IP Library › Granted Patent US 11,597,983
Granted Patent B2
US 11,597,983 · App. 17/041,567 · Granted Mar 7, 2023

High-strength hot-dip galvannealed steel sheet and method for producing same

Inventors: Satoshi Maeda (Tokyo, JP); Yoshiyasu Kawasaki (Tokyo, JP); Yusuke Fushiwaki (Tokyo, JP); Mai Aoyama (Tokyo, JP)
Assignee: JFE Steel Corporation
C21D9/46C21D6/00C21D6/005C21D6/008C21D8/0205C21D8/0226C21D8/0247C21D8/0263C21D8/0273C22C38/002C22C38/02C22C38/04C22C38/06C22C38/08C22C38/12C22C38/14C22C38/16C22C38/32C22C38/60C23C2/06C23C2/28C23C2/40
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Quick Facts
Patent No.
US 11,597,983
App. No.
17/041,567
Granted
Mar 7, 2023
Kind
B2
Abstract

A method for producing a high-strength hot-dip galvannealed steel sheet, in which a high-strength steel sheet is used as a base material, includes a rolling step (x) of rolling a hot-dip galvannealed steel sheet with a coating layer having an Fe concentration of 8% to 17% by mass, and a heat treatment step (y) of heating the coated steel sheet which has been subjected to the rolling step (x) under the conditions satisfying the following formulae (1) and (2): (273+ T )×(20+2×log 10 ( t ))≥8000  (1) 40≤ T ≤160  (2) where T: heating temperature (° C.) of the coated steel sheet, and t: holding time (hr) at the heating temperature T.

Claims (43)

1. A method for producing a high-strength hot-dip galvannealed steel sheet, in which a high-strength steel sheet is used as a base material, the method comprising:

a rolling step (x) of rolling a hot-dip galvannealed steel sheet with a coating layer having an Fe concentration of 8% to 17% by mass; and

a heat treatment step (y) of heating the coated steel sheet which has been subjected to the rolling step (x) under the conditions satisfying the following formulae (1) and (3):

(273+ T )×(20+2×log 10 ( t ))≥8000  (1)

60≤ T≤ 120  (3)

where T: heating temperature (° C.) of the coated steel sheet, and t: holding time (hr) at the heating temperature T.

2. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 1 , further comprising: before the rolling step (x),

an annealing step (a) of annealing the steel sheet;

a coating treatment step (b) of hot-dip galvanizing the steel sheet which has been subjected to the annealing step (a); and

an alloying treatment step (c) of subjecting a coating layer obtained in the coating treatment step (b) to an alloying treatment to obtain the coating layer having an Fe concentration of 8% to 17% by mass.

3. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 1 , wherein, in the rolling step (x), the coated steel sheet is rolled with light reduction at a rolling reduction of 0.10% to 1%.

4. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 1 , wherein the high-strength steel sheet has a composition containing, in percent by mass,

C: 0.03% to 0.35%,

Si: 0.01% to 2.00%,

Mn: 2.0% to 10.0%,

Al: 0.001% to 1.000%,

P: 0.10% or less, and

S: 0.01% or less

with the balance being Fe and unavoidable impurities, and has a tensile strength of 980 MPa or more, and a product (TS×EL) of tensile strength (TS) and total elongation (EL) of 16,000 MPa·% or more; and

a coating weight per one side of the coating layer is 20 to 120 g/m 2 .

5. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 4 , wherein the steel sheet further contains, in percent by mass, one or more selected from

B: 0.001% to 0.005%,

Nb: 0.005% to 0.050%,

Ti: 0.005% to 0.080%,

Cr: 0.001% to 1.000%,

Mo: 0.05% to 1.00%,

Cu: 0.05% to 1.00%,

Ni: 0.05% to 1.00%, and

Sb: 0.001% to 0.200%.

6. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 2 , wherein, in the annealing step (a), in accordance with an Ac 1 temperature and an Ac 3 temperature of the steel sheet, a steel sheet temperature (° C.) is set to be [Ac 1 +(Ac 3 −Ac 1 )/6] to 950° C., and a holding time at the steel sheet temperature is set to be 60 to 600 seconds; and

in the alloying treatment step (c), the alloying treatment temperature is set to be 460° C. to 650° C.

7. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 2 , wherein, in the annealing step (a), a region where a steel sheet temperature is 600° C. to 900° C. is set in an atmosphere having a H 2 concentration of 3% to 20% by volume, and a dew point of −60° C. to −30° C.

8. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 5 , wherein, in the annealing step (a), in accordance with an Ac 1 temperature and an Ac 3 temperature of the steel sheet, a steel sheet temperature (° C.) is set to be [Ac 1 +(Ac 3 −Ac 1 )/6] to 950° C., and a holding time at the steel sheet temperature is set to be 60 to 600 seconds; and

in the alloying treatment step (c), the alloying treatment temperature is set to be 460° C. to 650° C.

9. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 5 , wherein, in the annealing step (a), a region where a steel sheet temperature is 600° C. to 900° C. is set in an atmosphere having a H 2 concentration of 3% to 20% by volume, and a dew point of −60° C. to −30° C.

10. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 6 , wherein, in the annealing step (a), a region where the steel sheet temperature is 600° C. to 900° C. is set in an atmosphere having a H 2 concentration of 3% to 20% by volume, and a dew point of −60° C. to −30° C.

11. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 8 , wherein, in the annealing step (a), a region where the steel sheet temperature is 600° C. to 900° C. is set in an atmosphere having a H 2 concentration of 3% to 20% by volume, and a dew point of −60° C. to −30° C.

12. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 1 , wherein the holding time t at the heating temperature T is from 1 to 500 hours.

13. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 1 , wherein a surface roughness of a work roll used in the rolling is 1.5 μm or less.

14. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 1 ,

wherein the high-strength hot-dip galvannealed steel sheet includes a high-strength steel sheet serving as a base material, wherein a coating layer has an Fe concentration of 8% to 17% by mass, and out of hydrogen being present in the steel sheet, an amount of hydrogen that is released when a temperature of the steel sheet is increased to 200° C. is 0.35 mass ppm or less,

and wherein an average length (L) per unit area of microcracks introduced into the coating layer at a surface of the steel sheet is 0.010 μm/μm 2 or more and 0.070 μm/μm 2 or less, in which a percentage of microcracks that extend in a direction orthogonal to a rolling direction is 60% or less relative to a total length of all the microcracks.

15. The method for producing a high-strength hot-dip galvannealed steel sheet according to claim 14 , wherein the high-strength steel sheet has a product (TS×EL) of tensile strength (TS) and total elongation (EL) of 16,000 MPa·% or more.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 14, 2021
From: MAEDA, SATOSHI; KAWASAKI, YOSHIYASU; FUSHIWAKI, YUSUKE; AOYAMA, MAI
To: JFE STEEL CORPORATION
Reel/Frame 054915/0941 →
Priority Claims (1)
JP JP2018-063321 · Mar 28, 2018 · national
Continuity (1)
Related Publication 20210010100A1 · Jan 14, 2021