substrate.
2. The method of claim 1 , wherein the solvent is a minimum of one kind selected from the polar solvent group consisting of water, alcohol, acetone, and dichloromethane.
3. The method of claim 2 , wherein a concentration of the silver nano particles is 5 to 35 wt %.
4. The method of claim 2 , wherein a line width of the pattern is controlled by a movement speed of the nozzle.
5. The method of claim 4 , wherein the movement speed of the nozzle is 0.1 μm/sec to 200 μm/sec.
6. The method of claim 1 , wherein an aperture of the nozzle is 0.1 to 50 μm.
7. The method of claim 1 , wherein the ink includes a minimum of one kind of polymer selected from the group consisting of poly acrylic acid (PAA), carboxylmethyl cellulose, polyvinylpyrrolidone (PVP), alkyl amine, polyethylene glycol (PEG), and polyvinyl alcohol (PVA) as a capping agent.
8. The method of claim 7 , wherein the capping agent has molecular weight of 50,000 or more.
9. The method of claim 1 , wherein viscosity of the ink is 2 mPa·s to 100 mPa·s.
10. The method of claim 9 , wherein a concentration of silver particles within the ink is 10 to 35 wt %.
11. The method of claim 1 , wherein in the ink, a cumulative distribution of the silver particles of which grain size is 30 nm or more is 10% or more.
12. The method of claim 1 , wherein an average grain size of the ink is less than 15 nm.